Combining system for low pressure moulding of continuous-casting three critical parts

A combined system and low-pressure forming technology, applied in the field of continuous casting functional refractory materials, can solve the problems of unfavorable densification of cooked billets, low production efficiency, unfavorable low-pressure forming, etc., achieve obvious economic and social benefits, improve room temperature strength and Effects of high temperature strength, improved toughness and thermal shock resistance

Active Publication Date: 2014-07-23
SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, as the pressure increases, the production efficiency of the three major products becomes lower, the energy consumption becomes larger, and the loss of the expensive isostatic press becomes more and more serious, see Table 1
The combination system of phenolic resin powder + alcohol is not conducive to low-pressure molding, because alcohol is a low-boiling solvent. Under this combination system, the high volatile content required for low-pressure densification of the green body is not easy to control, and high-volatile substances are re-formed during heat treatment. Pores, not conducive to the densification of the cooked body

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Alumina and graphite are the main raw materials, wherein the content of alumina is 78%, the content of graphite is 22%, and phenolic resin powder of 5wt% of raw material weight and 2wt% of CarboresP are added, and the added solvent is alcohol of 3wt% of raw material weight and 2wt% of mixed distillate Dimethyl dibasic acid is kneaded by a high-speed mixer, the temperature of the mixer is 77°C, the volatile content of the billet is controlled to 2.5%, isostatically pressed at 40MPa, and finally heat-treated in an atmosphere protection treatment furnace, N 2 The content is greater than 99.99vol%, the temperature is raised to 950°C at 1°C / min, and the temperature is kept for 300min. After heat treatment, the apparent porosity of the material is 11.3%, and the bending resistance at normal high temperature is 8.6MPa and 11.1MPa respectively.

Embodiment 2

[0018] Alumina and graphite are the main raw materials, wherein the content of alumina is 75%, the content of graphite is 25%, and phenolic resin powder of 6wt% of raw material weight and CarboresP of 3wt% are added, and the added solvent is alcohol of 3wt% of raw material weight and 1.5wt% of mixed Dimethyl dibasic acid is kneaded by a high-speed mixer, the temperature of the mixer is 65°C, the volatile content of the billet is controlled to 2.1%, isostatically pressed at 40MPa, and finally heat-treated in an atmosphere protection treatment furnace, N 2 The content is greater than 99.99vol%, the temperature is raised to 950°C at 1°C / min, and the temperature is kept for 300min. After heat treatment, the apparent porosity of the material is 13.5%, and the bending resistance at normal high temperature is 7.3MPa and 10.2MPa respectively.

Embodiment 3

[0020] Alumina and graphite are the main raw materials, wherein the alumina content is 72%, the graphite content is 18%, and phenolic resin powder of 4wt% of raw material weight and 1.5wt% of CarboresP are added, and the added solvent is alcohol of 3wt% of raw material weight and 2.5wt% of Mixed dibasic acid dimethyl ester, kneaded by a high-speed mixer, the temperature of the mixer is 72°C, the volatile content of the billet is controlled to 3.1%, isostatically pressed at 40MPa, and finally heat-treated in an atmosphere protection treatment furnace, N 2 The content is greater than 99.99vol%, the temperature is raised to 950°C at 1°C / min, and the temperature is kept for 300min. After heat treatment, the apparent porosity of the material is 14.1%, and the bending resistance at normal high temperature is 6.5MPa and 9.5MPa respectively.

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Abstract

The invention belongs to the technical field of continuous-casting funcational refractory materials, and relates to a combining system for low pressure moulding of continuous-casting three critical parts. The combining system comprises a binding agent and a solvent. The binding agent is composed of phenolic resin powder and CarboresP, the adding amount of phenolic resin powder is 4-6 wt% of the total weight of the continuous-casting three critical parts, and the adding amount of CarboresP is 1.5-3 wt% of the total weight of the continuous-casting three critical parts. The solvent comprises alcohol and methyl mixed dicarboxylate, the adding amount of alcohol is 2-3 wt% of the total weight of the continuous-casting three critical parts, and the adding amount of methyl mixed dicarboxylate is 1.5-2.5 wt% of the total weight of the continuous-casting three critical parts. By controlling the adding amount of high-boiling-point solvents, the high-volatility composition needed by low-pressure molding of blank materials is regulated and controlled; by introducing the binding agent with high residual carbon rate, the densification of the products is guaranteed, also the high-temperature strength of the material is improved, so that the combining system has obvious economic benefit and social benefit.

Description

technical field [0001] The invention belongs to the technical field of continuous casting functional refractory materials, and mainly relates to a combination system for continuous casting and low-pressure forming of three large pieces. Background technique [0002] The three major components of continuous casting include the long nozzle for continuous casting, the integral stopper rod and the submerged nozzle, which are very important functional refractory materials in the continuous casting process. To control and divert molten steel, prevent the secondary oxidation of molten steel, and realize the continuous casting process. Usually, the three major parts of continuous casting select different carbon-containing materials according to the service conditions of different parts, mainly oxide materials (Al 2 o 3 , MgO, ZrO 2 , spinel) and graphite, and with the appropriate combination system in the isostatic press molding. [0003] The compactness of the three blanks depe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 钱凡刘国齐杨文刚于建宾马天飞马谓奎
Owner SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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