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Environment-friendly washing-resistant antistatic coating and preparation method thereof

An anti-static coating and washing-resistant technology, applied in conductive coatings, polyester coatings, polyurea/polyurethane coatings, etc., can solve the problems of poor operability, poor adhesion and oil resistance, and high cost of conductive materials, and achieve adhesion. Strong, water-resistant organic solvent washing, easy to use effect

Active Publication Date: 2013-06-26
广东广麟材耀新能源材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The technical problem to be solved by the present invention is that the antistatic coatings made by the method of adding conductive materials have poor adhesion and oil resistance and high cost, and the operability of directly coated conductive materials is poor and difficult. Due to the disadvantages of processing, provide an environmentally friendly anti-static coating with strong adhesion, washing resistance, low cost, easy processing and convenient use and its preparation method

Method used

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  • Environment-friendly washing-resistant antistatic coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033]An environment-friendly washing-resistant antistatic coating, comprising the following components in weight percent: PEDOT / PSS 0.5%, water-based saturated polyester (EW312) 3%, fatty alcohol polyoxyethylene (20) ether 0.2%, fluorocarbon Surfactant (FSN) 0.1%, fluorocarbon surfactant (Intechem-14-5B) 0.5%, titanate coupling agent (KINST114) 0.5%, dodecylbenzenesulfonic acid 0.1%, ethanol 8 %, butanone 5% and deionized water 82.1%. Its preparation method comprises the following steps:

[0034] Dissolve PEDOT / PSS in diluted dodecylbenzenesulfonic acid, adjust the pH value after mixing to prepare a conductive filler solution, and set aside; under heating conditions, dissolve water-based saturated polyester (EW312) in butanone, dissolve After completion, add fatty alcohol polyoxyethylene (20) ether, fluorocarbon surfactant (FSN), fluorocarbon surfactant (Intechem-14-5B), titanate coupling agent (KINST114) and Ethanol, mixed uniformly to prepare a film-forming solution; and ...

Embodiment 2

[0037] An environment-friendly washing-resistant antistatic coating, comprising the following components in weight percent: PEDOT / PSS 0.6%, water-based saturated polyester (EW370) 5%, fatty alcohol polyoxyethylene (200) ether 0.2%, fluorocarbon Surfactant (FSN) 0.05%, fluorocarbon surfactant (Intechem-14-5B) 0.8%, silane coupling agent (KH755) 0.3%, sulfuric acid 0.1%, isopropanol 10%, N-methyl Pyrrolidone 10% and deionized water 72.95%. Its preparation method comprises the following steps:

[0038] Dissolve PEDOT / PSS in diluted sulfuric acid, adjust the pH value after mixing to prepare a conductive filler solution, and set aside; dissolve water-based saturated polyester (EW370) in N-methylpyrrolidone under heating conditions, press Proportionally add fatty alcohol polyoxyethylene (200) ether, fluorocarbon surfactant (FSN), fluorocarbon surfactant (Intechem-14-5B), silane coupling agent (KH755) and isopropanol, mix The film-forming solution is uniformly prepared; the separat...

Embodiment 3

[0041] An environment-friendly washable and antistatic coating, comprising the following components in weight percent: PEDOT / PSS 0.1%, water-based saturated polyester (EW370) 3.05%, nonylphenol polyoxyethylene ether (TX-10) 0.1%, Fluorocarbon surfactant (FC4430) 0.1%, silane coupling agent (KH755) 0.1%, hydrochloric acid 0.05%, butanol 5%, N-methylpyrrolidone 5% and deionized water 86.5%. Its preparation method is the same as that of Example 1; in the preparation method, the concentration of hydrochloric acid is 15%.

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Abstract

The invention relates to an antistatic coating and discloses an environment-friendly washing-resistant antistatic coating. The antistatic coating comprises the following components by weight percent: 3-9% of film former, 0.1-0.6% of conductive filler, 0.2-3.1% of surfactants, 0.1-0.6% of coupling agents, 0-0.1% of acid, 5-20% of ketone solvent, 5-20% of alcohol solvent and 47-86.5% of water. The preparation method can be implemented to prepare the antistatic coating which is efficient, has low toxicity and strong adhesion, is resistant to washing with water and organic solvents and is convenient to use, prepare and process; the components of the antistatic coating are the raw materials which are easily available, so the cost of the prepared antistatic coating can be effectively lowered; with water as a main solvent, the prepared antistatic coating is non-toxic and environment-friendly; and the preparation method is carried out under normal temperature and pressure, the conditions required by the preparation process are easy to reach, the preparation flow is simple and the operability is strong.

Description

technical field [0001] The present invention relates to an antistatic coating, more specifically, relates to an environment-friendly washing-resistant antistatic coating and a preparation method thereof. Background technique [0002] Electrostatic charge exists widely in our daily life, which may cause the following four hazards: (1) electrostatic discharge; (2) electrostatic adsorption; (3) the existence of electrostatic charge will increase the reactivity of substances; (4) static electricity can Harmful to human health. One of the most serious hazards is that electrostatic discharge can generate sparks, which may cause explosions and fires where flammable and explosive materials exist. Secondly, the current of fast electrostatic discharge can cause breakdown and other damage to modern electronic products, especially integrated circuits. . [0003] Polymer materials are materials composed of compounds with relatively high molecular weights, including rubber, plastics, fi...

Claims

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Application Information

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IPC IPC(8): C09D167/06C09D175/04C09D5/24C09D7/12
Inventor 刘德龙蔡红军
Owner 广东广麟材耀新能源材料有限公司
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