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Method for preparing Ni-P-CNT (Carbon nanotube) nano composite coating

A composite coating, ni-p-cnt technology, applied in the application field of chemical plating, can solve the problem that the dispersion is not well solved, the stability of the plating solution, and the co-deposition mechanism of nanoparticles and metal ions has no perfect theory. Explanation and other issues to achieve the effect of superior performance, excellent mechanical properties, good toughness

Inactive Publication Date: 2013-05-08
XIAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) There is no perfect theoretical explanation for the co-deposition mechanism of nanoparticles and metal ions in nanocomposite coatings;
[0007] (2) The stability of the plating solution
[0008] (3) Dispersion of nanoparticles in composite bath and composite coating
The methods to solve the agglomeration of nanoparticles usually include mechanical stirring, magnetic stirring, gas stirring and ultrasonic dispersion. At present, the most effective way is to add surfactant, but the problem of its dispersion has not been well solved;

Method used

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  • Method for preparing Ni-P-CNT (Carbon nanotube) nano composite coating
  • Method for preparing Ni-P-CNT (Carbon nanotube) nano composite coating

Examples

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Effect test

Embodiment 1

[0050] The carbon nanotube (Carbon nano-tube, CNT, hereinafter referred to as CNT) raw material was boiled in concentrated sulfuric acid for 6 hours, and finally washed with deionized water to neutrality, filtered and placed in a drying oven at 80°C for drying.

Embodiment 2

[0052] The CNT raw material was boiled in concentrated nitric acid for 6 hours, and finally washed with deionized water until neutral, filtered and then put into a drying oven for drying at 80°C.

Embodiment 3

[0054] The CNT raw material was boiled for 6 hours in concentrated sulfuric acid and concentrated nitric acid with a volume fraction of 3:1, and finally washed with deionized water to neutrality, filtered, and then dried in a drying oven at 80°C.

[0055] figure 2 It is the TEM picture of the CNT before and after acid treatment in Example 3. From figure 2 (a), figure 2 (c) It can be seen that the entanglement and agglomeration of CNTs after acid treatment is significantly reduced. Simultaneous comparison figure 2 (b), figure 2 (d) It is not difficult to find that after pickling and oxidation, black groups appeared on the surface of carbon nanotubes, which were later confirmed to be hydroxyl or carboxyl groups.

[0056] image 3 Infrared spectrum pictures of carbon nanotubes (CNTs) before and after acid treatment in Example 3. Depend on image 3 It can be seen that no matter before or after concentrated acid treatment, there are obvious hydroxyl peaks (3444cm -1 )...

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Abstract

The invention discloses a method for preparing a Ni-P-CNT (Carbon nanotube) nano composite coating. The method comprises the following steps of: performing acid oxidation treatment on a carbon nano-tube (CNT) before coating, utilizing an ultrasonic dispersion technology and adding a proper amount of surfactant into a chemical plating solution, so that the CNT is uniformly dispersed in the chemical plating solution. A proper chemical plating solution formula is selected, a proper amount of surfactant is added, the coating solution is not decomposed and precipitated in the chemical plating process through an intermittent magnetic stirring method, the chemical and physical characteristics are stable and reliable, the nano composite coating which is high in hardness, wear resistance and corrosion resistance is prepared compared with the traditional Ni-P coating, and the problem that the CNT is dispersed is solved.

Description

technical field [0001] The invention belongs to the application field of electroless plating, and relates to a new method for preparing a Ni-P-CNT nanocomposite coating, which is mainly applied to wear-resistant and corrosion-resistant functional coatings and decorative coatings of various metal parts and materials . Background technique [0002] Nano surface engineering is based on nanomaterials and other low-fiber non-equilibrium materials, through specific processing techniques and means, to strengthen, modify, ultra-fine processing or endow the surface with new functions on the solid surface system engineering. In short, nano surface engineering is to intersect, compound, synthesize and develop applications of nanomaterials and nanotechnology with surface engineering. [0003] The electroless plating method is used to add nanoparticles to the ordinary plating solution, and the composite coating obtained by co-depositing the nanoparticles and the matrix metal under stirr...

Claims

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Application Information

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IPC IPC(8): C23C18/36
Inventor 孙万昌周泉侯嵬玮
Owner XIAN UNIV OF SCI & TECH
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