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A low odor, antistatic glass fiber reinforced AS composition and preparation method thereof

An antistatic, low-odor technology, applied in the field of antistatic glass fiber reinforced AS composition and its preparation, and low-odor, can solve the problems of mechanical property impact of AS alloy material, explosion and fire of chemical product warehouse, material adsorption of dust, etc., to achieve Effects of improving mechanical strength, low emission, and low odor

Active Publication Date: 2016-08-17
TIANJIN KINGFA NEW MATERIAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these additives have a great influence on the mechanical properties of AS alloy materials, especially the impact
[0007] The above-mentioned methods solve the odor problem of the material to varying degrees. However, the above-mentioned method is only aimed at the influence of a certain component on the odor, thereby adding an adsorbent to reduce the odor. result of action
Moreover, since AS material is a poor conductor of electricity, it is easy to accumulate static charge during processing and use. When the static charge accumulates to a certain extent, static electricity will cause the material to absorb dust, cause material damage, and may also generate static spark discharge, causing The chemical product warehouse exploded and caught fire, causing major personal accidents

Method used

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  • A low odor, antistatic glass fiber reinforced AS composition and preparation method thereof
  • A low odor, antistatic glass fiber reinforced AS composition and preparation method thereof
  • A low odor, antistatic glass fiber reinforced AS composition and preparation method thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0048] Preparation of jellyfish pellets:

[0049] Fully mix high-melt-strength polypropylene with different melt strengths and mineral fillers according to the ratio shown in Table 1, extrude strip-shaped polypropylene in the extruder, and then chop it into polypropylene pre-foaming Particles; using water as a foaming agent, the polypropylene pre-expanded particles are expanded to prepare expanded polypropylene with high melt strength; the expanded polypropylene with high melt strength and water are mixed in a high-speed mixer 5-10min, prepare jellyfish pellets with the water content shown in Table 1, and release them for use.

[0050] Table 1 The content of each component of jellyfish pellets (weight percent)

[0051]

Embodiment 1-4

[0053] A kind of low odor, antistatic glass fiber reinforced AS composition, its raw material formula is as shown in table 3, and its preparation method comprises the following steps:

[0054] Weigh the AS resin, compatibilizer 1, compatibilizer 2, antistatic agent and additives by weight percentage and mix them in a high-speed mixer for 1-3 minutes; mix evenly to obtain a premix; place the premix on a twin-screw In the main feed port of the extruder, glass fiber and jellyfish pellets are added from the side feed port for melt extrusion, granulation and drying. Determination of its performance, odor and volatile content, the specific data are listed in Table 4.

Embodiment 4

[0082] Comparing Example 4 with Comparative Example 4, the water content of jellyfish pellets in Comparative Example 4 is lower, and the prepared glass fiber reinforced AS composition has a poorer odor and higher volatile matter content.

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PUM

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Abstract

The invention discloses a low-smell and antistatic fiberglass reinforced AS (Styrene Acrylonitrile) combination and a preparation method thereof. The low-smell and antistatic fiberglass reinforced AS combination comprises 44.4-76.4 percent of AS resin, 10-30 percent of fiberglass, 1-5 percent of a compatilizer 1, 1-5 percent of a compatilizer 2, 1-5 percent of medusa particle, 10-15 percent of an antstatic agent and 0.1-3 percent of an assistant. The preparation method comprises the steps as follows: the AS resin, compatilizers 1 and 2, the antistatic and the assistant are mixed in a high mixing machine for 1-3 minutes, placed in a main feeding hole of a dual-screw extruder, added with fiberglass and the medusa particle from a side feeding hole, molten, extruded, pelletized and dried to obtain the low-smell and antistatic fiberglass reinforced AS combination. According to the invention, an AS blend of the maleic anhydride graft is used as the compatilizer 1 and can improve the interface coupling effect of the AS and the fiberglass; the maleic anhydride graft is used as the compatilizer 2 and can greatly improve the compatibilityof the composite material; the medusa particles adopting high-melts foamed PP as a carrier is used as a stripping agent, and various kinds of volatile small molecules and organic compounds which are generated during processing can be effectively removed, so that the prepared fiberglass reinforced AS combination has the characteristics of low smell and good mechanical performance, and the antistatic effect is good by virtue of the added antistatic agent.

Description

technical field [0001] The invention relates to the field of modified plastics, in particular to a low-odor, antistatic glass fiber reinforced AS composition and a preparation method thereof. Background technique [0002] Styrene-acrylonitrile resin (AS) is a hard, transparent material. The styrene component makes AS hard, transparent and easy to process; the acrylonitrile component makes AS chemically and thermally stable. AS has strong load bearing capacity, chemical reaction resistance, thermal deformation resistance and geometric stability. Adding glass fiber additives can increase strength and thermal deformation resistance, and reduce thermal expansion coefficient. [0003] However, due to the strong odor of glass fiber reinforced AS composite materials, its application in the fields of automobiles and home appliances is limited; therefore, a low-odor glass fiber reinforced AS composite material has been developed, which has a huge market. [0004] There are many re...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L25/12C08L23/12C08L51/00C08L51/06C08L71/00C08K13/04C08K7/14C08K3/00C08J3/22C08J9/08B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/625B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 肖华明李欣陶四平宋晓东饶湘李晟张春怀李聪
Owner TIANJIN KINGFA NEW MATERIAL
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