The application relates to the technical field of
sodium ion batteries, in particular to a
Prussian blue sodium ion battery positive
electrode material and a preparation method and application thereof. In the preparation method, when the
Prussian blue sodium ion battery positive
electrode material is prepared, a specific complexing agent (mellitic acid,
methane tricarboxylic acid or
nitrilotriacetic acid) is selected, and a non-ionic surfactant is added, so that the growth of the
Prussian blue material can be guided, and problems such as
particle size reduction and uneven distribution caused by excessively
high concentration when a conventional complexing agent such as
sodium citrate is used can be overcome. The preparation method can not only improve the sodium content of the prepared Prussian blue material, thereby improving the specific capacity of the material, but also control the
nucleation and
growth speed of the obtained Prussian blue material, form a large-size
single crystal, and the low-defect structure of the
single crystal is beneficial to extremely low
metal ion
dissolution, excellent specific capacity and excellent Na +
diffusion kinetics, and alleviates the rate and capacity attenuation caused by the long sodium ion
diffusion path of the polycrystalline structure.