Preparation method of carbon nano tube-reinforced aluminum base composite material

A carbon nanotube and aluminum-based technology, applied in the field of aluminum-based composite materials, can solve the problems of high process parameter requirements, complicated process operation, and carbon nanotubes are not easy to embed, so as to avoid difficult sintering, tensile strength and wear resistance. Sex-enhancing effect

Active Publication Date: 2014-03-05
STATE GRID CORP OF CHINA +3
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  • Abstract
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  • Application Information

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Problems solved by technology

[0006] In the invention patent with the publication number CN101864547A, the carbon nanotubes are acidified, soaked for 40-50 hours, and a surfactant is added to try to improve the dispersibility of the carbon nanotubes. However, due to the long acidification time, the surface of the carbon nanotubes The structure has been severely damaged, which is not conducive to the performance of its own performance
[0007] In the invention patent with the publication number CN1730688, carbon nanotube-reinforced aluminum matrix composites were prepared by in-situ reaction of vapor deposition, but the process operation is cumbersome, and the requirements for process parameters are high, which is not conducive to large-scale industrial production
[0008] The invention patent with the publi...

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  • Preparation method of carbon nano tube-reinforced aluminum base composite material

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Effect test

Embodiment 1

[0030] like figure 1 As shown, the preparation method of carbon nanotube-reinforced aluminum matrix composites is as follows:

[0031] 1) The carbon nanotubes are uniformly dispersed in N-methylpyrrolidone by ultrasonic vibration, and polyvinylidene fluoride is added and mixed to obtain a carbon nanotube dispersion liquid. The weight percentage of carbon nanotubes in the carbon nanotube dispersion liquid is 10%. The weight ratio of vinylidene fluoride to carbon nanotubes is 4:1;

[0032] 2) Mix the carbon nanotube dispersion with the pure aluminum powder evenly, then dry at 150 °C for 3 hours under vacuum conditions to volatilize the N-methylpyrrolidone to obtain a mixture. The weight of the carbon nanotubes in the mixture accounts for the pure aluminum powder. 10% by weight;

[0033] 3) Under the protection of inert gas, the mixture is ball-milled at 500rpm for 3h, the ratio of ball to material is 10:1, and the carbon nanotubes are completely embedded in the inside of the a...

Embodiment 2

[0036] 1) The carbon nanotubes are uniformly dispersed in toluene by ultrasonic vibration to obtain a carbon nanotube dispersion liquid, and the weight percentage of carbon nanotubes in the carbon nanotube dispersion liquid is 1%;

[0037] 2) Mix the carbon nanotube dispersion with the pure aluminum powder evenly, then dry at 150°C for 3 hours under vacuum conditions to volatilize the toluene to obtain a mixture, and the weight of the carbon nanotubes in the mixture accounts for 1% of the weight of the pure aluminum powder;

[0038] 3) Under the protection of inert gas, the mixture is ball-milled at 600rpm for 2h, the ratio of ball to material is 10:1, and the carbon nanotubes are completely embedded in the inside of the aluminum powder particles, so that the aluminum powder particles are exposed to the fresh surface;

[0039] 4) The ball-milled mixture is successively processed by cold pressing at a pressing pressure of 300 MPa, normal pressure sintering at 550 °C, hot-pressin...

Embodiment 3

[0041] 1) Disperse carbon nanotubes uniformly in ethanol by ultrasonic vibration, add sodium dodecyl sulfate and mix to obtain carbon nanotube dispersion liquid, the weight percentage of carbon nanotubes in carbon nanotube dispersion liquid is 8%, dodecane The weight ratio of sodium sulfate and carbon nanotubes is 3:1;

[0042] 2) Mix the carbon nanotube dispersion liquid with the pure aluminum powder evenly, and then dry it at 120°C for 4 hours under vacuum conditions to volatilize the ethanol to obtain a mixture. The weight of the carbon nanotubes in the mixture accounts for 8% of the weight of the pure aluminum powder;

[0043] 3) Under the protection of inert gas, the mixture is ball-milled at 500rpm for 6h, the ratio of ball to material is 15:1, and the carbon nanotubes are completely embedded in the inside of the aluminum powder particles, so that the aluminum powder particles are exposed to the fresh surface;

[0044]4) The ball-milled mixture is successively processed ...

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Abstract

The invention discloses a preparation method of a carbon nano tube-reinforced aluminum base composite material. The preparation method comprises the following steps: (1), uniformly dispersing carbon nano tubes into a dispersant which has chemical inertness on pure aluminum powder or aluminum alloy powder to obtain carbon nano tube dispersion liquid; (2), uniformly mixing the carbon nano tube dispersion liquid with the pure aluminum powder or the aluminum alloy powder, and drying to remove the dispersant to obtain a material mixture; (3), carrying out ball-milling onto the material mixture under protection of inert gases; and (4), carrying out cold pressing, normal-pressure sintering, hot-pressing and densifying under an atmospheric environment and hot-extrusion forming onto the ball-milled material mixture in sequence to obtain the carbon nano tube-reinforced aluminum base composite material. The preparation method disclosed by the invention further can reinforce the aluminum base body by utilizing co-action of base body processing and hardening, crystalline grain fining and reinforcing while bringing the excellent mechanical performances of the carbon nano tubes into play to reinforce the aluminum base body, so that tensile strength and wear resistance of the composite material are greatly improved; moreover, the carbon nano tube-reinforced aluminum base composite material with excellent performances can be industrially produced on a large scale.

Description

technical field [0001] The invention relates to an aluminum-based composite material, in particular to a preparation method of a carbon nanotube-reinforced aluminum-based composite material. Background technique [0002] The density of pure aluminum is small, ρ=2.7g / cm 3 , about 1 / 3 of iron, low melting point (660 ° C), aluminum is a face-centered cubic structure, so it has high plasticity and is easy to process, and can be made into various profiles and plates. The corrosion resistance of pure aluminum is good; but the strength of pure aluminum is low, and the σb value of the annealed state is about 8kgf / mm 2 , so it is not suitable for structural materials. Aluminum alloy has low density, but relatively high strength, close to or surpassing high-quality steel, good plasticity, can be processed into various profiles, has excellent electrical conductivity, thermal conductivity and corrosion resistance, widely used in industry, second only to steel . [0003] Aluminum all...

Claims

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Application Information

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IPC IPC(8): C22C47/14C22C49/06C22C49/14C22C101/10
Inventor 张广洲李清文王利民陈名海姚辉陈胜男
Owner STATE GRID CORP OF CHINA
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