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Metal nanoparticle complex and method for producing same

A metal nanoparticle and manufacturing method technology, applied in nanotechnology, nanotechnology, metal processing equipment and other directions, can solve the problems of less ruthenium metal precipitation and larger metal size, and achieve the effect of high activity

Inactive Publication Date: 2015-05-20
KYOTO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Non-Patent Document 3 discloses a technique of depositing ruthenium inside MOF by CVD, but this method has the following problems: ruthenium is easily deposited on the surface of MOF, the size of the metal deposited near the surface becomes large, and the metal near the center The precipitation of ruthenium metal is reduced

Method used

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  • Metal nanoparticle complex and method for producing same
  • Metal nanoparticle complex and method for producing same
  • Metal nanoparticle complex and method for producing same

Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0088] Manufacturing example 1: Preparation of PCP complex

[0089] In a 3000ml pear-shaped flask, add 2000ml of DMF-ethanol-water (1:1:1 by volume) and Ni(NO 3 ) 2 ·6H 2 O (23.8g), 2,5-dihydroxyterephthalic acid (H 4 dhtp, 4.8g), stirred and reacted at 100°C for 5 days. The precipitated three-dimensional structure metal complex (Ni 2 (dhtp)) was recovered by suction filtration, and washed with methanol and water. Then, dry under reduced pressure at 25°C for 24 hours to obtain the target metal complex (Ni 2 (dhtp)) 12g. Obtainment of the target metal complex was confirmed by powder X-ray structural analysis. Hereinafter, the obtained metal complex may be referred to as "Ni-MOF-74".

manufacture example 2

[0090] Manufacturing example 2: Preparation of PCP complex

[0091] In a 300ml pear-shaped flask, add 200ml of DMF-ethanol-water (1:1:1 by volume) as a solvent, Co(NO 3 ) 2 ·6H 2 O (2.4g), 2,5-dihydroxyterephthalic acid (H 4 dhtp, 0.5 g), stirred at 100° C. for 5 days, and made to react. The precipitated three-dimensional structure metal complex (Co 2 (dhtp)) was recovered by suction filtration, and washed with methanol and water. Next, drying was performed at 25° C. under reduced pressure for 24 hours to obtain 0.8 g of the target metal complex (Co2(dhtp)). Obtainment of the target metal complex was confirmed by powder X-ray structural analysis.

Embodiment 1

[0093] The Ni complex obtained in Production Example 1 was heated under reduced pressure (under vacuum) using a vacuum pump at the reaction temperature and reaction time shown in Table 2 below to produce the Ni complex of the present invention.

[0094] 【Table 2】

[0095] Synthetic conditions and batch names

[0096]

[0097] For the obtained Ni complex, the results of powder X-ray diffraction are shown in figure 1 , the scanning transmission electron microscope (STEM) photograph is shown in figure 2 , the High Resolution Transmission Electron Microscopy (HRTEM) photographs are shown in image 3 , the Raman measurement results are shown in Figure 4 , Figure 5 , the N under 77K 2 The results of the adsorption are shown in Figure 6 .

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Abstract

The present invention provides a metal nanoparticle complex characterized by having such a structure that metal nanoparticles are dispersed in an organic structure, wherein the organic structure comprises a structure of a porous coordination polymer (PCP) containing both a metal and a polyvalent ligand capable of reducing the metal or a structure of a metal-organic framework (MOF) and carbon.

Description

technical field [0001] The invention relates to a metal nanoparticle complex and a manufacturing method thereof. [0002] In addition, in this specification, the collective term of MOF and PCP may be described as "PCP". Background technique [0003] Many PCP / metal nanoparticle complexes have been developed so far, but in order to effectively realize the reaction of the complex, a complex in which metal nanoparticles are directly connected inside PCP is required. In addition, from the viewpoint of the production cost of the composite, a method for producing the PCP / metal nanoparticle composite simply and reliably is required. [0004] In order to produce PCP / metal nanoparticles, the following methods are adopted: synthesize metal nanoparticles, coat them with PCP, or synthesize metal nanoparticles inside (or outside) the synthesized PCP, and embed metal nanoparticles in PCP . [0005] According to Non-Patent Document 1, in order to composite metal nanoparticles after prefa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G79/00B01J23/75B01J23/755B01J37/16B22F9/24B82Y30/00B82Y40/00B22F1/054
CPCB01J23/755B22F9/24B82Y30/00B82Y40/00B01J21/18B01J37/0209H01M8/1013H01M4/9083B01J37/086B01J31/1691B01J31/2239B01J2231/62B01J2231/70B01J2231/763B01J2531/845B01J2531/847Y02E60/50B22F1/054B01J35/33B01J2235/15B01J2235/00B01J35/45B01J2235/30B01J35/23B01J35/30B01J23/75B01J31/2208B01J2540/12
Inventor 北川宏山田铁兵小林浩和向吉惠
Owner KYOTO UNIV
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