Method used for improving organic nanofiltration membrane separating property
A separation performance, nanofiltration membrane technology, applied in the field of membrane separation
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Embodiment 1
[0024] The feed liquid adopted is: pure water, isopropanol, bromothymol blue ethanol solution. In the glass filter device, the nano-inorganic-cellulose acetate composite nanofiltration flat wet film with a gold content of 0.44wt% and a nano-gold size of 20-30nm is attached to the insulating surface and sealed with a sealing ring. There is a transparent glass window on the top of the filter device, so that the continuous argon ion laser beam (wavelength of 514nm) can be irradiated on the upper surface of the membrane. Adjust the laser intensity to 0.2W / cm by adjusting the laser power and the distance between the laser beam emitting end and the film surface 2 , so that the temperature of the membrane reaches 42 °C. The average water flux measured was 0.38 (Lm -2 bar -1 h -1 ), the average flux of isopropanol is 0.30 (Lm -2 bar -1 h -1 ), the average rejection rate of bromothymol blue (BTB, 35 microns, 632 g / mol) was 80.5%.
[0025] The average value of water flux without...
Embodiment 2
[0027] The feed liquid that adopts is isopropanol, bromothymol blue ethanol solution. In the glass filter device, the nano-silver-polyimide nanofiltration flat membrane with a silver content of 0.1wt% and a nano-silver size of 70-80nm is attached to the insulating surface and sealed with a fluororubber O-ring. There is a transparent glass window on the top of the device, which can irradiate the continuous argon ion laser beam (wavelength 425nm) on the membrane surface through mirror reflection. Adjust the laser intensity to 0.13W / cm by adjusting different powers and different distances between the laser beam passing through the lens and the film surface 2 , bring the membrane to 36 °C. The measured flux of isopropanol is 0.25 (Lm -2 bar -1 h -1 ). The average rejection of bromothymol blue (BTB, 35 microns, 632 g / mol) was 82.7%.
[0028] The flux of isopropanol without laser irradiation is 0.21 (Lm -2 bar -1 h -1 ). The average rejection rate of bromothymol blue was ...
Embodiment 3
[0030] The feed liquid that adopts is isopropanol, bromothymol blue ethanol solution. In a specific glass filter device, a nano-gold-polyimide composite nanofiltration flat membrane with a gold content of 0.2wt% and a nano-gold size of 20-30nm is attached to the insulating surface, and a fluororubber O-ring is used to seal the membrane. seal. There is a transparent glass window on the top of the device, which can irradiate the continuous argon ion laser beam (wavelength: 514nm) on the membrane surface through mirror reflection. Adjust the laser intensity to 0.16W / cm by adjusting different powers and different distances between the laser beam passing through the lens and the film surface 2 , bring the film to 40 °C. The measured flux of isopropanol is 0.28 (Lm -2 bar -1 h -1 ), the average rejection rate of bromothymol blue (BTB, 35 microns, 632 g / mol) was 84.3%.
[0031] The flux of isopropanol without laser irradiation is 0.22 (Lm -2 bar -1 h -1 ), the average reject...
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