Undercoating layer for plating process, laminated board for wiring board and its manufacturing method, multilayer wiring board and its manufacturing method
一种底涂层、布线板的技术,应用在涂层、印刷电路制造、金属材料涂层工艺等方向,能够解决绝缘材料与铜粘接性不足等问题,达到高焊料耐热性、高粘接性的效果
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[0120] Next, the present invention will be specifically described by way of examples, but the scope of the present invention is not limited to these examples.
[0121] [Preparation of resin varnish for undercoating in plating process]
preparation example 1
[0123] N,N-Dimethylacetamide (DMAc) was mixed with 0.75 g of phenolic hydroxyl group-containing polybutadiene-modified polyamide (manufactured by Nippon Kayaku Co., Ltd., trade name: BPAM-155) as component (C). After 6.75 g, add 10 g of biphenyl aralkyl type epoxy resin (manufactured by Nippon Kayaku Co., Ltd., trade name: NC-3000H) as (A) component, cresol novolak type phenolic resin (DIC) as (B) component Manufactured by the company, trade name: KA-1165) 4.1 g, and after adding 0.1 g of 2-phenylimidazole (manufactured by Shikoku Chemical Industry Co., Ltd., trade name: 2PZ) as a curing accelerator, use a mixed solvent containing DMAc and methyl ethyl ketone. It was diluted to obtain a resin varnish A for an undercoat layer for a plating process (solid content concentration: about 25% by mass).
preparation example 2
[0125] N,N-Dimethylacetamide (DMAc) was mixed with 1.5 g of phenolic hydroxyl group-containing polybutadiene-modified polyamide (manufactured by Nippon Kayaku Co., Ltd., trade name: BPAM-155) as component (C). After 13.5 g, add 10 g of biphenyl aralkyl type epoxy resin (manufactured by Nippon Kayaku Co., Ltd., trade name: NC-3000H) as (A) component, novolak type phenol resin (manufactured by DIC Corporation) as (B) component , trade name: TD-2090) 3.6g, 2-phenylimidazole (manufactured by Shikoku Chemical Industry Co., Ltd., trade name: 2PZ) 0.1g, fumed silica (manufactured by Japan AEROSIL Corporation, trade name) as a curing accelerator : R972) after 0.9 g, was diluted with a mixed solvent containing DMAc and methyl ethyl ketone (solid content concentration: about 25% by mass). Subsequently, a uniform resin varnish B for an undercoat layer for a plating process was obtained using a disperser (Nanomizer, trade name, manufactured by Yoshida Kikuyo Co., Ltd.).
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