Light emitting device
A light-emitting device and technology for emitting red light, applied in the fields of lighting technology, display and optoelectronics, can solve the problems of harsh preparation method, high price, low brightness, etc., and achieve the effects of low cost, improved light-emitting brightness and novel structure.
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Embodiment 1
[0033] Example 1: Ca 0.8 Li 0.1 MoO 4-x f x : Eu 0.1 Preparation of fluorescent materials
[0034] Weigh various raw materials CaCO according to stoichiometric composition 3 , Li 2 CO 3 , Eu 2 o 3 , MoO 3 , NH 4 F, where NH is weighed 4 The molar masses of F are 0, 0.01, 0.02, 0.05, 0.08, 0.10, that is, the x values are 0, 0.01, 0.02, 0.04, 0.08, 0.10. After the above 6 groups of raw materials are fully ball-milled and mixed evenly, put them into a 99% porcelain crucible, keep warm at 500°C for 5 hours in an air atmosphere, then raise the temperature to 850°C and keep warm for 4 hours, cool the sintered body, crush, sieve, and classify. The chemical composition in the present invention is obtained as Ca 0.8 Eu 0.1 Li 0.1 MoO 4 : NH 4 F fluorescent material. where Ca 0.8 Li 0.1 MoO 3.92 f 0.08 : Eu 0.1 The excitation spectrum of figure 1 As shown, the emission spectra under different excitation light are as figure 2 Its maximum emission is shown at 6...
Embodiment 2
[0035] Example 2: Ca 0.72 Li 0.1 MoO 4-x f x : Eu 0.96 SM 0.04 Preparation of fluorescent materials
[0036] Weigh various raw materials CaCO according to stoichiometric composition 3 , Li 2 CO 3 , Eu 2 o 3 , MoO 3 , SmO 3 , NH 4 F, where NH is weighed 4 The molar masses of F are 0, 0.01, 0.02, 0.05, 0.08, 0.10, that is, the x values are 0, 0.01, 0.02, 0.04, 0.08, 0.10. After the above 6 groups of raw materials are fully ball-milled and mixed evenly, put them into a 99% porcelain crucible, keep warm at 500°C for 5 hours in an air atmosphere, then raise the temperature to 850°C and keep warm for 4 hours, cool the sintered body, crush, sieve, and classify. The chemical composition in the present invention is obtained as Ca 0.72 Li 0.1 O 4-x f x : Eu 0.96 SM 0.04 fluorescent material. Its excitation and emission spectral characteristics are basically consistent with those of Example 1. Different content of NH 4 The effect of F on the luminous intensity at...
Embodiment 3
[0037] Example 3: LiMo 2 o 8-x f 2x : Preparation of Eu fluorescent material
[0038] Weigh various raw materials CaCO according to stoichiometric composition 3 , Li 2 CO 3 , Eu 2 o 3 , MoO 3 , LiF, where the molar mass of LiF is weighed as 0, 0.01, 0.02, 0.05, 0.08, 0.10, that is, the x value is 0, 0.01, 0.02, 0.04, 0.08, 0.10. After the above 6 groups of raw materials are fully ball-milled and mixed evenly, put them into a 99% porcelain crucible, keep warm at 500°C for 5 hours in an air atmosphere, then raise the temperature to 850°C and keep warm for 4 hours, cool the sintered body, crush, sieve, and classify. Obtaining the chemical composition in the present invention is LiMo 2 o 8-x f 2x : Eu fluorescent material. Its excitation and emission spectral characteristics are basically consistent with those of Example 1. The influence of different contents of LiF on the luminous intensity at 615nm is as follows: image 3 Shown in line 3.
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