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Multiscale reaction carrier with porous microchannel structure and its preparation method

A technology of micro-channel structure and reaction carrier, which is applied to catalyst carriers, chemical instruments and methods, physical/chemical process catalysts, etc. problems such as decline, to achieve the effect of being conducive to cascading expansion, large-scale promotion, and improving the reaction rate and conversion rate

Inactive Publication Date: 2016-01-27
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The thermal conductivity of the reaction carrier produced by this method is not good, which is not conducive to the lamination and expansion of the reaction carrier
[0007] Chinese invention patent (application number 201310554712.3) discloses a self-heating staggered micro-boss array type alcohol reformer, including a reforming hydrogen production plate and a catalytic combustion plate, for alcohol combustion and water vapor reforming hydrogen production reaction, to achieve self-heating operation, but the surface-loaded catalyst is easy to fall off, resulting in a decrease in the reaction rate and a decrease in the conversion rate of alcohols

Method used

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  • Multiscale reaction carrier with porous microchannel structure and its preparation method
  • Multiscale reaction carrier with porous microchannel structure and its preparation method
  • Multiscale reaction carrier with porous microchannel structure and its preparation method

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preparation example Construction

[0044] Such as image 3 As shown, the preparation method of the present invention adopts the surface sintering dissolution method, and the specific preparation process includes the following steps:

[0045] 1) Grinding: the aluminum alloy powder and salt powder are ball-milled into small particles, and the upper surface of the lower die punch 5 of the mold is provided with micro-grooves, and the cross-section of the micro-grooves is an inverted trapezoid;

[0046] 2) Powder spreading: Evenly drop a layer of absolute ethanol on the upper surface of the lower die punch 5, and then evenly spread a layer of salt powder particles 7, then evenly spread aluminum alloy powder particles 8 on the salt powder particle layer, and then put After punching 6, the upper die is placed in the female die 4, such as figure 2 shown;

[0047] 3) Cold pressing: cold pressing in the mold, the pressure is 100-400MPa, keep for 6-10 minutes;

[0048] 4) Hot pressing: place the mold in a resistance f...

Embodiment 1

[0061] The preparation method of the present invention adopts the surface sintering dissolution method, and the specific preparation process is:

[0062] The first step is to grind and spread powder, such as figure 2 As shown, the aluminum alloy powder and salt powder are ground into particles of suitable size, the size of the aluminum alloy powder particle 8 is about 20 μm, and the particle size of the salt powder particle 7 is about 50 μm; In the microchannel 2, a layer of absolute ethanol is evenly dripped on the upper surface, and then a layer of salt powder particles 7 is evenly spread, and then the aluminum alloy powder particles 8 are evenly spread on the top of the salt powder particles 7. The thickness of the salt powder particles 7 is about 300 μm, and the thickness of the aluminum alloy powder particles 8 is about 1.5 mm.

[0063] In the second step, cold pressing is carried out in a mold with a pressure of 100 MPa and kept for 10 minutes.

[0064] The third step...

Embodiment 2

[0087] The preparation method of the present invention adopts the surface sintering dissolution method, and the specific preparation process is:

[0088] The first step is to grind and spread powder, such as figure 2 As shown, the aluminum alloy powder and the salt powder are respectively ground into particles of suitable sizes, the size of the aluminum alloy powder particles 8 is about 50 μm, and the particle size of the salt powder particles 7 is about 180 μm; For the trapezoidal microchannel 2, a layer of absolute ethanol is evenly dripped on the upper surface, and then a layer of salt powder particles 7 is evenly spread, and then the aluminum alloy powder particles 8 are evenly spread on the top of the salt powder particles 7, and the salt powder particles 7 The thickness is about 350 μm, and the thickness of the aluminum alloy powder particles 8 is about 1.8 mm.

[0089] In the second step, cold pressing is carried out in a mold with a pressure of 300 MPa and kept for 8...

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Abstract

The invention discloses a multi-scale reaction carrier with a porous micro-channel structure and a preparation method of the multi-scale reaction carrier. A rectangular plate is used as a reaction carrier, a plurality of rows of micro-channels which are uniformly distributed at intervals in parallel are formed in the rectangular plate, the section of each micro-channel is of an inverted trapezoid shape, micro-pores which are uniformly distributed are formed in three surfaces in the micro-channels, the inside of each micro-pore is an uneven surface, and each micro-pore, each micro-channel and the reaction carrier forms a microcosmic-mesoscopic-macroscopic multi-scale reaction carrier; the multi-scale reaction carrier with the porous channel structure is obtained by sequentially grinding, spreading, cold-pressing, hot-pressing, salt dissolving and processing by adopting a surface sintering and dissolving method. According to multi-scale reaction carrier, one-time forming and manufacturing of a multi-scale composite structure can be realized, the specific area of a micro-reactor and the attachment area of the catalyst are effectively improved, and the attachment of the catalyst and the effective performing of the reaction are facilitated. The preparation method is simple and is low in cost, and can be applied to reactions of hydrogen production by steam reforming of methanol, and the like; the reaction efficiency is effectively improved, and the volume and the weight of a reactor are reduced.

Description

technical field [0001] The invention relates to a reaction carrier and a preparation method thereof, in particular to a multi-scale reaction carrier with a porous microchannel structure and a preparation method thereof. Background technique [0002] With the development of social economy and the increase of population, energy is being consumed at a faster and faster rate. At present, the research and development of new energy has become a worldwide problem and hot spot. As a clean and efficient energy utilization technology in the 21st century, hydrogen energy and fuel cells have become one of the global research hotspots. Hydrogen energy is an extremely superior new energy source. Its main advantages are: high combustion calorific value, non-polluting combustion products, and abundant hydrogen production resources. Hydrogen fuel cells have been vigorously developed due to their advantages of high energy efficiency, convenience and reliability; at present, pure hydrogen tra...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J32/00B01J35/10
Inventor 梅德庆冯艳冰钱淼姚喆赫陈子辰
Owner ZHEJIANG UNIV
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