The invention discloses a preparation method of a
carbon nanotube-montmorillonoid self-assembled nano
powder grafting glass fiber reinforced
resin composite material. The preparation method comprises the following steps: dispersing a
carbon nanotube in aprotic
solvent, modifying by virtue of organic amine, performing
hydrochloric acid salt forming reaction, and obtaining
carbon nanotube ammonium salt; ultrasonically dispersing the montmorillonoid and carbon
nanotube ammonium salt in the water, filtering, repeatedly washing, spraying and
drying to obtain carbon naontube-montmorillonoid self-assembled nano
powder; ultrasonically dispersing the nano
powder in a
silane coupling agent solution, uniformly spraying on the surface of glass fibers, an
vacuum drying to obtain nano powder
grafting glass fiber prefabricated body; and compounding the prefabricated body with resin by virtue of a
composite material forming process, thus obtaining the carbon
nanotube-montmorillonoid self-assembled nano powder
grafting glass fiber reinforced
resin composite material. By adopting the preparation method, the
dispersity of the carbon
nanotube can be effectively improved, and the interlayer distance of the montmorillonoid can be increased; and the nano powder is grafted to the glass fibers, so that the
dispersity in the
composite material can be further improved, the interface adhesion between the resin and the fibers can be improved, and the mechanical performance and
heat resistance of the
fiber composite material can be improved.