Water reducing agent with concrete workability adjusting function and synthetic method thereof

A synthesis method and concrete technology, applied in the field of water reducing agent for construction, can solve the problems of increasing the viscosity of concrete, affecting the setting time of concrete, affecting the fluidity, etc., so as to achieve the effect of reducing surface tension, ensuring normal setting and strength development

Active Publication Date: 2014-05-28
大连市铭源全科技开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in its popularization and application, some shortcomings of polycarboxylate superplasticizer itself have also affected its development to some extent.
The existing problems are as follows: 1. Inadaptability to aggregates with high mud content
2. Sensitivity to dosage and water consumption
3. Concrete apparent bubble problem
4. Problems such as large collapse of concrete after pumping out
However, for most of the water-retaining and viscosity-adjusting agents, such as: cellulose, Wenlun gum, sodium alginate, and xanthan gum, there are a series of problems that are difficult to effectively apply.
Such as: incompatible with polysulfonic acid superplasticizer, there will be precipitation and layering phenomenon; it will increase the viscosity of concrete and affect the fluidity; most of them will affect the setting time of concrete and the strength of concrete; with the increase of concrete viscosity, its Plastic containment also increased

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Raw material composition and its ratio:

[0019] a prenol polyoxyethylene ether

[0020] b acrylic or

[0021] c maleic anhydride

[0022] d Sodium p-styrene sulfonate

[0023] ammonium persulfate

[0024] f sodium methacrylate,

[0025] The preferred molar ratio of described each raw material consumption: a: b: c: d: f=1: 1: 2: 0.2: 0.5, e consumption is a, b, 0.5% of c gross weight.

[0026] Synthesis method of water reducer with concrete workability adjustment function: Dissolve e in appropriate amount of water to make drop solution A, add water into the reaction kettle, then add a, b, c, d, f to the reaction kettle in turn , Stir to dissolve, and raise the temperature to 60-70 degrees, and evenly drop the addition solution A into the reactor, all added in 3 hours, and continue to maintain 60-70 degrees for 1 hour, the reaction is over.

Embodiment 2

[0028] Raw material composition and its ratio:

[0029] a prenol polyoxyethylene ether

[0030] bMethacrylic acid

[0031] c maleic anhydride

[0032] d Sodium p-styrene sulfonate

[0033] Potassium persulfate

[0034] f sodium methacrylate,

[0035] The molar ratio of the amount of each raw material: a:b:c:d:f=1:1:1.5:0.2:0.3, the amount of e is 0.6% of the total weight of a, b, and c.

[0036] Its synthetic method is with embodiment 1.

Embodiment 3

[0038] Raw material composition and its ratio:

[0039] a prenol polyoxyethylene ether

[0040] bAcrylic acid and methacrylic acid

[0041] c maleic anhydride

[0042] d Sodium p-styrene sulfonate

[0043] e ammonium persulfate and potassium persulfate

[0044] f sodium methacrylate,

[0045] The molar ratio of the amount of each raw material: a: b: c: d: f = 1: 1 ~ 1.5: 1.5 ~ 2.5: 0.2 ~ 0.25: 0.3 ~ 0.6, the amount of e is 0.5 ~ 1.0% of the total weight of a, b, c .

[0046] Its synthetic method is with embodiment 1.

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PUM

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Abstract

The invention discloses a water reducing agent with a concrete workability adjusting function. The water reducing agent is prepared from the following components: a. isopentenol polyoxyethylene ether, b. acrylic acid or methylacrylic acid or a mixture of the acrylic acid and the methylacrylic, c. maleic anhydride, d. sodium p-styrenesulfonate, e. ammonium persulfate or potassium persulfate or a mixture of the ammonium persulfate and the potassium persulfate, and f. sodium methallyl sulfonate, wherein the molar ratio of the using amount of a to b to c to d to f is 1:(1-1.5):(1.5-2.5):(0.2-0.25):(0.3-0.6); the using amount of e is 0.5 to 1.0 percent of the total weight of a, b and c. The water reducing agent provided by the invention has water retention capacity and has the function of reducing the surface tension of concrete so as not to influence the viscosity and the flowability of the concrete, and also can guarantee normal condensation and strength development of the concrete.

Description

technical field [0001] The invention relates to a water reducing agent for construction, in particular to a water reducing agent with the function of adjusting the workability of concrete and a synthesis method thereof. Background technique [0002] In recent years, with the development of large-scale national infrastructure projects such as national railways, ports, and nuclear power plants, and the high-performance requirements of these key projects for concrete, the market for polycarboxylate-based high-performance water-reducing agents has developed rapidly. The continuous progress of polycarboxylate superplasticizer synthesis and application technology. With the supply of upstream raw materials becoming more and more mature, the cost-effectiveness of polycarboxylate superplasticizers has become increasingly prominent compared with other superplasticizers. Its excellent water reducing properties, slump retention and environmental protection are increasingly recognize...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F290/06C08F220/06C08F222/06C08F212/14C08F228/02C04B24/16C04B103/30
Inventor 宫振鑫
Owner 大连市铭源全科技开发有限公司
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