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Storage battery electrode plate acid spraying and preparation method thereof

A battery and acid-leaching technology, which is applied in the direction of lead-acid battery electrodes, electrode manufacturing, chemical electrode manufacturing, etc., can solve the problems that lead sulfate is not easy to charge, increase resistance, etc., to improve charging acceptance, reduce energy consumption, and improve The effect of cycle life

Active Publication Date: 2014-03-19
HENAN CHAOWEI POWER SUPPLY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the existing products are internally formed into batteries. If the acid density is too high, it will not be easy to charge the lead sulfate on the surface of the battery board that is subsequently assembled, which means that the dead paste is not conductive and increases the resistance.

Method used

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  • Storage battery electrode plate acid spraying and preparation method thereof
  • Storage battery electrode plate acid spraying and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The present embodiment accumulator electrode plate leaching acid, comprises positive plate leaching acid and negative plate leaching acid, and described positive plate leaching acid comprises the following raw materials in parts by weight: 0.8 part of sodium carboxymethyl cellulose, 0.5 part of polyethylene glycol, sulfuric acid 1 part of sodium, 0.1 part of stannous sulfate, 4 parts of sulfuric acid, and 93.6 parts of water; the negative plate leaching acid includes the following raw materials in parts by weight: 0.8 part of sodium carboxymethyl cellulose, 0.5 part of polyethylene glycol, 1 part of sodium sulfate 0.1 part of stannous sulfate, 8 parts of analytically pure concentrated sulfuric acid, and 88.6 parts of water.

[0033] The acid density of the positive plate in this embodiment is 1.025 g / cm 3 , the acid density of the negative plate is 1.052 g / cm 3 In high temperature seasons, the plate loses water quickly and should adopt this embodiment.

Embodiment 2

[0035] The present embodiment accumulator pole plate leaching acid, comprises positive plate leaching acid and negative plate leaching acid, and described positive plate leaching acid comprises the following raw materials in parts by weight: 0.3 part of sodium carboxymethyl cellulose, 1 part of polyethylene glycol, sulfuric acid 0.5 part of sodium, 0.3 part of stannous sulfate, 5 parts of sulfuric acid, and 92.9 parts of water; the negative plate leaching acid comprises the following raw materials in parts by weight: 0.3 part of sodium carboxymethylcellulose, 1 part of polyethylene glycol, 0.5 part of sodium sulfate 0.3 parts of stannous sulfate, 10 parts of sulfuric acid, and 87.9 parts of water. The sulfuric acid is analytically pure concentrated sulfuric acid with a weight concentration of 96-99%.

[0036] The acid density of the positive plate in this embodiment is 1.032g / cm 3 , the acid density of the negative plate is 1.061 g / cm 3 , The powder falling off the board sur...

Embodiment 3

[0038]The present embodiment accumulator plate leaching acid, comprises positive plate leaching acid and negative plate leaching acid, and described positive plate leaching acid comprises the following raw materials in parts by weight: 0.5 part of sodium carboxymethyl cellulose, 0.7 part of polyethylene glycol, sulfuric acid 2 parts of sodium, 0.2 part of stannous sulfate, 4.5 parts of sulfuric acid, 93.1 parts of water; the negative plate leaching acid comprises the following raw materials in parts by weight: 0.5 part of sodium carboxymethyl cellulose, 0.7 part of polyethylene glycol, 2 parts of sodium sulfate Parts, 0.2 parts of stannous sulfate, 12 parts of sulfuric acid, 84.6 parts of water. The sulfuric acid is analytically pure concentrated sulfuric acid with a weight concentration of 96-99%, wherein Fe content (weight) ≤ 0.0005%, Cl content (weight) ≤ 0.0005%, KMnO 4 Content (weight) ≤ 0.001%.

[0039] The acid density of the positive plate in this embodiment is 1.028 ...

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Abstract

The invention belongs to the technical field of storage battery manufacturing, and specifically relates to a lead acid storage battery electrode plate acid spraying and a preparation method thereof. The electrode plate acid spraying comprises positive electrode plate acid spraying and negative electrode plate acid spraying, wherein the positive electrode plate acid spraying is composed of the following raw materials in parts by weight: 0.3 to 0.8 part of sodium carboxymethyl cellulose, 0.5 to 1 part of polyethylene glycol, 0.5 to 2 parts of sodium sulfate, 0.1 to 0.5 part of stannous sulfate, 3.2 to 7.7 parts of sulfuric acid, and 88 to 94.9 parts of water; and the negative electrode plate acid spraying is composed of the following raw materials in parts by weight: 0.3 to 0.8 part of sodium carboxymethyl cellulose, 0.5 to 1 part of polyethylene glycol, 0.5 to 2 parts of sodium sulfate, 0.1 to 0.5 part of stannous sulfate, 7.7 to 14.7 parts of sulfuric acid, and 81 to 90.4 parts of water. The storage battery electrode plate acid spraying can control the acid spraying density, and at the same time prominently improves the storage battery properties of recharging, over-discharging, low-temperature capacity, and service life.

Description

technical field [0001] The invention belongs to the technical field of storage battery manufacturing, and in particular relates to a lead-acid storage battery polar plate soaking acid and a preparation method thereof. Background technique [0002] In the production process of the lead-acid battery plate, after the plate is coated, the plate surface needs to be soaked in acid and rolled. Adding additives in the acid bath can increase the amount of lead paste on the plate, so that the strength of the lead paste on the surface of the plate is improved, and the surface of the plate is The content of lead sulfate is low, the generation of lead sulfate is inhibited during the battery discharge process, and the conductivity of the lead paste on the surface of the plate is improved, so as to improve the overall performance of the battery. [0003] Coated board dipping acid production line (see figure 1 ): 1-1 is the plate coating machine and lead paste storage bucket; 1-2 is the co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/20H01M4/16
CPCY02E60/126H01M4/049H01M4/20Y02E60/10
Inventor 李松林柴成雷
Owner HENAN CHAOWEI POWER SUPPLY
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