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Modification method for effectively improving adsorption performance of activated carbon on trace ammonia

An adsorption performance, activated carbon technology, applied in the field of ambient air purification, can solve problems such as ammonia pollution, and achieve the effects of enhanced adsorption performance, excellent market prospects, and important environmental protection.

Inactive Publication Date: 2014-11-26
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the shortcomings and deficiencies of the current technology and products, the present invention aims to solve the current pollution control problem of low-concentration ammonia in the air in various industries, and invents a modification method that effectively improves the adsorption performance of activated carbon on trace ammonia

Method used

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  • Modification method for effectively improving adsorption performance of activated carbon on trace ammonia
  • Modification method for effectively improving adsorption performance of activated carbon on trace ammonia
  • Modification method for effectively improving adsorption performance of activated carbon on trace ammonia

Examples

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Embodiment 1

[0020] Take 150g of activated carbon particles, put them in reaction vessel 1, add 500mL of nitric acid solution with a mass concentration of 10%, maintain a constant temperature reaction environment in a water bath, the temperature is 60°C, and the stirring reaction time is 2h; The activated carbon was washed with deionized water to make the pH of the washing liquid reach 5~6, and then dried at 80°C; the initially treated activated carbon was added to the reaction vessel 2, and 500 mL of citric acid aqueous solution, lemon The mass concentration of the acid is 10%, the oil bath method is used to maintain a constant temperature reaction environment, the temperature is 120 ° C, and the reaction is stirred for 4 hours; the activated carbon that has been preliminarily treated is filtered out and washed with deionized water to make the pH of the washing liquid reach 5~6; Add activated carbon to reaction vessel 3, add 500 mL of butane tetracarboxylic acid aqueous solution, the mass ...

Embodiment 2

[0022] Take 150g of activated carbon particles, put them in the first reaction vessel, add 500mL of nitric acid solution with a mass concentration of 40%, maintain a constant temperature reaction environment in a water bath, the temperature is 60°C, and the stirring reaction time is 2h; Wash the treated activated carbon with deionized water to make the pH of the washing liquid reach 5~6, and then dry it at 80°C; add the preliminary treated activated carbon into the second reaction vessel, and add 500mL of citric acid aqueous solution into the reaction vessel , the mass concentration of citric acid is 10%, the oil bath method is used to maintain a constant temperature reaction environment, the temperature is 120 ° C, and the reaction is stirred for 4 hours; the activated carbon that has been preliminarily treated is filtered out and washed with deionized water to make the pH of the washing liquid reach 5 ~6; Add activated carbon into the third reaction vessel, add 500mL of butan...

Embodiment 3

[0024] Take 150g of activated carbon particles, put them in the first reaction vessel, add 500mL of nitric acid solution with a mass concentration of 40%, maintain a constant temperature reaction environment in a water bath, the temperature is 60°C, and the stirring reaction time is 2h; Wash the treated activated carbon with deionized water to make the pH of the washing liquid reach 5~6, and then dry it at 80°C; add the preliminary treated activated carbon into the second reaction vessel, and add 500mL of citric acid aqueous solution into the reaction vessel , the mass concentration of citric acid is 25%, and the oil bath method is used to maintain a constant temperature reaction environment. ~6; Add activated carbon into the third reaction vessel, add 500mL of butane tetracarboxylic acid aqueous solution, the mass concentration of butane tetracarboxylic acid is 25%, maintain a constant temperature reaction environment in an oil bath, the temperature is 120 ° C, and stir the re...

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Abstract

The invention relates to a modification method for effectively improving the adsorption performance of activated carbon on trace ammonia. The activated carbon is treated in a chemical way by adopting a plurality of steps; the preparation method of a material comprises the steps of putting the activated carbon to be modified into a reaction vessel, feeding a nitric acid solution into the reaction vessel, and carrying out mixing reaction under the constant temperature condition; after primary treatment, filtering and washing the activated carbon, and drying to obtain dried activated carbon; putting the dried activated carbon into a constant temperature reaction vessel filled with a citric acid solution, stirring and carrying out reaction for a period of time; filtering out the activated carbon and washing the activated carbon by deionized water so as to obtain treated activated carbon; feeding the treated activated carbon into a reaction vessel filled with a butane-tetracarboxylic acid water solution, and carrying out stirring reaction under the constant temperature condition; separating the activated carbon in a filtering manner, washing the separated activated carbon by deionized water, and naturally drying so as to obtain dried activated carbon; and carrying out vacuum encapsulation on the dried activated carbon for later use. The activated carbon modification process is simple, high in operability and low in cost; the activated carbon prepared by adopting the method is capable of effectively improving the adsorption performance of the activated carbon on the trace ammonia in the air.

Description

technical field [0001] The invention belongs to the field of ambient air purification. In particular, it relates to a modification method for effectively improving the adsorption performance of activated carbon for trace amounts of ammonia. Background technique [0002] With the development of the economy, the pursuit of work and quality of life has increasingly become the focus of people's concern. The rise of interior decoration and the introduction of various modern daily necessities have made indoor air pollution more and more serious. Among them, the rate of ammonia gas exceeding the standard is relatively high, ranking first in pollution. Indoor ammonia gas is mainly emitted from building materials and decoration materials. For example, the high alkali expansion agent and antifreeze in concrete will be reduced to ammonia gas and released from the wall as the environmental factors change. In addition, since the decorative wooden boards contain urea, and the finishing...

Claims

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Application Information

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IPC IPC(8): B01J20/22B01J20/32B01D53/02
Inventor 徐斌吴娅
Owner TONGJI UNIV