Cerium-niobium-zirconium composite oxide catalyst, preparation method and uses thereof
A technology of composite oxides and catalysts, applied in the direction of metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problems of narrow temperature window, poor low temperature activity, etc., and achieve The effect of widening the temperature window, improving the low-temperature activity, and making the preparation process simple and easy
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Embodiment 1
[0041] Completely dissolve a certain amount of cerium nitrate and zirconium nitrate in a certain amount of deionized water, and then add fully dissolved NbCl 5 Aqueous solution and excess urea precipitant, wherein urea / (cerium nitrate + zirconium nitrate + niobium pentachloride) molar ratio is 10:1, finally add deionized water to the above mixed solution to a total volume of 250ml, and put it in a 90°C water bath Under the condition of continuous stirring for 12h. After the above mixed solution is cooled to room temperature, the obtained precipitate is fully suction-filtered and washed to neutral with deionized water, and then the precipitate is dried in an oven at 100°C for 12h, and finally roasted at 500°C for 3h in an air atmosphere , to get the composition as CeNb a Zr 2 o x The cerium niobium zirconium composite oxide catalyst, wherein a is 0.1.
Embodiment 2
[0043]All the other conditions are the same as in Example 1, except that the control a is 0.5.
Embodiment 3
[0045] All the other conditions are the same as in Example 1, except that the control a is 1.
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