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A method for anti-oxidation treatment of conductive rods in lead electrolysis system

A conductive rod and lead electrolysis technology, applied in the electrolysis process, electrolysis components, etc., can solve the problems of volatilization and lack of anti-oxidation, and achieve the effects of convenient and fast operation, long-lasting anti-oxidation time, and stable performance

Active Publication Date: 2016-08-24
CHENZHOU CITY JINGUI SILVER IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Applying a layer of glycerin on its surface will also volatilize with high temperature and fail to achieve the effect of anti-oxidation

Method used

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  • A method for anti-oxidation treatment of conductive rods in lead electrolysis system

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Step 1: Put 350 conductive rods into the bucket of the light rod machine, first add 1kg of 10% dilute sulfuric acid and mix the conductive rods. Then add 7kg of fresh rice husks, and turn the light rod machine to scrub the conductive rods and rice husks;

[0015] Step 2: After rotating for 15 minutes, sieve the chaff. Then add 1kg of 10% dilute sulfuric acid for the second pickling, and finally wash it with water, and quickly wipe it dry. The bend should be straightened or replaced;

[0016] Step 3: When casting the anode sheet, apply a uniform and thin anti-oxidation protective film on the surface of the conductive rod.

[0017] After observing an electrolysis cycle, the measurement results of the voltage drop at the contact points of the normal production cell and the antioxidant-coated electrolytic cell are compared as follows:

[0018] Comparison of measurement results of contact voltage drop mV

[0019] Power-on time / h

Embodiment 2

[0021] Step 1: Put 350 conductive rods into the bucket of the light rod machine, first add 1kg of 15% dilute sulfuric acid and mix with the conductive rods. Then add 8kg / time of fresh rice husks, and turn the light rod machine to scrub the conductive rods and rice husks;

[0022] Step 2: After rotating for 15 minutes, sieve the chaff. Then add 1kg of 15% dilute sulfuric acid for the second pickling, and finally wash it with water, and quickly wipe it dry. The bend should be straightened or replaced;

[0023] Step 3: When casting the anode sheet, apply a uniform and thin anti-oxidation protective film on the surface of the conductive rod.

[0024] After observing an electrolysis cycle, the measurement results of the voltage drop at the contact points of the normal production cell and the antioxidant-coated electrolytic cell are compared as follows:

[0025] Comparison of measurement results of contact voltage drop mV

[0026] Power-on time / h

Embodiment 3

[0028] Step 1: Put 350 conductive rods into the bucket of the light rod machine, first add 1.5kg / time of 20% dilute sulfuric acid and mix with the conductive rods. Then add 10kg of fresh rice husks, turn the light rod machine, so that the conductive rod and rice husk scrub each other;

[0029] Step 2: After rotating for 20 minutes, sieve the chaff. Then add 1.5kg of 20% dilute sulfuric acid for the second pickling, and finally wash it with water and dry it quickly. The bend should be straightened or replaced;

[0030] Step 3: When casting the anode sheet, apply a uniform and thin anti-oxidation protective film on the surface of the conductive rod.

[0031] After observing an electrolysis cycle, the measurement results of the voltage drop at the contact points of the normal production cell and the antioxidant-coated electrolytic cell are compared as follows:

[0032] Comparison of measurement results of contact voltage drop mV

[0033] Power-on time / h

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Abstract

The invention relates to the technical field of nonferrous metal smelting, in particular to an anti-oxidation treatment of conductive rods in a lead electrolysis system. It includes putting the conductive rod into the light rod machine bucket, adding dilute sulfuric acid with a concentration of 10-25% and fresh rice husk for pickling; , and finally cleaned with water; when cast into an anode sheet, apply a layer of appropriate antioxidant on its surface to form a uniform protective film on the surface. This method has long anti-oxidation time, low cost and no influence on the conductivity; it overcomes the problems of easy oxidation and electrochemical corrosion of the conductive rod in the electrolysis process, reduces the contact voltage in the later stage of electrolysis, and has obvious economic benefits.

Description

Technical field [0001] The invention relates to a method for anti-oxidation treatment of a conductive rod in a lead electrolysis system, and belongs to the technical field of non-ferrous metal smelting. Background technique [0002] At present, saving energy, reducing energy consumption, clean production, and building energy-saving and environment-friendly enterprises have become the general trend of the non-ferrous metal smelting industry. In the lead-zinc smelting industry, the cell voltage is a very important technical and economic index in the lead electrolysis system, and its level directly affects the quality of the cathode lead and the index of direct current unit consumption. During the production process, the cell voltage fluctuates between 0.3 and 0.6V with changes in technical conditions, mainly distributed in the electrolyte voltage drop, the voltage drop of each contact point, the conductor voltage drop, and the anode slime and concentration range. Among them, the v...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23G3/00C23F11/14C25C7/06
Inventor 柴承平谢兆凤刘万里覃小龙
Owner CHENZHOU CITY JINGUI SILVER IND CO LTD