Graphene-lead alloy as well as preparation method and application thereof

A graphene and lead alloy technology, applied in the direction of electrode carriers/current collectors, electrical components, circuits, etc., to achieve the effects of good fluidity and creep resistance, less water loss, and firm bonding

Active Publication Date: 2014-07-23
XIAMEN MATE HI TECH NEW ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this case, most manufacturers have to choose to use the lead-calcium-high-tin alloy that does not meet the market requirements as the positive electrode grid to manufacture batteries.

Method used

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  • Graphene-lead alloy as well as preparation method and application thereof
  • Graphene-lead alloy as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Embodiment 1: Preparation of graphene alloy plate and grid alloy thereof

[0044] Table 1 is the consumption (weight percentage) of following each embodiment

[0045] Composition / Content Graphene tin aluminum strontium copper Example 1 0.1 0.1 0 0 0 Example 2 0.05 0.4 0 0 0 Example 3 0.02 1.6 0.03 0 0 Example 4 0.02 0 0 0.05 0 Example 5 0.02 0 0.03 0.26 0 Example 6 0.05 0 0 1.2 0 Example 7 0.0015 0.4 0 0.26 0.05 Example 8 0.05 0.36 0.03 0.3 0.06 Example 9 0.01 0.25 0.02 0.35 0.09

[0046] Note: the balance of each embodiment in table 1 is lead;

[0047] Preparation method: Disperse natural graphite in water, heat it under an oxidizing agent such as sulfuric acid at a temperature of 30-99°C for 1-48 hours to obtain graphene oxide; disperse it with ultrasonic waves and wash it, then add tin oxide and or strontium oxide and or oxidation Copper and or alumin...

Embodiment 2

[0050] Embodiment 2: the preparation of graphene alloy and grid alloy thereof

[0051] See Table 1 for dosage.

[0052] See Example 1 for the preparation method.

[0053] The grid prepared in this embodiment has high hardness, good fluidity and strong corrosion resistance. The cycle life is better.

Embodiment 3

[0054] Embodiment 3: the preparation of graphene alloy and grid alloy thereof

[0055] See Table 1 for dosage.

[0056] See Example 1 for the preparation method.

[0057] The grid prepared in this embodiment has suitable hardness, good fluidity and weak corrosion resistance. The creep resistance of the grid is relatively weak, and the cycle life is relatively short.

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Abstract

The invention discloses a graphene-lead alloy as well as a preparation method and application thereof. The graphene-lead alloy is prepared from the following components in percentage by weight: 0.0015-0.1 percent of graphene, 96.96 percent of lead and any one, two, three or four of 0.1-1.6 percent of tin, 0.015-0.05 percent of aluminum, 0.05-1.2 percent of strontium and 0.05-0.09 percent of copper. The invention also discloses the preparation method and the application to a grid alloy. The graphene-lead alloy used by a grid is high in rigidity, good in toughness, mobility and creep resistance, strong in corrosion resistance and firm in combination of the grid and an active substance without a barrier layer. According to the invention, a battery manufactured by the graphene-lead alloy is little in water loss and long in cycle life.

Description

technical field [0001] The invention relates to the field of graphene alloys, in particular to a graphene lead alloy, a preparation method and an application thereof. Background technique [0002] As we all know, the mainstream grid alloys of lead-acid batteries are divided into lead-calcium series and lead-antimony series. Lead-calcium series include commonly used lead-calcium-tin-aluminum, uncommonly-used lead-calcium-high-tin, lead-calcium rare earth, lead-calcium-bismuth-silver, etc.; lead-antimony series include high-antimony, medium-antimony, low-antimony multi-element, lead-antimony-cadmium positive grids, etc. alloy. Calcium-based and antimony-based alloys have their own advantages and disadvantages: lead-calcium alloys have the advantages of less water loss, small internal resistance, and long-term floating charge resistance, and have been widely used in backup power applications; lead-antimony series are mainly used for high-current discharge occasions and deep c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/68C22C11/00C22C11/02C22C11/06C22C1/03
CPCC22C1/03C22C11/02C22C11/06H01M4/662H01M4/685Y02E60/10
Inventor 陈振富陈本
Owner XIAMEN MATE HI TECH NEW ENERGY CO LTD
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