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Graphene oxide reinforced vinyl ester composite material and preparation method thereof

A technology of composite material and vinyl ester, which is applied in the field of graphene oxide reinforced vinyl ester composite material and its preparation, can solve the problems such as ambiguity of graphene oxide monolithic peeling, and achieve the effect of improving stretching

Inactive Publication Date: 2014-01-29
JIANGSU ZHAOJUN NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the past 10 years, there have been a large number of reports on the composite of GO and various substrates at home and abroad, but it is not clear whether graphene oxide can achieve single-sheet exfoliation, and it can only be called GO / polymer intercalation composite material.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of graphene oxide (GO) reinforced vinyl ester composite material, its raw material composition is by weight fraction:

[0028] Vinyl 20

[0029] Fiberglass 20

[0030] GO 5

[0031] low profile agent 8

[0032] Inorganic mineral filler 40

[0033] thickener 2

[0034] Release agent 3

[0035] Hardener 2

[0036] Among them: the vinyl resin is epoxy vinyl resin; the glass fiber is treated with a silane-based coupling agent; the low-profile agent is PVAc; the inorganic mineral filler is aluminum hydroxide; the curing agent is TBPB or TBPB and TBPO composite initiation system, Wherein the weight ratio of TBPB / TBPO is 0.7 / 0.3; the release agent is zinc stearate.

[0037] Concrete preparation steps are as follows:

[0038] (1) Disperse GO in anhydrous ethanol solvent, vibrate for 1h with ultrasonic to further exfoliate it into a single sheet of graphene oxide, then add vinyl ester r...

Embodiment 2

[0045] A kind of graphene oxide (GO) reinforced vinyl ester composite material, its raw material composition is by weight fraction:

[0046] Vinyl 20

[0047] Fiberglass 20

[0048] GO 10

[0049] low profile agent 8

[0050] Inorganic mineral filler 40

[0051] thickener 2

[0052] Release agent 3

[0053] Hardener 2

[0054] Among them: the vinyl resin is epoxy vinyl resin; the glass fiber is treated with a silane-based coupling agent; the low-profile agent is PVAc; the inorganic mineral filler is aluminum hydroxide; the curing agent is TBPB or TBPB and TBPO composite initiation system, Wherein the weight ratio of TBPB / TBPO is 0.7 / 0.3; the release agent is zinc stearate.

[0055] Concrete preparation steps are as follows:

[0056] (1) Disperse GO in anhydrous ethanol solvent, vibrate for 1h with ultrasonic to further exfoliate it into a single sheet of graphene oxide, then add vinyl est...

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Abstract

The invention discloses a graphene oxide reinforced vinyl ester composite material and a preparation method thereof. The graphene oxide reinforced vinyl ester composite material disclosed by the invention comprises vinyl ester resin, glass fibre, graphene oxide powder, a low profile agent, a thickener, inorganic mineral filler and a curing agent. The graphene oxide reinforced vinyl ester composite material disclosed by the invention has excellent composite performances by utilizing the huge specific surface area of graphene oxide and the abundant functional groups on the surface; graphene oxide and a resin-based composite material are composited, and therefore, the performances in the aspects of heat, force, electric and the like of the material can be obviously improved. The composite material disclosed by the invention is in the form of a sheet moulding compound; the adopted forming process is compression moulding forming or injection forming; the preparation method disclosed by the invention is simple and easy to implement.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a graphene oxide reinforced vinyl ester composite material and a preparation method thereof. Background technique [0002] In the past 10 years, there have been a large number of reports on the composite of GO and various substrates at home and abroad, but it is not clear whether graphene oxide can achieve single-sheet exfoliation, and it can only be called GO / polymer intercalation composite materials. After 2004, with the confirmation of the stable existence of graphene monoliths in ordinary environments, and the mature application of mechanical exfoliation of GO to prepare graphene oxide, the synthesis of graphene oxide / polymer nanocomposites was truly realized. . [0003] Similar to single-walled carbon nanotubes (SWCNTs), graphene has excellent thermal, mechanical, and electrical properties. However, it is difficult for polymer molecules to enter the inner surface of SWC...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/10C08L31/04C08L25/06C08L33/12C08K13/06C08K9/06C08K7/14C08K3/04C08K3/26C08K3/22C08K3/34C08K5/098
Inventor 鲁平才魏涛赵钎
Owner JIANGSU ZHAOJUN NEW MATERIAL CO LTD
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