Two-stage fluidized bed coal bed gas non-catalytic deoxidation technology

A first fluidized bed, coalbed methane technology, applied in the petroleum industry, gas fuel, fuel and other directions, can solve the problems of low methane concentration and high methane loss rate, achieve high deoxygenation efficiency, high utilization rate, and improve mass transfer. The effect of thermal coefficient

Inactive Publication Date: 2013-10-30
TAIYUAN UNIV OF TECH
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  • Application Information

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Problems solved by technology

[0018] The present invention aims at the problems that the existing coalbed methane deoxygenation method uses a fixed bed for deoxidation, and there is heat accumulation that easily generates a high-temperature zone, causing methane to crack, resulting in low methane concentration in product gas and high methane loss rate, etc., and provides a secondary flow Non-catalytic deoxidation process of bed methane

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  • Two-stage fluidized bed coal bed gas non-catalytic deoxidation technology
  • Two-stage fluidized bed coal bed gas non-catalytic deoxidation technology
  • Two-stage fluidized bed coal bed gas non-catalytic deoxidation technology

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Embodiment Construction

[0027] The specific embodiment of the present invention is further described below:

[0028] like figure 1 Describe, carry out a kind of secondary fluidized bed coalbed methane non-catalytic deoxidation process provided by the present invention, the deoxidizer raw material that adopts is to take semi-coke as an example, the raw material coalbed methane that adopts is the preparation coalbed methane, the mixed raw material gas that adopts is Start the mixed gas of unqualified product gas and raw coalbed methane, and prepare the composition of coalbed methane as follows: (vol%): CH 4 : 25.63; O 2 : 12.67; N 2 : 61.73;, the deoxidizer used is: non-catalytic deoxidizer with particle size <3mm, its deoxidation reaction pressure is: 0.008Mpa, in the first fluidized bed reactor, the feed amount of selected deoxidizer per unit time is 140kg / h, the feed rate of raw coalbed methane and primary product gas per unit time is 1200kg / h, satisfying that the feed mass ratio of raw coalbed ...

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Abstract

The invention provides a two-stage fluidized bed coal bed gas non-catalytic deoxidation technology. The technology comprises that after passing through a heat exchanger, a raw material coal bed gas is introduced into a second fluidized bed reactor from the bottom part of the second fluidized bed reactor to be subjected to a first stage deoxidation reaction with a deoxidizer II, a gas-solid mixture after the deoxidation is introduced into a second gas-solid separator from the top lateral part of the second fluidized bed, and a separated solid is discharged from an ash bucket; a separated primary product gas is introduced into the bottom part of a first fluidized bed to be subjected to a second stage deoxidation reaction with a deoxidizer introduced from the bottom lateral part of the first fluidized bed, a gas-solid mixture after the reaction is introduced into a first gas-solid separator from the top lateral part of the first fluidized bed, and a deoxidation product gas which has an oxygen content less than 1.5% is finally acquired after a separated product gas passes through a heat exchanger, a cooler and a deduster. The deoxidation technology avoids the combustion and cracking reaction of methane and reduces the loss of methane, and at the same time the deoxidizers can be fully used.

Description

technical field [0001] The invention relates to a method for deoxidizing coal bed gas, in particular to a non-catalytic deoxidation process for coal bed gas in a two-stage fluidized bed. Background technique [0002] Coalbed methane belongs to unconventional natural gas, that is, natural gas that is generated during the formation and evolution of coal, has not been migrated, and exists in the coal seam in an adsorbed state. The main component of coalbed methane is methane (CH 4 ), nitrogen and oxygen, is a clean and high calorific value of energy. Since coalbed methane usually does not contain carcinogenic toxic substances such as sulfur, benzene, mercury, and lead, coalbed methane can replace conventional natural gas as a high-calorific value, pollution-free high-quality clean energy, and can be used as fuel for power generation, industrial fuel, and vehicles. Fuel, chemical raw material and residential fuel. Currently, for CH 4 Coalbed methane with a content of more th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L3/10
Inventor 张永发熊小晋刘俊赵钰琼
Owner TAIYUAN UNIV OF TECH
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