Method for preparing Ni-P-CNT (Carbon nanotube) nano composite coating
A composite coating, ni-p-cnt technology, applied in the application field of chemical plating, can solve the problem that the dispersion is not well solved, the stability of the plating solution, and the co-deposition mechanism of nanoparticles and metal ions has no perfect theory. Explanation and other issues to achieve the effect of superior performance, excellent mechanical properties, good toughness
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Embodiment 1
[0050] The carbon nanotube (Carbon nano-tube, CNT, hereinafter referred to as CNT) raw material was boiled in concentrated sulfuric acid for 6 hours, and finally washed with deionized water to neutrality, filtered and placed in a drying oven at 80°C for drying.
Embodiment 2
[0052] The CNT raw material was boiled in concentrated nitric acid for 6 hours, and finally washed with deionized water until neutral, filtered and then put into a drying oven for drying at 80°C.
Embodiment 3
[0054] The CNT raw material was boiled for 6 hours in concentrated sulfuric acid and concentrated nitric acid with a volume fraction of 3:1, and finally washed with deionized water to neutrality, filtered, and then dried in a drying oven at 80°C.
[0055] figure 2 It is the TEM picture of the CNT before and after acid treatment in Example 3. From figure 2 (a), figure 2 (c) It can be seen that the entanglement and agglomeration of CNTs after acid treatment is significantly reduced. Simultaneous comparison figure 2 (b), figure 2 (d) It is not difficult to find that after pickling and oxidation, black groups appeared on the surface of carbon nanotubes, which were later confirmed to be hydroxyl or carboxyl groups.
[0056] image 3 Infrared spectrum pictures of carbon nanotubes (CNTs) before and after acid treatment in Example 3. Depend on image 3 It can be seen that no matter before or after concentrated acid treatment, there are obvious hydroxyl peaks (3444cm -1 )...
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