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Solar battery and preparing method thereof

A solar cell and optoelectronic technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of not fundamentally improving battery efficiency, increasing battery light absorption, etc., and achieving the effects of low production cost, increased compactness, and increased height.

Active Publication Date: 2014-04-23
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Another approach is to use anti-reflection layers to improve the efficiency of graphene / silicon cells (E.Shi, H.Li, L.Yang, L.Zhang, Z.Li, P.Li, Y.Shang, S.Wu , X.Li, J.Wei, K.Wang, H.Zhu, D.Wu, Y.Fang, A.Cao, Nano Letters2013, 13, 1776-1781.), but this method can only increase the light absorption of the battery, Does not essentially improve the efficiency of the battery

Method used

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  • Solar battery and preparing method thereof

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Experimental program
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Effect test

Embodiment 1

[0053] A solar cell, which sequentially comprises from bottom to top: a 300 μm thick silicon sheet layer, a 10 nm thick graphene oxide layer, and a 3 nm thick graphene layer; wherein, the oxygen-to-carbon ratio in the graphene oxide layer is about 3.0;

[0054] The preparation method of described solar cell comprises the steps:

[0055] (1) Provide a silicon substrate, and use RCA standard cleaning steps to clean the silicon substrate to remove pollutants on it;

[0056] (2) Prepare a 10 mg / mL graphene oxide solution, spin-coat graphene oxide on the silicon substrate described in step (1) to obtain a graphene oxide interface layer, and obtain a structure of silicon sheet layer / graphene oxide layer; The operating conditions of the coating are to drop the graphene oxide solution on the silicon substrate, and then spin-coat at a speed of 2000 rpm for 60 seconds:

[0057] (3) calcining the structure of the silicon sheet layer / graphene oxide layer obtained in step (2) at 200°C for...

Embodiment 2

[0062] A solar cell, which comprises from bottom to top: a 300 μm thick silicon sheet layer, a 4 nm thick graphene oxide layer, and a 5.6 nm thick graphene layer; wherein the oxygen-to-carbon ratio in the graphene oxide layer is about 0.8;

[0063] The preparation method of described solar cell comprises the steps:

[0064] (1) Provide a silicon substrate, and use RCA standard cleaning steps to clean the silicon substrate to remove pollutants on it;

[0065] (2) Prepare a 5 mg / mL graphene oxide solution, pull the graphene oxide on the silicon substrate described in step (1) to obtain a graphene oxide interface layer, and obtain the structure of silicon sheet layer / graphene oxide layer; The operating conditions for pulling are: place the silicon wafer in the graphene oxide solution for 1 min, and then pull it up at a speed of 0.2 mm / s;

[0066] (3) Calcining the structure of the silicon sheet layer / graphene oxide layer obtained in step (2) at 600°C for 10 minutes to obtain a s...

Embodiment 3

[0071] A solar cell, which sequentially includes from bottom to top: a 300 μm thick silicon sheet layer, a 1 nm thick graphene oxide layer, and an 8 nm thick graphene layer; wherein the oxygen-to-carbon ratio in the graphene oxide layer is about 1.3;

[0072] The preparation method of described solar cell comprises the steps:

[0073] (1) Provide a silicon substrate, and use RCA standard cleaning steps to clean the silicon substrate to remove pollutants on it;

[0074] (2) Prepare a 0.1 mg / mL graphene oxide solution, spin-coat graphene oxide on the silicon substrate described in step (1) to obtain a graphene oxide interface layer, and obtain a silicon sheet layer / graphene oxide layer structure; The operating condition of spin coating is to drop the graphene oxide solution on the silicon substrate, then spin coating for 60 seconds at a speed of 2000 rpm;

[0075] (3) calcining the structure of the silicon sheet layer / graphene oxide layer obtained in step (2) at 400°C for 30 mi...

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Abstract

The invention relates to a solar battery, which sequentially comprises a silicon wafer layer, a graphene oxide layer and a graphene layer from bottom to top. The solar battery provided by the invention has the advantages that the efficiency of the silicon / graphene solar battery is greatly improved, and in addition, the cost is low.

Description

technical field [0001] The invention relates to a solar cell and a preparation method thereof, in particular to a graphene Schottky junction solar cell and a preparation method thereof. Background technique [0002] Solar cell, also known as "solar chip" or "photovoltaic cell", is a kind of photoelectric semiconductor sheet that uses sunlight to directly generate electricity. As long as it is illuminated by light, it can output voltage and current in an instant. At present, the most commonly used solar cell is polycrystalline silicon The battery, its working principle is based on the p-n junction. Although the polycrystalline silicon battery is stable and has a high conversion rate, it has problems such as high energy consumption, large pollution, and cumbersome preparation process. At present, people are trying their best to find materials that can replace silicon, in order to prepare Higher efficiency, lower cost, more environmentally friendly batteries. [0003] Graphene...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0352H01L31/04H01L31/18
CPCY02E10/50H01L31/02168H01L31/028H01L31/1804Y02E10/547Y02P70/50
Inventor 王钰焦柯嘉陈运法
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI