Medium for copper electrode ceramic capacitor and preparation method thereof
A technology of ceramic capacitors and copper electrodes, which is applied in the dielectric field of capacitors, can solve the problems of low dielectric loss, inability to meet high dielectric constant, performance deterioration of ceramic capacitors, etc., and achieve the effect of low loss
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Embodiment 1
[0036] First, BaTiO was synthesized by a solid-phase method 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Ba 4 LiNb 3 o 12 .
[0037] BaTiO 3 Prepared by the following process: equipped with BaCO at a molar ratio of 1:1 3 and TiO 2 , then for BaCO 3 and TiO 2 Grind and mix well; BaCO 3 and TiO 2 The mixed material was put into an alumina crucible and kept at 1260°C for 120 minutes to obtain BaTiO 3 . BaTiO 3 After cooling, grind and pass through a 200-mesh sieve for later use.
[0038] MgTiO 3 The following process is used to prepare: equip MgCO with a molar ratio of 1:1 3 and TiO 2 , then for MgCO 3 and TiO 2 Grind and mix well; then MgCO 3 and TiO 2 The mixed material was put into an alumina crucible and kept at 1300°C for 120 minutes to obtain MgTiO 3 . The obtained MgTiO 3 After cooling, grind and pass through a 200-mesh sieve for later use.
[0039] CaZrO 3 Prepared by the following process: equip CaCO with a molar ratio of 1:1 3 and ZrO 2 , then for CaCO ...
Embodiment 2
[0057] In this example, BaTiO 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Ba 4 LiNb 3 o 12 The preparation process is the same as in Example 1.
[0058] In this embodiment, the preparation method of the medium that can be used for copper electrode ceramic capacitors includes the following steps in sequence:
[0059] (1) Equipped with BaTiO in proportion 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Co 2 o 3 , Y 2 o 3 , V 2 o 5 and Ba 4 LiNb 3 o 12 ;
[0060] With reference to Table 1, the weight percentages of various raw materials equipped are as follows: BaTiO 3 54%, MgTiO 3 4%, CaZrO 3 20%, ZrTiO 4 12%, Co. 2 o 3 1%, Y 2 o 3 1%, V 2 o 5 1%, Ba 4 LiNb 3 o 12 7%;
[0061] (2) The BaTiO prepared in step (1) 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Co 2 o 3 , Y 2 o 3 , V 2 o 5 and Ba 4 LiNb 3 o 12 Pulverize and mix evenly to obtain a mixture;
[0062] In this embodiment, a planetary ball mill is used to carry out ball milling on the prepared r...
Embodiment 3
[0073] In this example, BaTiO 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Ba 4 LiNb 3 o 12 The preparation process is the same as in Example 1.
[0074] In this embodiment, the preparation method of the medium that can be used for copper electrode ceramic capacitors includes the following steps in sequence:
[0075] (1) Equipped with BaTiO in proportion 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Co 2 o 3 , Y 2 o 3 , V 2 o 5 and Ba 4 LiNb 3 o 12 ;
[0076] With reference to Table 1, the weight percentages of various raw materials equipped are as follows: BaTiO 3 91%, MgTiO 3 1%, CaZrO 3 4%, ZrTiO 4 3%, Co. 2 o 3 0.1%, Y 2 o 3 0.1%, V 2 o 5 0.1%, Ba 4 LiNb 3 o 12 0.7%;
[0077] (2) The BaTiO prepared in step (1) 3 , MgTiO 3 , CaZrO 3 , ZrTiO 4 、Co 2 o 3 , Y 2 o 3 , V 2 o 5 and Ba 4 LiNb 3 o 12 Pulverize and mix evenly to obtain a mixture;
[0078] In this embodiment, a planetary ball mill is used to carry out ball milling on the prep...
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