Casting polypropylene protection film pressure-sensitive adhesive, casting polypropylene protection film and their preparation methods
A technology of casting polypropylene and protective film, which is applied in the direction of polyurea/polyurethane adhesives, adhesives, ester copolymer adhesives, etc., which can solve the problem of decreased cohesion of pressure-sensitive adhesives, poor high-temperature resistance of pressure-sensitive adhesives, and aggravated degumming problems and other problems, to achieve the effect of increasing molecular attraction, not easy to degumming, and easy to control
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Embodiment 1
[0038] 1. Preparation of pressure-sensitive adhesive for cast polypropylene protective film
[0039] 1) Weigh each component according to the following formula:
[0040]
[0041]
[0042] 2) First feed nitrogen into the reactor, discharge the air in the reactor, then add 460Kg of ethyl acetate, and raise the temperature to 78°C-80°C;
[0043] 3) Add the polymerized monomer in step 1) into the feeding kettle, and stir evenly; then take 1.6Kg of benzoyl peroxide, dissolve it with 60.4Kg of ethyl acetate, add it to the feeding kettle, and stir evenly to obtain a mixed prepolymer Monomer 460Kg;
[0044] 4) Add 92Kg of mixed pre-polymerized monomers into the reactor, and keep it warm for 30-40 minutes at 78°C-80°C;
[0045] 5) Add the remaining 368Kg of mixed pre-polymerized monomers to the reaction kettle dropwise, and finish the dropwise addition in 3 to 3.5 hours, keep the temperature at 78°C to 80°C, and keep warm for 1 to 1.5 hours after the dropwise addition;
[0046...
Embodiment 2
[0056] 1. Preparation of pressure-sensitive adhesive for cast polypropylene protective film
[0057] 1) Weigh each component according to the following formula:
[0058]
[0059] 2) First feed nitrogen into the reactor, discharge the air in the reactor, then add 460Kg of ethyl acetate, and raise the temperature to 78°C-80°C;
[0060] 3) Add the polymerized monomer in step 1) into the feeding kettle, and stir evenly; then take 1.6Kg of benzoyl peroxide, dissolve it with 60.4Kg of ethyl acetate, add it to the feeding kettle, and stir evenly to obtain a mixed prepolymer Monomer 460Kg;
[0061] 4) Add 92Kg of mixed pre-polymerized monomers into the reactor, and keep it warm for 30-40 minutes at 78°C-80°C;
[0062] 5) Add the remaining 368Kg of mixed pre-polymerized monomers to the reaction kettle dropwise, and finish the dropwise addition in 3 to 3.5 hours, keep the temperature at 78°C to 80°C, and keep warm for 1 to 1.5 hours after the dropwise addition;
[0063] 6) Dissolv...
Embodiment 3
[0073] 1. Preparation of pressure-sensitive adhesive for cast polypropylene protective film
[0074] 1) Weigh each component according to the following formula:
[0075]
[0076] 2) First feed nitrogen into the reactor, discharge the air in the reactor, then add 460Kg of ethyl acetate, and raise the temperature to 78°C-80°C;
[0077] 3) Add the polymerized monomer in step 1) into the feeding kettle, and stir evenly; then take 1.6Kg of azobisisobutyronitrile, dissolve it with 60.4Kg of ethyl acetate, add it to the feeding kettle, and stir evenly to obtain a mixed pre- Polymer 460Kg;
[0078] 4) Add 92Kg of mixed pre-polymerized monomers into the reactor, and keep it warm for 30-40 minutes at 78°C-80°C;
[0079] 5) Add the remaining 368Kg of mixed pre-polymerized monomers to the reaction kettle dropwise, and finish the dropwise addition in 3 to 3.5 hours, keep the temperature at 78°C to 80°C, and keep warm for 1 to 1.5 hours after the dropwise addition;
[0080] 6) Dissolv...
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