Dibutyl itaconate modified acrylic resin and preparation method thereof

A technology of dibutyl itaconate and acrylic resin, which is applied in the field of paint, can solve the problems of paint viscosity, high paint cost, and the molecular weight of the plasticizer is not too large, so as to achieve good wettability and improve the overall performance

Inactive Publication Date: 2015-10-21
NANTONG PUTHON CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

1. Add organic pigments and fillers wetting agents to the paint. The characteristic is that the wetting properties of pigments and fillers are particularly good. When making black paints or red and yellow paints, an appropriate amount of wetting agents is generally added, but these additives are generally very good. Expensive, adding 5/1000 will increase a lot of cost
2. Add plasticizer. Generally, the amount should not be too much. If too much, the paint will become very viscous. If you add less, it will not achieve a good effect. Therefore, it is necessary to determine the amount of plasticizer according to the amount of pigments and fillers added. The amount of plasticizer, the molecular weight of this plasticizer is not too large, an...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0009] Dibutyl itaconate modified acrylic resin, its components by mass parts are as follows: xylene 30g, butyl acetate 10g, acrylic acid 3g, styrene 21g, methyl methacrylate 12g, butyl acrylate 20g, clothing Dibutyl conate 2g, acrylamide 1g, di-tert-butyl peroxide 1g.

[0010] Its preparation method is: add xylene and butyl acetate into the reaction kettle according to the formula amount, gradually raise the temperature to the reflux temperature (130°C), and then add acrylic acid, styrene, methyl methacrylate, butyl acrylate, itaconic Acrylic acid dibutyl ester, acrylamide, and di-tert-butyl peroxide were weighed and added to the dripping kettle in sequence. After the temperature in the reaction kettle reached reflux, di-tert-butyl peroxide was also added to the dripping kettle and Stir for 15-20 minutes until evenly mixed, then add the materials in the dripping kettle dropwise to the reaction kettle for 4-5 hours. Sampling, testing, packaging.

Embodiment 2

[0012] The components are as follows in parts by mass: 20 g xylene, 15 g butyl acetate, 8 g acrylic acid, 15 g styrene, 15 g methyl methacrylate, 17 g butyl acrylate, 5 g dibutyl itaconate, 3 g acrylamide, Di-tert-butyl oxide 2g.

[0013] Its preparation method is with embodiment 1.

Embodiment 3

[0015] Dibutyl itaconate modified acrylic resin, its percentage by mass parts is as follows, xylene 34g, butyl acetate 5g, acrylic acid 5g, styrene 25g, methyl methacrylate 10g, butyl acrylate 15g, itaconic Acrylic acid dibutyl ester 3g, acrylamide 2g, di-tert-butyl peroxide 1g.

[0016] Its preparation method is with embodiment 1.

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PUM

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Abstract

The invention discloses a dibutyl itaconate modified acrylic resin, which is characterized by comprising the following components by mass: 20-40% of xylene, 5%-15% of butyl acetate, 5-8% of acrylic acid, 15%-25% of styrene, 10%-15% of methyl methacrylate, 15%-25% of butyl acrylate, 1%-5% of dibutyl itaconate, 1-3% of acrylamide, and 1-2% of di-tert-butyl peroxide. The dibutyl itaconate modified acrylic resin provided by the invention has good wettability to organic pigments and fillers, has no influence to the paint film, and also greatly improves the comprehensive properties of resin.

Description

technical field [0001] The invention relates to a paint, in particular to a dibutyl itaconate modified acrylic resin and a preparation method thereof. Background technique [0002] In our traditional oil paint production process, in order to make the paint have a good anti-sedimentation effect, the following methods are mainly used. 1. Add organic pigments and fillers wetting agents to the paint. The characteristic is that the wetting properties of pigments and fillers are particularly good. When making black paints or red and yellow paints, an appropriate amount of wetting agents is generally added, but these additives are generally very good. Expensive, adding five thousandths will increase a lot of costs. 2. Add plasticizer. Generally, the amount should not be too much. If too much, the paint will become very viscous. If you add less, it will not achieve a good effect. Therefore, it is necessary to determine the amount of plasticizer according to the amount of pigments a...

Claims

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Application Information

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IPC IPC(8): C08F212/08C08F220/06C08F220/14C08F220/18C08F222/14C08F220/56C09D125/14
Inventor 徐建军王明星
Owner NANTONG PUTHON CHEM
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