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Vacuum-assisted resin diffusion molding method for fiber-reinforced PBT composite material

A technology of fiber-reinforced materials and composite materials, applied in the field of large-scale thermoplastic composite components, can solve the problems of large-scale manufacturing limitations of large components, high molding temperature and pressure, and strict requirements for mold equipment, so as to avoid molding temperature and molding Effects of pressure, enhanced wetting, and ease of handling

Inactive Publication Date: 2015-04-08
HARBIN ENG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These molding processes have high molding temperature and molding pressure, high energy consumption, and strict requirements on mold equipment, so the production cost is high, especially limited in the large-scale manufacturing of large components

Method used

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  • Vacuum-assisted resin diffusion molding method for fiber-reinforced PBT composite material
  • Vacuum-assisted resin diffusion molding method for fiber-reinforced PBT composite material
  • Vacuum-assisted resin diffusion molding method for fiber-reinforced PBT composite material

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Experimental program
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Effect test

specific Embodiment approach 1

[0026] The catalyst used is dihydroxybutyl tin chloride of the type PC-4101 produced by Guangzhou Yuansu Chemical Co., Ltd.; the fiber reinforcement used is produced by Yixing Fuxing Glass Fiber Co., Ltd. with an area density of 300g / m 2 The glass fiber unidirectional cloth; the CBT resin used is the model CBT100 resin produced by Cyclics Company of the United States, and it is dried in an oven at 105 ° C for 10 h before use.

[0027] Step 1), attach the catalyst to the glass fiber unidirectional cloth. The specific operation is: pour the catalyst with a mass of 0.6% of the mass injected into the CBT resin into an appropriate amount of isopropanol solution, and use a magnetic stirrer to stir at 80°C for 10 minutes. Dissolve the catalyst completely, brush the solution evenly on the glass fiber cloth, put it in an oven at 130°C, bake for 30 minutes, and turn the glass fiber cloth over halfway.

[0028] Step 2), select a flat mold with a cavity thickness of 2mm, paste a high-temp...

specific Embodiment approach 2

[0033] The catalyst used is dihydroxybutyl tin chloride of the type PC-4101 produced by Guangzhou Yuansu Chemical Co., Ltd.; the fiber reinforcement used is produced by Sichuan Tuoxin Research Institute with an area density of 424g / m 2 The basalt fiber woven cloth; the CBT resin used is the type CBT100 resin produced by Cyclics Company of the United States, and it is dried in an oven at 105 ° C for 10 h before use.

[0034] Step 1), attach the catalyst to the basalt fiber woven cloth, the specific operation is: pour the catalyst with a mass of 0.6% of the mass injected into the CBT resin into an appropriate amount of isopropanol solution, and use a magnetic stirrer to stir at 80°C for 10 minutes to make The catalyst is completely dissolved, brush the solution evenly on the fiber cloth, put it in an oven at 130°C, bake for 30 minutes, and turn the fiber woven cloth over halfway.

[0035] Step 2) Select a flat mold with a cavity thickness of 4mm, paste a high-temperature release...

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Abstract

The invention provides a vacuum-assisted resin diffusion molding method for a fiber-reinforced PBT composite material. The method comprises: attaching a catalyst onto fiber cloth; putting fiber-reinforced materials into a mold pasted with high-temperature demolding cloth and embedded with a high-temperature sealing strip; heating the mold to 180-220 DEG C, heating a resin injecting pipe to 180-220 DEG C by using a polytetrafluoroethylene heating pipe and heating CBT resin to 180-220 DEG C through oil bath; immersing a nozzle of the resin injecting pipe into melted CBT resin, with the CBT resin being injected into the mold under the effect of the vacuum; insulating the mold at 180-220 DEG C for 30-60 minutes so that the CBT resin can fully immerse the fiber-reinforced materials and meanwhile the CBT resin is subjected to ring-opening polymerization and crystallization into high-molecular-weight PBT; annealing and demolding to obtain the fiber-reinforced PBT composite material. The invention provides a high-performance and low-cost technology which can be used for preparation of thin-wall products and production of large-size composite material components.

Description

technical field [0001] The invention relates to a molding method of fiber-reinforced resin composite material, which is suitable for producing large-scale thermoplastic composite material components with high fiber content. Background technique [0002] In recent years, the research of continuous fiber reinforced thermoplastic resin matrix composites has been highly valued by aerospace industry and automobile manufacturing industry. Compared with thermosetting resin matrix composites, thermoplastic composites have many important advantages, such as better toughness and impact resistance, short molding cycle, low manufacturing cost, and waste can be recycled. However, due to the characteristics of the molecular structure of thermoplastic composite materials, thermoplastics are solid at room temperature; under heating and melting, the resin melt has a high viscosity (>1000Pa.s), and the melt flow is difficult, making it difficult for the resin to completely infiltrate the f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C70/34
Inventor 张璐周利民章继峰范绍华
Owner HARBIN ENG UNIV