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Laminated polyester film as protective material for rear surface of solar cell

A technology of solar cells and laminated polyester films, which can be used in electronic equipment, applications, coatings, etc., can solve the problems of water resistance-poor adhesion, insufficient adhesion maintenance, etc., and achieve excellent hydrolysis resistance and excellent water resistance - Adhesiveness and high utility value

Active Publication Date: 2013-01-02
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, as a problem, it has been clarified that, for example, when the resin coating film proposed in Patent Document 1 is coated on the white polyester film shown in the examples of Patent Document 2, and the hydrolysis resistance of adhesiveness is evaluated, Adhesion maintenance may not be sufficient
That is, it is clear that when the white pigment is added at a concentration sufficient to reflect light leakage on the polyester film, compared with the case where the white pigment is not added or a small amount is added to the polyester film, the polyester film and EVA or PBV Etc. water resistance - poor adhesion

Method used

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  • Laminated polyester film as protective material for rear surface of solar cell
  • Laminated polyester film as protective material for rear surface of solar cell
  • Laminated polyester film as protective material for rear surface of solar cell

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0158] The polyester in which the above-mentioned polyester (2) and polyester (4) were mixed in a weight ratio of 70:30 was set as the raw material for the polyester A layer, and the polyester ( 2) The polyester with white pigment masterbatch 1 (WMB1) is set as the raw material for the polyester B layer. Put these raw materials into two twin-screw extruders with ventilation holes, melt and extrude them at 290°C, and merge them with a multi-branched pipe die to achieve a layer structure ratio of A / B=2 / 3. After layering, quenching and solidification was carried out on a casting drum whose surface temperature was set to 40° C. using an electrostatic application adhesion method to obtain an unstretched sheet. The longest residence time during this melt extrusion was 12 minutes. The obtained sheet was stretched 3.6 times in the longitudinal direction at 85° C. by a roll stretching method. Wherein, after the corona discharge treatment is carried out on the surface of the polyester...

Embodiment 2

[0160] In Example 1, as a raw material, a polyester mixed with polyester (2) and polyester (4) in a weight ratio of 70:30 was used as a raw material for the polyester A layer, and a polyester layer was used in a weight ratio of 70:30 Polyester mixed with polyester (2) and white pigment masterbatch 2 (WMB2) was set as the raw material for polyester B layer. Each of these raw materials was put into two twin-screw extruders with ventilation holes, melted and extruded at 290°C, and multi-branched pipes were used to achieve a layer structure ratio of A / B / A=3 / 44 / 3. After the dies were merged and laminated, they were rapidly cooled and solidified on a casting drum whose surface temperature was set to 40° C. using an electrostatic adhesion method to obtain an unstretched sheet. The longest residence time during this melt extrusion was 14 minutes. The obtained sheet was stretched 3.6 times in the longitudinal direction at 85° C. by a roll stretching method. Here, after the corona dis...

Embodiment 3

[0162] In Example 2, as a raw material, the polyester mixed with polyester (2), polyester (4) and white pigment masterbatch 2 (WMB2) at a weight ratio of 56:30:14 was changed to polyester A layer A film having a thickness of 50 μm was obtained in exactly the same manner as in Example 2 except that the raw materials were used. The longest residence time during this melt extrusion was 14 minutes. Table 3 shows the characteristics and evaluation results of the film.

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Abstract

Provided is a laminated polyester film as a protective material for the rear surface of a solar cell, which has excellent resistance to hydrolysis, and excellent adhesion to a solar cell encapsulating resin. The laminated polyester film as a protective material for the rear surface of a solar cell is a laminated polyester film having the polyester (A) layer below in at least one of the outermost layers, and contains the polyester (B) layer below in at least one of the layers. The amount of terminal carboxyl groups in the laminated polyester film is not more than 26 eq / ton. The laminated polyester film has a coating layer formed on at least one surface of the polyester (A) layer from a polyurethane having a polycarbonate skeleton and / or a polyether skeleton, and a crosslinking agent. Polyester (A) layer: a layer comprising a polyester having an aromatic polyester as the main constituent, and containing less than 8 wt% of white pigment Polyester (B) layer: a layer comprising a polyester having an aromatic polyester as the main constituent, and containing at least 8 wt% of white pigment

Description

technical field [0001] The present invention relates to a laminated polyester film for protecting the back of a solar cell, in particular, to a laminated polyester for protecting the back of a solar cell, the base film of which is a white film with high reflectivity, and the The laminated polyester film for solar cell back protection material has excellent hydrolysis resistance, and has the properties of ethylene-vinyl acetate copolymer resin (hereinafter, sometimes abbreviated as EVA) and polyvinyl acetal Sealing resins such as butyral resin (hereinafter, sometimes abbreviated as PVB) have excellent water resistance-adhesive properties. Background technique [0002] In recent years, photovoltaic power generation has attracted much attention as a clean energy source that contributes to the prevention of global warming, and has begun to spread to a considerable extent. As a representative of this photovoltaic power generation, a solar cell using a semiconductor such as monoc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/042B32B27/36B32B27/40C08J7/04C08J7/043C08J7/044C08J7/046C08J7/052
CPCH01L31/0487B32B2457/12B32B27/20Y02E10/50B32B27/40Y02B10/12B32B27/36H01L31/048B32B27/08B32B27/306B32B27/365B32B2255/10B32B2255/26B32B2264/102B32B2264/104B32B2307/416B32B2307/518B32B2307/714C08J7/06C08J2367/02C08J2475/04H01L31/049Y10T428/31565Y10T428/31576Y10T428/31573C08J7/0427Y02B10/10C08J7/052C08J7/043C08J7/046C08J7/042C08J7/044C08G71/00C08G71/04B32B2367/00C08G2115/06
Inventor 增田成裕能泽晃太郎T·奇内
Owner MITSUBISHI CHEM CORP