Spraying-free ABS composition with special aesthetic effect, preparation method and applications thereof

Abstract

The invention discloses a spraying-free ABS composition with a special aesthetic effect, a preparation method and applications thereof. The ABS composition consists of 70 to 98 wt% of ABS resin, 1 to 25 wt% of polymer-coated microspheres with a special effect, 0 to 10 wt% of compatilizer, 0.1 to 1 wt% of antioxidant, and 0.1 to 0.5 wt% of processing aid. The powder with a special effect is coated by aqueous dispersion liquid to form microspheres, then the microspheres are dispersed into the ABS resin so as to improve the compatibility between the powder with a special effect and the ABS resin, thus the flow marks on the surface during the extrusion or injection moulding process can be eliminated, and the weld lines can be reduced. The prepared spraying-free ABS composition has a prominent metal texture and special aesthetic effects such as pearl-liked sparkling, and the application range of spraying-free materials is greatly enlarged.

Description

[0001] The invention belongs to the field of polymer materials, and in particular relates to a spray-free ABS composition with special aesthetic effects, a preparation method and application thereof. Background technique [0002] As people pay more and more attention to environmental issues, spray-free material products are gradually showing their competitiveness. Spray-free aesthetic resins can replicate the bright and colorful hues produced by spray paint, pearlescent, glitter effects, metallic luster and texture, etc. Special effects, so as to meet the diverse and differentiated customer needs, and can truly achieve energy saving and emission reduction in the production process, and can be widely used in handicrafts, toys, home appliances, automobiles, electronic products, sporting goods and office supplies and other fields. [0003] At present, the more common preparation method of spray-free resin is to add metal powder, pearl powder and other effect powders with special c...

AI Technical Summary

Problems solved by technology

By dispersing the special effect powder into the matrix resin, the special effect powder is connected to each other to form a continuous special effect film, which covers the base material and presents a special effect texture, although the special effect powder is directly added to the resin base. , can achieve a special glossy effect, but the compatibility between the matrix resin and the special effect powder is poor. Under the strong pressure and strong shear conditions of extrusion or injection molding, it is difficult for the special effect powder and the matrix resin material to achieve the same fluidity, especially It is a product with a complex structure. The special effect powder oriented along the flow direction occurs and the melt flow turns, the flow velocity is unstable, and the melt merges, etc., causing the special effect powder to be unevenly distributed in the melt and easy to form on the surface of the product. Defects such as flow marks and weld lines seriously prevent and limit the market promotion and application of this type of spray-free material

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