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Novel diffusion process capable of increasing polysilicon open-circuit voltage

A technology of diffusion process and open circuit voltage, which is applied in the field of diffusion process of solar cells, can solve the problems of high surface doping concentration, low internal doping concentration, and high recombination speed on the surface of silicon wafers, so as to reduce the surface recombination speed and improve the open circuit voltage. voltage, the effect of reducing the width

Inactive Publication Date: 2015-07-01
JETION SOLAR HLDG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The PN junction formed in the prior art has a low internal doping concentration and a high surface doping concentration, which leads to a high surface recombination speed of the silicon wafer, which reduces the open circuit voltage of the solar cell, and a low open circuit voltage will reduce the efficiency of the cell.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The embodiment of the present invention discloses a diffusion process for making a solar cell, which includes the following steps:

[0019] 1) In the first step, put the silicon wafer into the diffusion furnace and raise the temperature to 800°C;

[0020] 2) Source: At this temperature, diffuse nitrogen, oxygen and purge nitrogen with a flow ratio of 3:1:17 are introduced into the diffusion furnace tube, and the diffusion nitrogen, oxygen and purge nitrogen are respectively 0.9L: 0.3L: 5.1L, the whole process takes 10 minutes;

[0021] 3) Heating push-off: It takes 20 minutes to raise the temperature inside the diffusion furnace tube to 850°C. During the entire heating process, purge nitrogen and oxygen with a flow ratio of 10:3 are continuously fed into the diffusion furnace tube, and the total amount of feeding is 10L. ;

[0022] 4) It takes 20 minutes to reduce the temperature inside the diffusion furnace tube to 750°C, and continuously blow 20L of purge nitrogen g...

Embodiment 2

[0025] The embodiment of the present invention discloses a diffusion process for making a solar cell, which includes the following steps:

[0026] 1) In the first step, put the silicon wafer into the diffusion furnace and raise the temperature to 800°C;

[0027] 2) Ventilation: At this temperature, diffuse nitrogen, oxygen and purge nitrogen with a flow ratio of 3:1:17 are introduced into the diffusion furnace tube. 0.7L, 11.9L, the whole process takes 25 minutes;

[0028] 3) Heating push-off: It takes 15 minutes to raise the temperature inside the diffusion furnace tube to 850°C. During the whole heating process, the purge nitrogen and oxygen with a flow ratio of 10:3 are continuously fed into the diffusion furnace tube, and the total amount of feeding is 8L. ;

[0029] 4) Reduce the temperature inside the diffusion furnace tube to 780°C in 20 minutes, and continuously inject 15 L of nitrogen gas into the diffusion furnace tube during the entire cooling process;

[0030] 5...

Embodiment 3

[0032] The embodiment of the present invention discloses a diffusion process for making a solar cell, which includes the following steps:

[0033] 1) In the first step, put the silicon wafer into the diffusion furnace and raise the temperature to 800°C;

[0034] 2) Ventilation: At this temperature, diffuse nitrogen, oxygen and purge nitrogen with a flow ratio of 3:1:17 are introduced into the diffusion furnace tube, and the diffusion nitrogen, oxygen and purge nitrogen are respectively 3L and 1L. , 17L, the whole process takes 20 minutes;

[0035] 3) Heating push-off: It takes 25 minutes to raise the temperature inside the diffusion furnace tube to 860°C. During the whole heating process, purge nitrogen and oxygen with a flow ratio of 10:3 are continuously fed into the diffusion furnace tube, and the total amount of feeding is;

[0036] 4) It takes 25 minutes to reduce the temperature inside the diffusion furnace tube to 800°C, and continuously blow 25L of purge nitrogen gas ...

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PUM

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Abstract

The invention discloses a novel diffusion process capable of increasing polysilicon open-circuit voltage. The novel diffusion process includes: 1), placing a silicon wafer in a diffusion furnace, and heating to 800 DEG C; 2), feeding a source, namely feeding diffusion nitrogen, oxygen and purging nitrogen into the diffusion furnace at the temperature according to a feeding flow ratio of 3:1:17 for 10-25 minutes; 3), heating for knot pushing, namely, using 10-25 minutes to increase temperature in a diffusion furnace pipe to be 850-860 DEG C, and continuously feeding purging nitrogen and oxygen with a feeding flow ratio of 10:3 into the diffusion furnace pipe in the whole process of heating; 4), using 10-25 minutes to lower temperature in the diffusion furnace pipe to be 750-800 DEG C, and continuously feeding purging nitrogen into the diffusion furnace pipe in the whole process of cooling; 5), taking the silicon wafer out. By the novel diffusion process, surface compositing speed of the silicon wafer can be lowered, knot depth can be increased, width of a polysilicon substrate can be reduced, and open-circuit voltage of a solar cell is increased.

Description

technical field [0001] The invention relates to the field of manufacturing crystalline silicon solar cells, in particular to a diffusion process for solar cells. Background technique [0002] At present, the main manufacturing process of monocrystalline and polycrystalline silicon solar cells has been standardized. The main production steps are: cleaning and preparing the suede on the surface of silicon wafers, diffusion to form PN junctions, dry and wet etching to remove peripheral and back junctions, and PECVD to form anti-reflection nitriding Silicon film, screen printing to form electrodes, and sintering to form ohmic contact resistance. [0003] We use POCl at high temperature 3 Diffusion to form a PN junction. The PN junction formed in the prior art has a low internal doping concentration and a high surface doping concentration, which leads to a high surface recombination speed of the silicon wafer and reduces the open circuit voltage of the solar cell. A low open ci...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/18H01L21/223
CPCH01L21/223H01L31/18Y02P70/50
Inventor 钱小芳杨冬生
Owner JETION SOLAR HLDG
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