A kind of composite material prepreg for ultraviolet curing structure repair and preparation method thereof

Abstract

The invention provides a composite material prepreg for repairing glass fiber-reinforced resin-based structures with a certain thickness of ultraviolet light rapid curing and a preparation method thereof. This method uses ordinary free radical curable resin as the matrix, selects appropriate photoinitiators, thermal initiators and other additives to form a "light-thermal composite initiation system", uses glass fiber fabrics as reinforcing materials, and adopts appropriate composite processes. into a composite material prepreg with a certain thickness. The prepreg can be fully cured within 10 minutes by irradiating one side of ultraviolet light, and the thickness of one-time photocuring can reach more than 15mm. The invention solves the technical problem that the current ultraviolet light cannot cure large-thickness (10-15mm and above) composite material structural parts at one time, and makes the curing of the composite material prepreg more convenient and efficient. This light-curing resin and its composite materials have shown great application prospects and market potential in some specific fields such as trenchless repair of municipal drainage pipes.

Description

technical field

[0001] The invention relates to the field of materials, in particular to a composite material prepreg with a relatively large thickness (10-15mm) cured by one-time single-sided irradiation of ultraviolet light (within 10 minutes) and using a free radical curable resin as a matrix and its preparation method. Background technique

[0002] With the continuous development of the application of polymer composite materials, its curing methods are becoming more and more abundant to meet various actual needs. The rapid UV curing technology of composite resin matrix has developed rapidly in recent years. Compared with traditional thermal polymerization, UV curing has a series of outstanding advantages: ① Fast speed, which can be cured within a few seconds at the fastest, which greatly saves time , which improves production efficiency; ② less pollution, most of the diluents used for UV curing are active monomers, which participate in the curing reaction, and the solid...

Examples

Embodiment 1

[0033] The composite material prepreg (about 4mm thick) for UV curing structure repair provided by this embodiment consists of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator) and reinforcing material (⑤ Alkali-free glass fiber grid cloth) is prepared according to a certain proportion. The proportion of these five raw materials is calculated in parts by weight, which is 100:2:0.5:1:(80-100).

[0034] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0035] (1) Choose TH230 vinyl ester resin as the base material;

[0036] (2) Select Darocur1173 (2-hydroxyl-2-methyl-1-phenylacetone) as photoinitiator;

[0037] (3) Select stannous octoate matched with Darocur1173 as photosensitization accelerator;

[0038] (4) Select BPO (benzoyl peroxide) matched with Darocur1173 as thermal initiator;

[0039] (5) Blend the resin, select the non-alkali g...

Embodiment 2

[0043] The composite material prepreg (about 6 mm thick) for UV curing structure repair provided by this embodiment consists of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator) and reinforcing material (⑤ Alkali-free glass fiber grid cloth) is prepared according to a certain proportion. The proportion of these five raw materials is calculated in parts by weight, which is 100:2:0.5:1:(80-100).

[0044] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0045] (1) Choose TH230 vinyl ester resin as the base material;

[0046] (2) Select Irgacure184 (1-hydroxycyclohexyl phenyl ketone) photoinitiator;

[0047] (3) Select stannous octoate matching Irgacure184 as photosensitizer;

[0048] (4) AIBN (azobisisobutyronitrile) matching with Irgacure184 is selected as thermal initiator;

[0049] (5) extract approximately 80% styrene in the original ...

Embodiment 3

[0054] The composite material prepreg (about 8mm thick) that this embodiment provides for UV-curable structural repair is made of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator A, ⑤thermal initiator B) and the reinforcing material (⑥ non-alkali glass fiber grid cloth) are prepared in a certain proportion. The proportions of these six raw materials are calculated in parts by weight, which are 100:2:0.8:1:1 in turn: (80-100).

[0055] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0056] (1) Choose TH230 vinyl ester resin as the base material;

[0057] (2) Select Irgacure184 (1-hydroxycyclohexyl benzophenone) photoinitiator;

[0058] (3) select stannous octoate as photosensitizer;

[0059] (4) BPO (dibenzoyl peroxide) and MEKP (methyl ethyl ketone peroxide) are selected as thermal initiators A and B;

[0060] (5) extract approximate...

technical field

[0001] The invention relates to the field of materials, in particular to a composite material prepreg with a relatively large thickness (10-15mm) cured by one-time single-sided irradiation of ultraviolet light (within 10 minutes) and using a free radical curable resin as a matrix and its preparation method. Background technique

[0002] With the continuous development of the application of polymer composite materials, its curing methods are becoming more and more abundant to meet various actual needs. The rapid UV curing technology of composite resin matrix has developed rapidly in recent years. Compared with traditional thermal polymerization, UV curing has a series of outstanding advantages: ① Fast speed, which can be cured within a few seconds at the fastest, which greatly saves time , which improves production efficiency; ② less pollution, most of the diluents used for UV curing are active monomers, which participate in the curing reaction, and the solid...

Examples

Embodiment 1

[0033] The composite material prepreg (about 4mm thick) for UV curing structure repair provided by this embodiment consists of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator) and reinforcing material (⑤ Alkali-free glass fiber grid cloth) is prepared according to a certain proportion. The proportion of these five raw materials is calculated in parts by weight, which is 100:2:0.5:1:(80-100).

[0034] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0035] (1) Choose TH230 vinyl ester resin as the base material;

[0036] (2) Select Darocur1173 (2-hydroxyl-2-methyl-1-phenylacetone) as photoinitiator;

[0037] (3) Select stannous octoate matched with Darocur1173 as photosensitization accelerator;

[0038] (4) Select BPO (benzoyl peroxide) matched with Darocur1173 as thermal initiator;

[0039] (5) Blend the resin, select the non-alkali g...

Embodiment 2

[0043] The composite material prepreg (about 6 mm thick) for UV curing structure repair provided by this embodiment consists of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator) and reinforcing material (⑤ Alkali-free glass fiber grid cloth) is prepared according to a certain proportion. The proportion of these five raw materials is calculated in parts by weight, which is 100:2:0.5:1:(80-100).

[0044] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0045] (1) Choose TH230 vinyl ester resin as the base material;

[0046] (2) Select Irgacure184 (1-hydroxycyclohexyl phenyl ketone) photoinitiator;

[0047] (3) Select stannous octoate matching Irgacure184 as photosensitizer;

[0048] (4) AIBN (azobisisobutyronitrile) matching with Irgacure184 is selected as thermal initiator;

[0049] (5) extract approximately 80% styrene in the original ...

Embodiment 3

[0054] The composite material prepreg (about 8mm thick) that this embodiment provides for UV-curable structural repair is made of resin mixture (①resin matrix, ②photoinitiator, ③photosensitization accelerator, ④thermal initiator A, ⑤thermal initiator B) and the reinforcing material (⑥ non-alkali glass fiber grid cloth) are prepared in a certain proportion. The proportions of these six raw materials are calculated in parts by weight, which are 100:2:0.8:1:1 in turn: (80-100).

[0055] The above-mentioned composite material prepreg for UV curing structure repair is prepared by the following method, and the steps include:

[0056] (1) Choose TH230 vinyl ester resin as the base material;

[0057] (2) Select Irgacure184 (1-hydroxycyclohexyl benzophenone) photoinitiator;

[0058] (3) select stannous octoate as photosensitizer;

[0059] (4) BPO (dibenzoyl peroxide) and MEKP (methyl ethyl ketone peroxide) are selected as thermal initiators A and B;

[0060] (5) extract approximate...