Molded body for dental use
A molding and dental technology, applied in the direction of dental prosthesis, dentistry, dental preparations, etc., can solve unknown problems and achieve the effects of easy bending, excellent impact resistance, and good formability
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Embodiment 1
[0033] Example 1: Synthesis example of polyester resin constituting the dental molding of the present invention
[0034]In a 500ml flask equipped with a nitrogen injection port, a metal stirrer and a short distillation column, 77.7g of dimethyl terephthalate, 48.5g of 1,4-cyclohexanedimethanol, 2,2,4,4- A mixture of 17.9 g of tetramethyl-1,3-cyclobutanediol and 0.046 g of dibutyltin oxide. The flask was placed in a Wood metal bath which had been heated to 210°C. The stirring speed was set at 200 RPM throughout the experiment. The contents of the flask were heated at 210°C for 5 minutes, then the temperature was slowly raised to 290°C over 30 minutes. The reaction mixture was kept at 290° C. for 60 minutes, and then vacuum was slowly drawn over 5 minutes after the pressure inside the flask reached 100 mmHg. Then, the pressure inside the flask was further lowered to 0.3 mmHg over 5 minutes. The pressure of 0.3 mmHg was maintained for a total of 90 minutes to remove excess un...
Embodiment 2
[0035] Embodiment 2: physical property comparative experiment
[0036] Various physical property comparison experiments were carried out between the polyester resin constituting the dental molded article of the present invention and conventionally used resins (polyamide resin, polyester resin, and polycarbonate resin). The resins used in the experiments are as follows.
[0037] Product of the present invention: the polyester resin produced in the above-mentioned Example 1
[0038] Existing product 1: Polyamide resin (commercially available thermoplastic resin for denture bases)
[0039] Existing product 2: Polyester resin (commercially available thermoplastic resin for denture bases)
[0040] Existing product 3: Polycarbonate resin (commercially available thermoplastic resin for denture bases)
[0041] 1. Bending strength, bending modulus of elasticity test
[0042] Using the resins of the present invention and conventional products 1 to 3, test bodies conforming to ISO207...
Embodiment 3
[0084] Example 3: Specific examples of the dental molding of the present invention (1) Aesthetic dentures
[0085] A material in which 0.015 parts by weight of titanium oxide, 0.0005 parts by weight of solvent red 151, 0.002 parts by weight of red iron, and 0.001 parts by weight of black iron oxide were mixed with 100 parts by weight of the polyester resin produced in Example 1 above was prepared. The mixture is molded with a dental injection molding machine to produce denture bases for aesthetic dentures.
[0086] It was confirmed that the denture base produced in this way has moderate flexibility, is not easy to break, is also excellent in impact resistance, and has no problem at all when it is mounted and used by a patient.
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Abstract
Description
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