Core-shell type composite fire-extinguishing powder and preparation method thereof

A composite powder, core-shell structure technology, applied in fire protection equipment and other directions, can solve the problems of large particle size, fast particle settling, slow decomposition speed, etc., achieves broad practical application prospects, simple preparation process, and reduces fire extinguishing costs.

Inactive Publication Date: 2014-06-25
SUZHOU INST FOR ADVANCED STUDY USTC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional dry powder fire extinguishing agent has large particle size, fast particle settlement, and slow decomposition speed, so that the fire extinguishing active component particles cannot fully contact with the flame, and the fire extinguishing effect cannot be fully exerted, thus restricting the practical application range of powder fire extinguishing agent
In order to improve the fire extinguishing performance of the powder fire extinguishing agent, the main measure currently adopted is to carry out ultra-fine treatment on the powder, but the ultra-fine treatment of the powder requires special equipment, and the degree of particle size reduction is limited; while the particle size The smaller particles have a large surface energy, they are easy to agglomerate with each other, the fluidity decreases, and the fire extinguishing efficiency of the dry powder fire extinguishing agent will be reduced.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1: after ball milling 140g 13X type zeolite in a ball mill for 30min, its average particle diameter reaches below 10 μm; get this refined zeolite 120g and put it into 20L sodium bicarbonate concentration in the aqueous solution of 0.01mol / L, at a speed Stir mechanically at a speed of 400r / min for 6h, then vacuum freeze-dry the solution at a temperature of -10°C and a pressure of 5.0Pa, then add 1.0g of silicon dioxide and 2.0g of talc, and mix well , to obtain the composite powder fire extinguishing agent of the present invention.

[0017] As measured by a particle size analyzer, the average particle size of the particles in the fire extinguishing agent is 8.6 μm.

[0018] Put 100g of the composite powder in a 1.0L powder storage tank, pressurize it to 0.6MPa, and spray it onto a gasoline fire with an oil pan diameter of 30cm and a flame power of 200kW. The fire extinguishing time is 3.5s, and the amount of fire extinguishing agent is 36.2 g. Under the same...

Embodiment 2

[0019] Example 2: After milling 240g of mordenite in a ball mill for 60min, dry it at 120°C for 2h; take 200g of the refined zeolite and put it into 20L of potassium bicarbonate solution with a concentration of 0.025mol / L at a speed of 500r / L Stir mechanically at a speed of min for 8 hours, then vacuum freeze-dry the solution at a temperature of -15°C and a pressure of 10.0Pa, then add 2.5g of silicon dioxide and 4.5g of talcum powder, and mix evenly to obtain The composite powder fire extinguishing agent of the present invention.

[0020] As measured by a particle size analyzer, the average particle size of the particles in the fire extinguishing agent is 7.5 μm.

[0021] 100g of the composite powder is packed in a 1.0L powder storage tank, pressurized to 0.6MPa, sprayed onto a fire source with an oil pan diameter of 40cm, a thickness of edible oil of 5cm, and a flame power of 70kW. The average fire extinguishing time is 5.0 s, the average amount of fire extinguishing agent ...

Embodiment 3

[0022] Example 3: After ball milling 350g of 4A type zeolite in a ball mill for 90min, dry at 120°C for 2h; take 300g of the refined zeolite and put it into 30L of ammonium dihydrogen phosphate concentration in an aqueous solution of 0.015mol / L, at a speed of Stir mechanically at a speed of 600r / min for 12h, then vacuum freeze-dry the solution at a temperature of -20°C and a pressure of 8.0Pa, then add 4.0g of silicon dioxide and 8.0g of talc, mix well, That is the composite powder fire extinguishing agent of the present invention.

[0023] As measured by a particle size analyzer, the average particle size of the particles in the fire extinguishing agent is 8.2 μm.

[0024] Put 100g of the composite powder in a 1.0L powder storage tank, pressurize it to 0.6MPa, and spray it onto a gasoline fire with an oil pan diameter of 30cm and a flame power of 200kW. The fire extinguishing time is 3.0s, and the amount of fire extinguishing agent is 31.2 g. Under the same experimental con...

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PUM

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Abstract

The invention discloses a core-shell type composite fire-extinguishing powder and a preparation method thereof. The preparation method is characterized by comprising the following steps: adding refined zeolite with an average particle size of 10 [mu]m or less into a water solution (0.01-0.10 mol / L) containing sodium bicarbonate and potassium bicarbonate / ammonium dihydrogen phosphate, wherein the refined zeolite accounts for 78% to 90% of the weight of the system and the water solution accounts for 8% to 18% of the weight of the system; mechanically stirring the mixture for 4 to 8 hours at a speed of 300 to 600 r / min; carrying out a vacuum freeze-drying treatment on the solution at a temperature of -10 to -30 DEG C under a pressure of 1.3 to 13 Pa, adding silica accounting for 0.5 to 1.05 of the weight of the system and talcum powder accounting for 1.5 to 3.0% of the weight of the system into the obtained powder, and evenly mixing the powder together so as to obtain the target product. The composite fire-extinguishing powder has the advantages of high fire-extinguishing efficiency, cheap and available raw materials, and simple preparation technology, can be directly applied to the conventional dry powder fire extinguishers, and is suitable for various types of fires such as fire on solid substances, fire on flammable gas, fire on liquid, and the like.

Description

【Technical field】 [0001] The invention belongs to the technical field of powder fire extinguishing agents, in particular to a composite powder fire extinguishing agent with a core-shell structure and a preparation method thereof. 【Background technique】 [0002] Among the commonly used fire extinguishing agents such as gas, powder, water system, foam, etc., powder fire extinguishing agent is widely used because of its high fire extinguishing efficiency, fast fire extinguishing speed, environmental friendliness, non-toxicity to human body, wide source and low price. It is especially suitable for fire fighting in water-scarce areas. The fire extinguishing active components of commonly used powder fire extinguishing agents mainly include sodium bicarbonate, potassium bicarbonate, ammonium dihydrogen phosphate, etc. However, the traditional dry powder fire extinguishing agent has large particle size, fast particle settlement, and slow decomposition speed, so that the fire exting...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/00
Inventor 倪小敏
Owner SUZHOU INST FOR ADVANCED STUDY USTC
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