Combined polyether for flame-retardant bulk rigid polyurethane foams and application method of combined polyether

A technology of rigid foam and combined polyether, which is applied in the field of combined polyether, can solve problems such as rotten bottom, foam cracks, cavities, etc., and achieve the effect of wide source of raw materials, low thermal conductivity, and reduced thermal conductivity

CN104387549AActive Publication Date: 2015-03-04SHANDONG INOV NEW MATERIALS CO LTD
3 Cites 10 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2015-03-04

Smart Images

  • Figure 1
    Figure 1
  • Figure 2
    Figure 2
  • Figure 3
    Figure 3
Patent Text Reader

Abstract

The invention relates to combined polyether for flame-retardant bulk rigid polyurethane foams and an application method of the combined polyether and belongs to the technical field of the combined polyether. The combined polyether for the flame-retardant bulk rigid polyurethane foams is prepared from the following components including flame-retardant polyester polyol A, flame-retardant polyester polyol B, flame-retardant polyester polyol C, a crosslinking agent, a foam stabilizer A, a foam stabilizer B, a chemical foaming agent, a catalyst, a physical foaming agent, a flame retardant A and a flame retardant B. The combined polyether for the flame-retardant bulk rigid polyurethane foams is wide in raw material source and is low in cost. With the adoption of the combined polyether, the flame-retardant bulk rigid polyurethane foams prepared by the combined polyether are good in flame retardancy, low in thermal conductivity, good in airtightness and stable in quality performance. The invention also provides the application method of the combined polyether for the flame-retardant bulk rigid polyurethane foams. The application method is simple in process, is easily operated, is low in volatilization and is high in production efficiency without three wastes.
Need to check novelty before this filing date? Find Prior Art

Description

technical field

[0001] The invention relates to a combination polyether for flame-retardant bulk polyurethane rigid foam and an application method thereof, belonging to the technical field of combination polyether. Background technique

[0002] Since the implementation of building energy conservation in my country in the 1980s, the external wall insulation materials are mainly inorganic insulation materials, such as rock wool, perlite, glass wool, and rubber powder polystyrene particles. These insulation materials are cheap, but the insulation effect is poor, the thermal conductivity is generally above 0.06W / M.K, easy to crack and leak, technically it is difficult to meet the 65% energy-saving standard.

[0003] In recent years, fires involving building external insulation materials have successively occurred in Nanjing Central International Plaza, Harbin Jingwei 360-degree Twin Star Building, Jinan Olympic Sports Center, Beijing CCTV New Site Affiliated Cultural Center, Sha...

Examples

Embodiment 1

[0037] (1) Preparation of component A, 100kg: Weigh flame-retardant polyester polyol CF-6255 (functionality 2, molecular weight 440, commercially available product of Jiangsu Fusheng New Material Co., Ltd.), 30kg, flame-retardant polyol FR- 2026 (functionality 2.3, molecular weight 640, commercially available product of Wanhua Chemical Group Co., Ltd.), 15kg, polyether polyol SA460 (functionality 6, molecular weight 730, commercially available product of Shandong Bluestar Dongda Chemical Co., Ltd.), 5.3kg, crosslinking agent 403 (functionality 3, molecular weight 220, commercially available product of Shandong Bluestar Dongda Chemical Co., Ltd.), 8kg, foam stabilizer: B8545 (commercially available product of Evonik Degussa Specialty Chemical Co., Ltd.) . Potassium mixture, weighing 1.4kg, 1.5kg and 1.1kg respectively, physical blowing agent 1,1-dichloro-1-fluoroethane, 10.1kg, flame retardant A tris(2-chloropropyl) phosphoric acid Ester, 10kg, flame retardant B triethyl phosp...

Embodiment 2

[0042](1) Prepare component A, 100kg: Weigh flame-retardant polyester polyol 6300 (functionality 2.2, molecular weight is 390, commercially available product of Jiangsu Fusheng New Material Co., Ltd.), 40kg, flame-retardant polyol FR-2026 ( Functionality 2.7, molecular weight 640, commercially available product of Wanhua Chemical Group Co., Ltd.), 5kg, polyether polyol 6207 (functionality 6, molecular weight 730, commercially available product of Hebei Yadong Chemical Group Co., Ltd.), 5kg, cross-linked Agent MN450 (functionality 3, molecular weight 370, commercially available product of Shandong Bluestar Dongda Chemical Co., Ltd.), 2kg, foam stabilizer: B8525 (commercially available product of Evonik Degussa Specialty Chemical Co., Ltd.), 2.0kg, ten Sodium dialkylbenzenesulfonate, 0.3kg, deionized water, 3.5kg, catalyst selection N,N dimethylcyclohexylamine, N,N dimethylbenzylamine and 1,3,5-tri(dimethylamino Propyl) the mixture of hexahydrotriazine, the weight is respectivel...

Embodiment 3

[0047] (1) Prepare component A, 100kg: Weigh flame-retardant polyester polyol 6255 (functionality 2.1, molecular weight is 440, commercially available product of Jiangsu Fusheng New Material Co., Ltd.), 35kg, flame-retardant polyol FR-1830 ( Functionality 2.5, molecular weight 620, commercially available product of Wanhua Chemical Group Co., Ltd.), 10kg, polyether polyol SA460 (functionality 6, molecular weight 730, commercially available product of Shandong Bluestar Dongda Chemical Co., Ltd.) 7kg, delivery Joint agent MN450 (functionality 3, molecular weight 370, commercially available product of Shandong Bluestar Dongda Chemical Co., Ltd.), 3kg, foam stabilizer: L-6950 (commercially available product of Momentive Silicone Material (Shanghai) Co., Ltd.), 1.0kg, polysorbate, 0.5kg, water, 1.3kg, catalyst potassium acetate, 2.0kg, physical blowing agent 1,1-dichloro-1-fluoroethane, 20kg, flame retardant A three (2- Chloropropyl) phosphate, 10.2kg, flame retardant B triethyl pho...