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A kind of heat-resistant magnesium alloy strengthened by Sn, Si compound and preparation method thereof

A magnesium alloy and heat-resistant technology, applied in the field of metal materials and metallurgy, can solve the problems of reducing the corrosion resistance of the alloy, the refinement is not obvious, and the magnesium alloy grain is coarse, and achieves the effect of improving the heat resistance and mechanical properties.

Active Publication Date: 2015-12-02
镁高镁诺奖(铜川)新材料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, there is still a large amount of β-Mg in the alloy structure l7 al 12 phase, which weakens the effect of the high-temperature strengthening phase in the alloy, and the high-temperature performance of the alloy cannot be effectively improved.
In addition, due to the use of expensive rare earth elements, the cost of the alloy is increased, which is not conducive to practical application
Third, due to the presence of aluminum, brittle phases containing aluminum-rare earth will be formed, which is not conducive to the improvement of the overall performance of the alloy.
However, adding some elements as modifiers for nascent bulk Mg 2 Si refinement is not obvious, and adding a large amount of Ca and La elements will cause hot cracking of the alloy and increase the cost, and reduce the corrosion resistance of the alloy, so the alloying and microalloying modification treatment is limited
The patent published by Li Xinlin "Mg-Si-Sn series magnesium alloy and the heat treatment process of the Chinese character-shaped eutectic Mg2Si phase" (application number: 200710144699.9, publication number: CN101161840A, publication date: 2008.04.16) treats Mg by high temperature heat treatment. 2 The Si phase is refined, and its heat treatment temperature is as high as 490-550 ° C, which will inevitably cause overheating or over-burning of the magnesium alloy, resulting in coarse grains, and this temperature is even more undesirable for larger magnesium alloy castings

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  • A kind of heat-resistant magnesium alloy strengthened by Sn, Si compound and preparation method thereof
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  • A kind of heat-resistant magnesium alloy strengthened by Sn, Si compound and preparation method thereof

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preparation example Construction

[0031] The present invention also provides the preparation method of above-mentioned magnesium alloy, improves the heat-resistant performance of alloy through Sn, Si composite strengthening, such as figure 1 As shown, follow the steps below to implement:

[0032] Step 1, weigh magnesium ingot, SiO 2 and Sn, so that it satisfies the following mass percentages: 3-6% Sn, 0.5-3.5% Si, and the balance is Mg, and the total mass percentage of the above components is 100%; wherein SiO 2 for SiO 2 powder or SiO 2 Granules, i.e. quartz powder or quartz granules, SiO 2 The particle size of the powder is 3-100μm, SiO 2 The particle size of the particles is 0.5-1.5mm;

[0033] Step 2, the SiO 2 Dry at a temperature of 200-450°C, and the drying time is 0.5-2.5 hours;

[0034] Step 3, Drill holes on the magnesium ingot, the size of the holes can be filled with the required SiO 2 As the standard, the SiO that has been dried in step 2 2 Place in the drilled hole and seal the hole with...

Embodiment 1

[0048] The composition of the alloy is composed by weight percentage: 3% Sn, Si% 1, the rest is Mg and unavoidable impurities.

[0049] The alloy casting process is:

[0050] SiO with a particle size of 3-100 μm 2 The powder was dried at a temperature of 250°C for 1.5 hours, and the dried SiO 2 Powder ready for use. Saw industrial pure magnesium ingots into small pieces, the size of which can be put into the crucible, and drill holes on the sawed magnesium ingots, the size of which can be filled with the required SiO 2 The powder shall prevail; the magnesium ingot quality after drilling shall be weighed according to the ratio; the SiO 2 The powder is filled into the drilled holes on the magnesium ingot. The ingot is placed in the crucible with the drilled hole facing up, and the required Sn is added to heat to 750°C for melting, and the melting process is carried out under the protection of Ar gas. When the AZ91 magnesium alloy is completely melted, it is mechanically sti...

Embodiment 2

[0054] The composition of the alloy is composed by weight percentage: 5% Sn, Si% 0.5, and the rest are Mg and unavoidable impurities.

[0055] The alloy casting process is:

[0056] SiO with a particle size of 3-100 μm 2 The powder was dried at 200°C for 2.5 hours, and the dried SiO 2 Powder ready for use. Saw industrial pure magnesium ingots into small pieces, the size of which can be put into the crucible, and drill holes on the sawed magnesium ingots, the size of which can be filled with the required SiO 2 The powder shall prevail; the magnesium ingot quality after drilling shall be weighed according to the ratio; the SiO 2 The powder is filled into the drilled holes on the magnesium ingot. The ingot is placed in the crucible with the drilled hole facing up, and the required Sn is added to heat to 750°C for melting, and the melting process is carried out under the protection of Ar gas. When the AZ91 magnesium alloy is completely melted, mechanical stirring is used for ...

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Abstract

The invention discloses a novel Sn and Si combined reinforced novel heat-resistant magnesium alloy and a preparation method thereof. The magnesium alloy comprises the following components of: 3 to 6 mass percent of Sn, 0.5 to 3.5 mass percent of Si and the balance of Mg. The preparation method comprises the following steps of: weighing a magnesium ingot, SiO2 and Sn, and drying the SiO2; drilling a hole in the magnesium ingot, putting the dried SiO2 in the drilled hole, and sealing the hole by using the magnesium ingot; placing the magnesium ingot and the Sn in a crucible for heating and melting; after the metal is completely melted, stirring, performing drossing and casting to prepare a magnesium alloy blank; and performing thermal treatment on the magnesium alloy blank, and extruding or rolling to form a bar or a plate. Mg2Sn and Mg2Si high-temperature strengthening phases are generated by adding Sn, Si and Mg, the Mg2Sn phase is separated out in a dispersive mode through T6 treatment, and the Mg2Si phase is nodulized. The magnesium alloy is extruded and deformed and further refines the strengthening phases and a structure, so that joint strengthening of various strengthening mechanisms is realized, the strength and the heat resistance of the alloy are effectively improved, and the magnesium alloy is low in cost and high in performance.

Description

technical field [0001] The invention belongs to the technical field of metal materials and metallurgy, and relates to an alloy, in particular to a heat-resistant magnesium alloy strengthened by Sn and Si composites and a preparation method thereof. Background technique [0002] Magnesium and magnesium alloys are currently the lightest metal structural materials, with their high specific strength, specific stiffness, good anti-magnetic interference, high electronegativity and thermal conductivity, and become one of the most promising metal materials in the 21st century. First, it is widely used in industries such as aerospace, modern automobiles, and portable electronic products. At present, two Mg-Al magnesium alloys, AZ and AM, are widely used in production, among which the most representative AZ91D magnesium alloy has high room temperature strength, good casting process performance and machinability and excellent The advantages of corrosion resistance and low cost have ma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/00C22C1/02C22F1/06
Inventor 徐春杰屠涛余玲张忠明
Owner 镁高镁诺奖(铜川)新材料有限公司