Heat vulcanization adhesive and preparation method thereof

An adhesive and thermal vulcanization technology, applied in the direction of adhesives, halogen rubber derivative adhesives, adhesive types, etc., can solve the problems of cumbersome process, low bonding strength and 90° peel strength, etc., and achieve simple construction technology, Enhanced adhesive strength and 90° peel strength, effects of high adhesive strength and 90° peel strength

Active Publication Date: 2014-01-22
ZHUZHOU TIMES NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to solve the problems in the prior art and provide a composition and preparation method of a phenolic / epoxy modified rubber metal thermal vulcanization adhesive; Relatively low bonding strength and 90°peel strength

Method used

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  • Heat vulcanization adhesive and preparation method thereof
  • Heat vulcanization adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] The dry weight of the thermally vulcanized adhesive in this embodiment is 100 parts by weight, and the solid content is 20% by weight.

[0049] The preparation method is as follows:

[0050] Step a: Weigh metal oxides (3 parts by weight ZnO, 10 parts by weight MgO and 2 parts by weight TiO 2 ) and solid inert filler (10 parts by weight of ceramic microspheres, 6 parts by weight of silicon dioxide and 3 parts by weight of carbon black), the above components were placed in an oven and dried at 60 ° C for 24 hours;

[0051] Step b: Add the mixed solvent into the mixer, add 1.5 parts by weight of wetting / dispersing agent and 2.5 parts by weight of adhesion promoter (chlorinated polyolefin); wherein the mixed solvent is a mixture of xylene and acetone, xylene: Acetone=2:1 (weight ratio);

[0052] Step c: Add the phenolic / epoxy component and the first accelerator component (10 parts by weight bisphenol A type novolac epoxy resin, 10 parts by weight tetrahydrophthalate bisgl...

Embodiment 2

[0058] The dry weight of the thermally vulcanized adhesive in this embodiment is 100 parts by weight, and the solid content is 30% by weight.

[0059] The preparation method is the same as in Example 1, wherein the phenolic / epoxy component and the first accelerator component (15 parts by weight of tetraglycidyl-4,4'-diaminodiphenylmethane, 15 parts by weight of allyl bisphenol A-type ring Oxygen resin, 2.5 parts by weight octylphenolic tackifying resin, 7.5 parts by weight brominated octylphenolic vulcanization resin and 2.0 parts by weight 2-ethyl-4-methylimidazole); halogenated polyolefin and co-vulcanization components (15 parts by weight Chlorinated natural rubber S170, 15 parts by weight of chlorosulfonated natural rubber CSM30 type, 1 part by weight of DCP and 0.5 parts by weight of Qiulan parent accelerator); metal oxide (5 parts by weight of ZnO, 5 parts by weight of MgO and 2 parts by weight of TiO 2 ); solid inert filler (5 parts by weight of ceramic microspheres, 5...

Embodiment 3

[0064] The dry weight of the thermal vulcanization adhesive in this embodiment is 100 parts by weight, and the solid content is 40% by weight.

[0065] The preparation method is the same as in Example 1, wherein the novolac epoxy component and the first accelerator component (20 parts by weight of o-cresol type novolak epoxy resin, 10 parts by weight of tetrahydrophthalic acid diglycidyl ester, 5 parts by weight of terpene phenolic tackifying resin, 5 parts by weight brominated octyl phenolic vulcanization resin and 2.0 parts by weight 2-methylimidazole); halogenated polyolefin and co-vulcanization components (15 parts by weight chlorinated natural rubber S170 and 15 parts by weight neoprene A -90 type, 1.5 parts by weight of BIPB and 0.5 parts by weight of bismaleimide); metal oxides (5 parts by weight of ZnO, 5 parts by weight of MgO and 5 parts by weight of TiO 2 ); solid inert filler (2.5 parts by weight of ceramic microspheres, 5 parts by weight of aluminum oxide and 1 pa...

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Abstract

The invention relates to a heat vulcanization adhesive. The heat vulcanization adhesive comprises a solvent and solid components; on the calculation basis of 100 parts by weight of the solid components, the solid components comprise 30-45% by weight of phenol aldehyde / epoxy component, preferably 35-40% by weight; 1-2.5 parts by weight of first accelerator; 20-30% by weight of halogenated polyolefin, preferably 25-30% by weight; 1-2% by weight of co-vulcanization component; 10-15% by weight of metal oxide; 2-5% by weight of adhesion promoter; 1-2 parts by weight of wetting / dispersing agent; and the balance of inert filler. The invention further provides a preparation method of the heat vulcanization adhesive.

Description

technical field [0001] The invention relates to the field of adhesives, in particular to a phenolic / epoxy modified rubber-metal thermal vulcanization adhesive and a preparation method thereof. Background technique [0002] With the rapid development of the rubber industry, rubber composite materials are widely used in petrochemical, construction, transportation and other industrial fields by combining the high elasticity of rubber and the high strength of metal. Among them, the quality of rubber and metal adhesives is the key to the success of composite materials. The key is that with the increase in the types of composite products and the expansion of application fields, the requirements for bonding technology are becoming more and more stringent. The traditional chlorinated rubber method, isocyanate method and other technologies have been eliminated, and the mainstream products are chemlok, Thxion (Rohm and Haas), vulcanized rubber-metal adhesives from Sibang, England, whi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J161/06C09J115/02C09J123/34C09J123/28C09J11/04C09J11/06
Inventor 李鸿岩曾智姚智平董洪海姜其斌
Owner ZHUZHOU TIMES NEW MATERIALS TECH
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