Reservoir protection agent composition and drilling fluid for medium-permeability reservoir and application of drilling fluid
The technology of a reservoir protective agent and composition is applied in the directions of drilling composition, earthwork drilling, flushing wellbore, etc., which can solve the problem of filtrate intrusion into the reservoir, water sensitivity, water lock damage, and poor sealing performance. and other problems to achieve the effect of good rheological properties
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[0038] According to the present invention, the above-mentioned reservoir protection agent can be carried out by conventional polymerization reaction, as long as the structure and composition characteristics of the reservoir protection agent in the present invention can be satisfied, preferably, the preparation of the reservoir protection agent of the present invention The method comprises: in the presence of an initiator, contacting a compound with a structure shown in formula (4), a compound with a structure shown in formula (5), a compound with a structure shown in formula (6) and an emulsifier in water to obtain an emulsified mother liquor and Carry out polymerization reaction; Wherein, the molar ratio of the compound of structure shown in formula (4), the compound of structure shown in formula (5) and the compound of structure shown in formula (6) is 1:0.3-1.5:0.3-1 ; The weight average molecular weight of the polymer obtained by the polymerization reaction is 60000-70000g / ...
preparation example 1
[0073] Styrene (62g, 0.59mol), butyl acrylate (35.6g, 0.28mol) and 2-acrylamido-2-methylpropanesulfonic acid (42.1g, 0.2mol) were added to 100mL of water to form a primary mother liquor, and then Add 5.9g of sodium dodecylbenzenesulfonate (purchased from Chengdu McCarthy Chemical Co., Ltd.) to obtain the emulsified mother liquor, and add 0.6g of ammonium persulfate to the emulsified mother liquor after passing nitrogen gas for 30min and then adding 0.6g of ammonium persulfate to 70°C, and then continue Raise the temperature to 75°C, and keep it warm for 5 hours; after the reaction is completed, cool the reaction solution to 30°C, add 20% by weight of sodium hydroxide aqueous solution until the pH is 8.5, then add 10mL of methanol to stir and precipitate, and place the obtained precipitate at 100°C Dry and pulverize to obtain 131 g of the protective agent solid A1 (light yellow powder) of the present invention, with a particle size of 0.7-0.8 μm. Its weight-average molecular we...
preparation example 2
[0075] p-methylstyrene (52 g, 0.44 mol), ethyl acrylate (25.6 g, 0.26 mol) and 2-acrylamido-2-methylpropanesulfonic acid (62.1 g, 0.3 mol) were added to 100 mL of water to form a primary Mother liquor, then add 6.7g of sodium lauryl sulfate (purchased from Zibo Jujin Chemical Co., Ltd.) to obtain emulsified mother liquor, and add 0.7g of azobisisobutyronitrile to the emulsified mother liquor after passing nitrogen for 30min and then warming up to 75°C , and then continue to heat up to 85 ° C, and heat preservation reaction 4.5h; after the reaction is completed, cool the reaction solution to 30 ° C, add 30% by weight of sodium hydroxide aqueous solution to pH 9.5, then add 10 mL of methanol to stir and precipitate, and the obtained precipitate Dry and pulverize at 100° C. to obtain 145 g of the protective agent solid A2 (light yellow powder) of the present invention, with a particle size of 0.7-0.8 μm. Its weight-average molecular weight is 64582g / mol, and molecular weight dist...
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