Waste copper sulfate electrolyte purification system and method

A technology for waste electrolyte and purification system, which is applied to the purification system of copper sulfate waste electrolyte and the purification field of copper sulfate waste electrolyte, which can solve the problem of decreased heat exchange efficiency of heat exchangers, scaling of plate heat exchangers, water-containing and acid-containing solutions It can ensure the safety of equipment, reduce water and acid content, and improve product quality.

Inactive Publication Date: 2014-04-09
BAIYIN NONFERROUS GROUP
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Problems solved by technology

[0004] (1) Due to the high content of impurities in the waste electrolyte, the fouling problem of the plate heat exchanger is quite serious, resulting in a serious decrease in the heat exchange efficiency of the heat exchanger, and a large number of flakes of calcium, bismuth, tellurium and other compounds can be seen when the plate is clean

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  • Waste copper sulfate electrolyte purification system and method
  • Waste copper sulfate electrolyte purification system and method

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Embodiment Construction

[0015] Such as figure 1 As shown, a copper sulfate waste electrolyte purification system includes a waste electrolyte storage tank 1, a waste electrolyte pump 2, a plate filter 3, a filter waste liquid storage tank 4, a filter waste liquid pump 5, and a plate filter connected in sequence. Heater 6, vacuum evaporator group 7, copper sulfate water-cooled crystallization tank 8, belt filter 9 and suction filter tank 10; There is an orifice plate 1002, which divides the tank body into a material chamber 1003 and a suction filter chamber 1004 arranged in an upper and lower position. The filter cloth (not shown in the figure) is laid on the orifice plate 1002, and the suction filter chamber 1004 is connected to a vacuum pump. 11. Vacuum pump 11 is preferably a water ring vacuum pump.

[0016] A method for purifying copper sulfate waste electrolyte by using the above system, the specific steps are: pump the waste electrolyte stored in the waste electrolyte storage tank 1 into th...

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Abstract

The invention provides a waste copper sulfate electrolyte purification system and a waste copper sulfate electrolyte purification method realized by using the system. The system comprises a waste electrolyte storage tank, a waste electrolyte pump, a plate filter, a waste filtrate storage tank, a waste filtrate pump, a plate heat exchanger, a vacuum evaporator set, a copper sulfate water cooling crystallization tank, a belt filter and a suction filtration tank which are sequentially connected, wherein the suction filtration tank comprises a tank body; the upper part of the tank body is opened; the middle of the tank body is provided with a pore plate; the tank body is partitioned into a material chamber and a suction filtration chamber by the pore plate; filter cloth covers on the pore plate; the suction filtration chamber is connected with a vacuum pump. According to the invention, devices such as the plate heat exchanger and the like are not easy to scale, so that the safety use of the equipment is ensured; meanwhile, waste electrolyte entering the vacuum evaporator set is low in impurity content, so that the purity of a final product is improved; secondary suction filtration is realized by the suction filtration tank, so that the water and acid contents of a copper sulfate crystal product are effectively reduced, and the quality of the product is improved.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and relates to a copper sulfate waste electrolyte purification system and a copper sulfate waste electrolyte purification method using the system. Background technique [0002] During the copper electrolytic refining process, the composition of the electrolyte is constantly changing, the concentration of copper ions is constantly increasing, and impurities are constantly accumulating, while the concentration of sulfuric acid is gradually decreasing. In order to produce qualified quality cathode copper, the concentrations of copper ions, sulfuric acid and impurities in the electrolyte are maintained at Within the specified range, the electrolyte must be purified to remove excess copper and impurities. At present, most of the electrolyte purification adopts the following process: extract a part of the electrolyte or waste electrolyte for evaporation and concentration, and crystallize through coo...

Claims

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Application Information

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IPC IPC(8): C25C7/06C01G3/10C02F9/10
Inventor 赵宇飞郭树东王玮栾辉李学国蔺桃德
Owner BAIYIN NONFERROUS GROUP
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