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High-rigidity high-transparency polypropylene composite material

A technology of high transparency and composite materials, which is applied in the field of polypropylene composite materials, high rigidity and high transparency polypropylene composite materials, can solve the problems of reducing the haze of polypropylene, the decline of impact resistance, difficulties, etc., and achieve accelerated crystallization, Effect of improving rigidity and transparency, and refining spherulites

Inactive Publication Date: 2014-12-17
广东顺威赛特工程塑料开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the nucleating agents on the market mainly include sorbitol, phosphate, carboxylate, etc., but there are some disadvantages, such as phosphate and carboxylate nucleating agents, although they can improve the rigidity of polypropylene , but it will lead to a decrease in impact resistance and warpage, and it cannot effectively improve the transparency of the product
The sorbitol-based nucleating agent DBS can reduce the haze of polypropylene and greatly increase the transparency of the product, but its improvement in rigidity is not outstanding
Therefore, it is very difficult to use a single nucleating agent to increase the transparency of polypropylene while improving the rigidity of the product
However, due to the different nucleation mechanisms, some nucleating agents will fight against each other when mixed together, and cannot exert their respective effects. Therefore, the modified polypropylene on the market cannot improve rigidity and transparency at the same time, so as to meet the dual needs of the market for transparency and rigidity.

Method used

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Examples

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Embodiment Construction

[0016] A high-rigidity and high-transparency polypropylene composite material, which includes the following mass percentage components:

[0017]

[0018]

[0019] The sum of the percentages of the above components is 100%.

[0020] The preparation method of the present invention is to mix the raw materials from the first barrel feeding section of a twin-screw extruder with a length-to-diameter ratio of 32-68 into the twin-screw machine at a speed of 180-500 rpm and a temperature of 180-230 It can be extruded and granulated at ℃.

[0021] The present invention will be further described below in conjunction with specific embodiments:

[0022] The ratios of Examples 1-5 and Comparative Examples 1-3 are shown in Table 1:

[0023] Table 1:

[0024]

[0025] The preparation method of Example 1-5 is the same as that of Comparative Example 1-3:

[0026] After mixing the raw materials, the first section of the twin-screw extruder with a length-to-diameter ratio of 32-68 is added to the twin-scre...

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Abstract

The invention discloses a high-rigidity high-transparency polypropylene composite material, and belongs to the technical field of high polymer alloy materials. The high-rigidity high-transparency polypropylene composite material is compounded by 2-4wt% of nanoscale barium sulfate master batch, 0.1-0.3wt% p-tertiary butyl hydroxyl aluminum benzoate and 0.1-0.3wt% sorbitol acetal as a nucleating agent of polypropylene. According to the high-rigidity high-transparency polypropylene composite material, the nanoscale barium sulfate master batch is added to achieve a certain compatible effect on two nucleating agents, so that the two nucleating agents are prevented from resisting against each other; and meanwhile, the effects of nucleating heterogeneously, promoting the polypropylene to quicken crystallization and refining spherocrystal effects are achieved, so that the rigidity and the transparency of a PP (polypropylene) product are further improved.

Description

【Technical Field】 [0001] The invention relates to a polypropylene composite material, in particular to a high rigidity, high permeability and lateness polypropylene composite material, belonging to the technical field of polymer alloy materials. 【Background technique】 [0002] Polypropylene (PP for short) is one of the thermoplastic plastics with the largest output. It has the advantages of low density, good heat resistance, excellent bending fatigue resistance, excellent chemical stability and electrical properties, so it is widely used Automobiles, home appliances, office supplies, electronic appliances and other fields. Polypropylene is a highly crystalline polymer, so its transparency is far inferior to non-crystalline plastics such as PS and PC. In addition, polypropylene has a lower strength among plastics, and the parts are easily deformed, which greatly limits its further use in the market. Therefore, polypropylene must be modified to meet market demand. The most effec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K13/02C08K3/30C08K5/06C08K5/00B29C47/92B29C48/92
CPCC08K13/02C08K3/30C08K5/09C08K5/1575C08K2003/3045C08K2201/011C08L23/12C08L2201/10C08L2205/025C08L2205/24
Inventor 彭万汪克风胡天赐刘珍元段为胡世军
Owner 广东顺威赛特工程塑料开发有限公司
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