Polycarbonate-organosiloxane copolymer material capable of selectively transmitting near-infrared rays

An organosiloxane and polycarbonate technology, which is applied in the field of near-infrared transmission materials, can solve the problems of affecting the mechanical properties of materials, poor low-temperature impact resistance, etc., and achieves good processing performance, excellent low-temperature impact resistance, and heat resistance. Excellent effect of oxygen aging performance

Active Publication Date: 2014-09-03
GUANGZHOU SUPER DRAGON ENG PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the low-temperature impact resistance of polycarbonate materials is poor, and the addition of a large amount of inorganic infrared penetrating agents or other small molecule additives mentioned in the above patents will seriously affect the mechanical properties of the material

Method used

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  • Polycarbonate-organosiloxane copolymer material capable of selectively transmitting near-infrared rays
  • Polycarbonate-organosiloxane copolymer material capable of selectively transmitting near-infrared rays
  • Polycarbonate-organosiloxane copolymer material capable of selectively transmitting near-infrared rays

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Polycarbonate-organosiloxane copolymer (Tarflon Neo Rc1700, silicone copolymerization rate 3%) 97wt%, flame retardant 0.1wt% (Dyneon-FR2025), infrared penetrating agent perylene red (Bai Lingwei reagent, particle diameter is 1100nm) 2wt%; UV blocker 0.6wt% (UV1164), antioxidant 0.2wt% (phosphonite antioxidant 168), lubricant 0.1wt% (pentaerythritol stearate).

[0041] Test results: product color: red; normal temperature and low temperature notched impact strength test: 64KJ / m 2 , 52KJ / m 2 (-30°C); flame retardant test: meet the flame retardant UL94V-1 grade at a thickness of 1.6mm; visible light transmittance (350-760nm): ≤3%; initial penetration wavelength: 723nm; infrared transmittance (800 -1500nm): 89%.

Embodiment 2

[0043] Polycarbonate-organosiloxane copolymer (Tarflon Neo AG2530, silicone copolymerization rate 9%) 97wt%, flame retardant 0.1wt% (Dyneon-FR2025), infrared penetrating agent perylene red (Bai Lingwei reagent, particle diameter is 1100nm) 2wt%; UV blocker 0.6wt% (UV1164), antioxidant 0.2wt% (phosphonite antioxidant 168), lubricant 0.1wt% (pentaerythritol oleate).

[0044] The test results show: product color: red; normal temperature and low temperature notched impact strength test: 65KJ / m 2 , 57KJ / m 2 (-30°C); flame retardant test: meet the flame retardant UL94V-1 grade at a thickness of 1.6mm; visible light transmittance (350-760nm): ≤3%; initial penetration wavelength: 723nm; infrared transmittance (800 -1500nm): 75%.

Embodiment 3

[0046] Polycarbonate-organosiloxane copolymer (Tarflon Neo Rc1700, silicone copolymerization rate 3%) 98wt%, flame retardant 0.1wt% (Dyneon-FR2025), infrared penetrating agent perylene red (Bai Lingwei reagent, particle diameter is 1100nm) 1wt%; UV blocker 0.6wt% (UV1164), antioxidant 0.2wt% (phosphonite antioxidant 168), lubricant 0.1wt% (pentaerythritol stearate).

[0047] The test results show: product color: red; normal temperature and low temperature notched impact strength test: 68KJ / m 2 , 59KJ / m 2 (-30°C); flame retardant test: meet the flame retardant UL94V-1 grade at a thickness of 1.6mm; initial penetration wavelength: 723nm; visible light transmittance (350-760nm): ≤10%, infrared transmittance (800 -1500nm): 90%.

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Abstract

The invention belongs to the technical field of near-infrared ray transmission materials, and discloses a polycarbonate-organosiloxane copolymer material capable of selectively transmitting near-infrared rays. The product prepared from the material has higher low-temperature impact resistance and near-infrared ray transmission selectivity. The material comprises 94.1-98.7wt% of polycarbonate-methylsiloxane copolymer, 0.1-0.3 wt% of flame retardant, 1-4 wt% of infrared penetrant, 0.1-1 wt% of ultraviolet blocking agent, 0.1-0.5 wt% of antioxidant and 0-0.1 wt% of lubricant. The polycarbonate-organosiloxane copolymer selected as the substrate has better mechanical properties than the existing material, and has higher low-temperature impact resistance and high near-infrared transmittance. By selecting the perylene organic pigment as the near-infrared penetrant, the material can implement very high visible light covering performance, near-infrared region transmittance and selectivity for multiple colors.

Description

technical field [0001] The invention belongs to the technical field of near-infrared transmission materials, in particular to a polycarbonate-organosiloxane copolymer material which selectively transmits near-infrared rays. Selective permeability. Background technique [0002] The wavelength range of visible light is between 350-770nm, and electromagnetic radiation of different wavelengths gives people different color perceptions: 350-455nm is purple; 455-492nm is indigo; 492-577nm is green; 577-597nm is yellow; 597nm -622nm is orange; 600-770nm is red. The wavelength range of infrared rays is from 770nm to 400μm. Infrared rays can be divided into three bands: 780-1500nm is the near-infrared region, 1500-6000nm is the mid-infrared region, and 6000nm-1000μm is the far-infrared region. The heat in sunlight is mainly transmitted through electromagnetic waves in the near-infrared region. [0003] Selective infrared-transmitting materials can allow infrared rays in a specific...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08K5/3437C08K5/42C08K5/103
Inventor 郝源增郝建鑫任萍陈瑜邓爵安
Owner GUANGZHOU SUPER DRAGON ENG PLASTICS
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