Film for pressure-sensitive adhesive tape and pressure-sensitive adhesive tape
A technology of pressure-sensitive adhesive tape and pressure-sensitive adhesive layer, applied in the directions of adhesives, adhesive types, chemical instruments and methods, etc., can solve problems such as operability deterioration, temperature influence, change, etc., to suppress excessive adhesion , good compatibility, good follow-up effect
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[0089] Hereinafter, the present invention is specifically described by way of examples. However, the present invention is by no means limited to these Examples. The term "part" means "part by weight". In addition, the amount of the reagent supplied as a solution is represented by the amount of solid content remaining after the solution evaporates (amount in terms of solid content).
[0090]
[0091] The maximum elongation is measured with an Instron type tensile tester (manufactured by Shimadzu Corporation, Autograph) according to JIS-K-7127. Specifically, a sample having a size of 20 mm wide by 100 mm long was placed with a distance between clamps of 50 mm. Then, the sample was stretched at a tensile speed of 0.3 m / min, and the value of elongation at break was measured.
[0092]
[0093] The modulus of elasticity is measured according to JIS-K-7127.
[0094]
[0095] (observed with TEM)
[0096] Processing was performed so that the cross-section of the non-pressure...
manufacture example 1
[0129] (Manufacturing example 1): Manufacture of plastic film
[0130]Polyvinyl chloride having a degree of polymerization P of 1,050 was produced by a colander method with 27 parts by weight of a DOP plasticizer (bis(2-ethylhexyl) phthalate, produced by J-PLUS Co., Ltd.) soft polyvinyl chloride film. The soft polyvinyl chloride film had a thickness of 70 μm, an elastic modulus (MD) of 250 MPa measured according to JIS-K-7127, and a maximum elongation (MD) of 400% measured according to JIS-K-7127. In addition, the film immediately after production had a surface roughness (arithmetic mean surface roughness Ra) of 0.1 μm.
Embodiment 1
[0132] 60 parts by weight of polysiloxane resin (KS-723A, manufactured by Shin-Etsu Chemical Co., Ltd.), 40 parts by weight of polysiloxane resin (KS-723B, manufactured by Shin-Etsu Chemical Co., Ltd.), 100 parts by weight of acrylic copolymer (methyl methacrylate (MMA) / butyl acrylate (BA) / hydroxyethyl acrylate (HEA)=70 / 30 / 10), 10 parts by weight Parts of tin-based catalyst (Cat-PS3, manufactured by Shin-Etsu Chemical Co., Ltd.) and 1.0 parts by weight of methylhydrogensiloxane-based curing accelerator X92-122 (manufactured by Shin-Etsu Chemical Co., Ltd.) in a solution state mix. Thus, a mixed solution (1) was obtained. The mixing ratio "polysiloxane:(meth)acrylic polymer" between polysiloxane and (meth)acrylic polymer in the mixed solution (1) was 1:1 by weight.
[0133] The mixed solution (1) was applied to one surface of the soft polyvinyl chloride film prepared in Production Example 1 and dried to form a non-pressure-sensitive film having a thickness of 1.0 μm and an ar...
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Abstract
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