Method for rapidly evaluating adsorption effect of porous filter tip additive

An additive and porosity technology, which is applied in the field of rapid evaluation of the adsorption effect of porous filter additives, can solve the problems of large waste, high cost, inconsistent filter adding methods (evenly distributed in acetate fibers, etc.), and achieve high test sensitivity and operation Simple, step-saving and cost-effective

Inactive Publication Date: 2014-03-05
CHONGQING CHINA TOBACCO IND CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The commonly used evaluation method is to detect the release of harmful components in the smoke, that is, by adding filter tip additives directly to the filter rod to make a composite tip, and then roll it into finished cigarettes, and analyze the harmful components of the smoke. However, in the current domestic actual production process, it often requires kilograms of materials to roll the prepared filter additives into cigarettes, and the cost is high and wasteful in the trial production process, which also affects the normal production of enterprises.
Patents CN200982968Y and CN201429591Y disclose the cigarette filter additive simulation smoke harm reduction effect evaluation device. The principle is to add a piece of filter material between the cigarette and the smoke catcher to evaluate the adsorption performance of the filter material, but this The addition method simulated by this device is inconsistent with the "Dalmatian" filter addition method currently used in the production of tobacco enterprises in my country (evenly distributed in the acetate fiber)
In addition, adding a piece of filter material often has a local physical blocking effect on smoke that is greater than the adsorption performance of the material itself, so it is not possible to accurately evaluate the adsorption effect of the adsorption material itself

Method used

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  • Method for rapidly evaluating adsorption effect of porous filter tip additive
  • Method for rapidly evaluating adsorption effect of porous filter tip additive
  • Method for rapidly evaluating adsorption effect of porous filter tip additive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The toxic substance is n-butyraldehyde, and the porous filter additives to be evaluated are powdered additive 1 (molecular sieve), additive 2 (molecular sieve), and additive 3 (micro-medium composite porous material).

[0028] (1) Preliminary degassing of additives: Weigh 150-200 mg of the above three additives and degas at 180°C overnight with a specific surface area meter to preliminarily remove the impurity gases in the filter additives.

[0029] (2) Transfer 5-15ml of n-butyraldehyde liquid to the vaporization storage tank, weigh 50-100mg of the filter additive after preliminary degassing treatment, and install it into the quartz hanging basket of the intelligent weight absorption instrument.

[0030] (3) Secondary degassing: Heat the sample to 180°C through the external heating device, keep it for 4 hours, and use the vacuum pump to further remove the residual impurity gas in the additive.

[0031] (4) Adsorption: According to the saturated vapor pressure of the selected or...

Embodiment 2

[0042] The toxic substance is selected as benzene, and the filter additives to be evaluated are powdered additive 4 (molecular sieve) and additive 5 (micro-mesoporous material) for their adsorption effect on benzene series.

[0043] (1) Preliminary degassing of additives: Weigh 150-200 mg of the above two additives respectively, and degas at 180°C overnight with a surface area meter to preliminarily remove the impurity gases in the filter additives.

[0044] (2 Transfer 5-15ml of benzene liquid to the vaporization storage tank, weigh 50-100mg of the filter additive after preliminary degassing treatment, and install it into the quartz hanging basket of the intelligent weight absorption meter.

[0045] (3) Secondary degassing: Heat the sample to 180°C through an external heating device, keep it for 4 hours, and use a vacuum pump to further remove the residual impurity gas in the additive.

[0046] (4) Adsorption: According to the saturated vapor pressure of the selected organic liquid or...

Embodiment 3

[0056] The toxic substance is selected as CO, and the filter additives to be evaluated are powdered additive 6 (molecular sieve) and additive 7 (micro-mesoporous material) for the adsorption effect of CO.

[0057] (1) Preliminary degassing of additives: Weigh 150-200 mg of the above two additives respectively, and degas at 180°C overnight with a surface area meter to preliminarily remove the impurity gases in the filter additives.

[0058] (2) Connect the CO gas bottle to the intelligent adsorption instrument, weigh 50-100mg of the filter additive after preliminary degassing treatment, and install it into the quartz hanging basket of the intelligent weight absorption instrument.

[0059] (3) Secondary degassing: Heat the sample to 180°C through the external heating device, keep it for 4 hours, and use the vacuum pump to further remove the residual impurity gas in the additive.

[0060] (4) Adsorption: According to the saturated vapor pressure of the selected gas, 27 test pressure point...

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Abstract

The invention discloses a method for rapidly evaluating the adsorption effect of a porous filter tip additive. The method comprises the following steps: degassing the additive through a specific surface area analyzer overnight at 80-180 DEG C to primarily remove impurity gases in the porous additive; transferring an organic liquid into a vaporization storage tank for vaporizing, connecting the organic liquid to a weight absorption instrument, or directly connecting a poisonous gas to the weight absorption instrument, weighing the primarily degassed additive and filling the additive in a quartz hanging basket of the weight absorption instrument; degassing the additive for the second time; setting 10-30 test pressure points according to the saturated vapor pressure of the organic liquid or the poisonous gas, respectively carrying out saturation adsorption on different pressure points through the weight absorption instrument, and drawing an adsorption curve graph; and analyzing according to the obtained adsorption curve graph to obtain the adsorbing capacity and the adsorption tendency change of the type of additives in low pressure regions. The method is high in test sensitivity, simple and convenient to operate and capable of accurately evaluating the adsorption effects of different filter tip additives on harmful substances.

Description

Technical field [0001] The invention belongs to the field of cigarette production, and specifically relates to a method for quickly evaluating the adsorption effect of porous filter tip additives. Background technique [0002] With the progress of society, smoking and environmental issues have attracted worldwide attention. The "Framework Convention on Tobacco Control" requires governments to formulate stricter "tobacco control" laws and regulations, prompting cigarette manufacturers to strictly control the release of major harmful components in cigarette smoke while reducing the release of cigarette tar. Nowadays, relevant tobacco companies and research institutions continue to develop various new materials every year, and try to apply new materials to cigarettes. Among them, porous materials have been widely concerned because of their large specific surface area and abundant pores. The convenient, fast and efficient evaluation of the effect of such materials on the absorption ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N5/02
Inventor 戴亚俞海军汪长国马扩彦孙玉峰
Owner CHONGQING CHINA TOBACCO IND CO LTD
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