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Glass fiber, preparation method thereof and glass fiber composite material

A glass fiber and content technology, applied in the field of its preparation and glass fiber, can solve the problems of restricting the conversion of wind energy and electric energy, low output, restricting the cost of wind power generation, etc., and achieve the effect of reducing carbon emissions and low viscosity temperature.

Inactive Publication Date: 2013-08-07
杨德宁
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0023] 9. Especially for wind blade materials in glass fiber composite materials, due to the low strength of glass fibers used, or the high cost and low output of S-grade glass fibers, the sweeping area of ​​wind blades cannot be increased, which seriously restricts The conversion of wind energy to electric energy restricts the cost of wind power generation, which is much higher than that of thermal power and hydropower.

Method used

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  • Glass fiber, preparation method thereof and glass fiber composite material
  • Glass fiber, preparation method thereof and glass fiber composite material

Examples

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preparation example Construction

[0053] Now the preparation technology of glass fiber of the present invention is made its goods with stretching spinning process and is described further, and its manufacturing process comprises the following steps:

[0054] (1) First, the raw materials are prepared, and the ratio of the raw materials is calculated according to the glass fiber composition of the above-mentioned first embodiment and various modification examples thereof.

[0055] (2) Prepare the production line equipment required for the drawing and drawing process including the raw material warehouse, melting pool kiln, and platinum alloy drawing plate with drawing holes.

[0056] (3), press figure 2 In the production flow of the process shown, the predetermined raw materials prepared in step (1) are put into the feed bin, and then the raw materials are transported from the feed bin to the molten pool kiln, and then melted at the predetermined temperature after entering the molten pool and Air bubbles are re...

Embodiment 1

[0063] In terms of weight percentage, the content of silicon oxide in the glass is 54.8%, the content of calcium oxide is 12.2%, the content of magnesium oxide is 8%, the content of aluminum oxide is 25%, and the content of silicon oxide is 4.5 times that of calcium oxide. The content of calcium oxide is 1.52 times that of magnesium oxide.

[0064] Its actual melting viscosity temperature is 10 1.5 (Pa·s) when the temperature is 1690°C viscosity temperature, the actual homogenized air bubble viscosity temperature is 10 2 (Pa·s) at 1495°C; molding viscosity temperature 10 3 (Pa·s) is 1295°C; the upper line of crystal folding temperature is 1265°C.

[0065] The nominal diameter of the glass fiber is within 3 microns to 15 microns, the deviation of the glass fiber diameter is within ±15% of the nominal diameter, and the breaking strength (N / tex) is 0.88 when the diameter is less than or equal to 9 microns.

Embodiment 2

[0067] In terms of weight percentage, the content of silicon oxide in the glass is 56.3%, the content of calcium oxide is 13%, the content of magnesium oxide is 8.7%, the content of aluminum oxide is 22%, and the content of silicon oxide is 4.3 times that of calcium oxide. The content of calcium is 1.5 times that of magnesium oxide.

[0068] The actual melting viscosity temperature is 10 1.5 (Pa·s) when the temperature is 1660°C viscosity temperature, the actual homogenized bubble discharge viscosity temperature is 10 2 (Pa·s) at 1465°C; molding viscosity temperature 10 3 (Pa·s) is 1275°C; the upper line of crystal folding temperature is 1245°C.

[0069] The nominal diameter of the glass fiber is within 3 microns to 15 microns, the deviation of the glass fiber diameter is within ±15% of the nominal diameter, and the breaking strength (N / tex) is 0.75 when the diameter is less than or equal to 9 microns.

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Abstract

The invention discloses a glass fiber, a preparation method thereof and a glass fiber composite material. The nominal diameter of the glass fiber ranges from 3 micro to 15 micro and the deviation value of the diameter of the glass fiber is within + / -15% of the nominal diameter. According to the weight percent, in the glass fiber, the alumina content is 20-33%, the silicon oxide content is 4.11-5.48 times of calcium oxide and the calcium oxide content is 0.9-2.1 times of magnesium oxide. Under the condition of high alumina content (20-33% or 23-33% or 25-33%), the glass fiber can generate a new product property with the function of dispersion of aluminum, silicon, calcium and magnesium, so that the problem in the prior art that the dissolving and the quality of air bubbles cannot be controlled resulting from high glass viscosity as a result of high aluminum content is solved; energy and consumption are greatly reduced; the carbon emission is lowered; the devitrification temperature is low, so that mass production can be carried out; and besides, pollutant discharge of toxic boron gas is not generated in the production process.

Description

technical field [0001] The invention relates to glass fiber and its preparation method. The glass fiber has the characteristics of low crystallization temperature, high strength and low viscosity. The glass fibers can be used to make glass fiber composites. Background technique [0002] Existing glass fibers and glass fiber composite products all have some defects: [0003] 1. High and medium-alkali glass fiber: by weight percentage, its composition contains about 67% silicon oxide, about 1% magnesium oxide, about 9.5% calcium oxide, about 5-7% aluminum oxide, and about 2-2% sodium oxide 10%, fluorine oxide about 0.5%, boron oxide about 3%, barium oxide about 2%. The defect of its products is that the viscosity in the production process is high, and the production energy consumption is large; when the diameter of the glass fiber is less than or equal to 9 microns, the breaking strength (N / tex) is poor, generally below 0.4, so the technical effect is poor, and it is difficu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C13/00C03B37/022
CPCC03C13/00C03B37/022C03C3/087
Inventor 杨德宁
Owner 杨德宁
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