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Flexible composite electromagnetic wave absorbing material applied to sensing radio frequency identification for internet of things

A composite wave-absorbing material and radio frequency identification technology, applied in other chemical processes, chemical instruments and methods, etc., can solve the problems of high manufacturing cost, difficulty in uniform distribution, shortened reading and writing distance, etc., to increase external mechanical orientation, solve Frequency shift, improve the effect of impedance matching

Inactive Publication Date: 2015-02-11
宜宾金原复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the flexible composite absorbent material available in the market is used for anti-metal electronic tags. When it is used on metal objects, it can guarantee that the effective recognition distance can reach about 40% of the designed recognition distance at most, and the thickness is generally 0.5mm, which cannot meet the requirements of light and thin applications.
At the same time, although the high-permeability sheet-shaped sintered soft ferrite prepared by the tape casting method can ensure that the effective recognition distance reaches about 80% of the designed recognition distance, because it has been sintered at a high temperature of at least 1100 ° C, there are high manufacturing costs, Defects such as fragile products and difficult die-cutting
CN102300446A "An Electromagnetic Wave Composite Absorbing Material for Internet of Things Radio Frequency Identification" describes that the electromagnetic wave composite absorbing material used for Internet of Things radio frequency identification materials is composed of various soft magnetic materials and their mixtures, and its essence has Certain conductivity, although a certain proportion of resin is added, because the absorbent particles are difficult to achieve uniform distribution in the adhesive, contact between adjacent absorbent particles is inevitable, and absorbent particles are inevitably exposed on the surface of the product. When the absorbent particles are in contact with the surface of the metal object, its surface resistivity is also (1.0×105~1.0×106)Ω·m, so when the material is in a high-frequency electromagnetic field, it will generate a certain amount of inductance. When the material is pasted or attached to the electronic tag, the inductance generated by the material will affect the inductance of the inherent design of the tag, thereby changing the inductance of the electronic tag, changing the impedance of the electronic tag, and generating the returned signal frequency point and design signal The frequency point shifts, which affects the exchange of communication signals. In practical applications, it is reflected as: the reading and writing distance becomes shorter or the stability of the reading and writing distance is poor or the label compatibility is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. Fe-Si-Al alloy flake powder (aspect ratio greater than 5) is selected as the electromagnetic interference absorber, and the electromagnetic wave absorber particles are in the range of 0.5 microns to 40 microns.

[0026] 2. Use Ni-Zn ferrite 0.1-2 micron spherical particles as composite particles, and use oleic acid for surface activation treatment.

[0027] 3. Use commercially available 135A CPE resin as an organic bridge, dissolve in commercially available aromatic hydrocarbons or halogenated hydrocarbons, the viscosity of the resin solution is 300mPa·s, and then add the activated composite particles for mixing and stirring. The amount of resin solution According to the particle volume ratio of the electromagnetic wave absorber is about 92%:8%, the soft magnetic ferrite magnetic suspension liquid is obtained.

[0028]4. Add Fe-Si-Al alloy flake powder to Ni-Zn ferrite magnetic suspension liquid, the volume ratio of Fe-Si-Al alloy flake powder to Ni-Zn ferrite magnet...

Embodiment 2

[0031] 1. Select Fe-Si-Al alloy flake powder (aspect ratio greater than 5), Fe-Ni-Mo alloy flake powder mixture as electromagnetic wave absorber, Fe-Si-Al alloy flake powder and Fe-Ni-Mo The weight ratio of the alloy flake powder is 70%:30%, and the particle size of the electromagnetic wave absorbing agent is in the range of 0.9 microns to 40 microns.

[0032] 2. Ni-Cu-Zn ferrite spherical particles with a thickness of 0.1 micron to 2 microns are used as composite particles, and soybean lecithin is used for surface activation treatment.

[0033] 3. Use commercially available PVP as the organic bridge, and use ethanol as the organic solvent. After dilution, the viscosity of the organic bridge is 100mPa·s, and then add the activated composite particles for mixing and stirring. The amount of the resin solution is based on the volume ratio of the electromagnetic wave absorber particles. About 90%: 10%, the Ni-Cu-Zn system ferrite magnetic levitation liquid is obtained.

[0034] 4...

Embodiment 3

[0037] 1. Fe-Cr-Al-Si alloy flake powder (length-to-diameter ratio greater than 5) is selected as the electromagnetic interference absorber, and the electromagnetic wave absorber particles are in the range of 0.1 microns to 40 microns.

[0038] 2. Spherical particles of Mn-Zn ferrite with a thickness of 0.1 micron to 2 microns are used as composite particles, and the surface is activated with oleic acid.

[0039] 3. Use commercially available PU as an organic bridge, dissolve it in acetone, the viscosity of the resin solution is 200mPa·s, and then add the activated composite particles for mixing and stirring. The amount of the resin solution is about 95% according to the volume ratio of the electromagnetic wave absorber particles : 5%, to obtain Mn-Zn series ferrite magnetic levitation liquid.

[0040] 4. Add Fe-Si-Al alloy flake powder to Mn-Zn ferrite ferrite magnetic suspension liquid, the volume of Fe-Si-Al alloy flake powder and Mn-Zn ferrite ferrite magnetic suspension l...

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Abstract

The invention provides a flexible composite electromagnetic wave absorbing material applied to sensing radio frequency identification for internet of things. The flexible composite electromagnetic wave absorbing material comprises the following components in percentage by mass: 60%-95% of composite anti-electromagnetic interference absorbent particles and 40%-5% of an adhesive, wherein the composite anti-electromagnetic interference absorbent particles are formed by mixing, drying and dispersing of 0.1-40 microns of soft magnetic metal particles and soft magnetic levitation liquid, of which the volume ratio is (60%-70%) to (40%-30%); the soft magnetic levitation liquid is formed by stirring and mixing of an organic bridging material which is diluted until the viscosity is within the range of 100-300mPa.s, and surface-activated composite particles; and the volume ratio of the organic bridging material to the composite particles is (90%-95%) to (10%-5%). Through the organic bridging material, the effects on an electronic tag caused by electromagnetic interference under various environments are reduced to the minimal extent; impedance matching of the electromagnetic wave absorbing material and an electronic tag antenna is improved; and the frequency offset phenomenon caused by encapsulation of the wave absorbing material is solved, thus the read reliability of the tag and the compatibility of actual use of the tag are ensured.

Description

technical field [0001] The invention relates to an electromagnetic wave absorbing material, in particular to a flexible electromagnetic wave composite absorbing material used for sensing radio frequency identification of the Internet of Things. Background technique [0002] Radio Frequency Identification (RFID) technology is an important part of the Internet of Things, and Radio Frequency Identification (RFID) technology is essentially an automatic identification technology. Usually, the RFID system consists of three main parts: electronic tags, readers and data management systems. The electronic tag consists of an antenna and an RFID chip, and each chip contains a unique identification code, which is used to indicate the object to which the electronic tag is attached. The reader is used to read and write the information in the electronic tag. The reader communicates with other computers or systems through the network to complete the information acquisition, interpretation ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/00
Inventor 曾华胡健黄道平宋强
Owner 宜宾金原复合材料有限公司
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