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Method for smelting ultra-low carbon steel with carbon lower than or equal to 20 PPm

A technology for ultra-low carbon steel and ton of steel, applied in the field of smelting ultra-low carbon steel with C≤20PPm, can solve the problems of increased carbon content, difficulty in control, increased production cost, etc., to achieve cost reduction, good slag formation, and stable smelting process Effect

Active Publication Date: 2015-10-21
武汉钢铁有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In the prior art, there is a practice of using high-carbon ferromanganese to replace low-carbon ferromanganese in the steel smelting process with a carbon content of 400-3000ppm, but there is no such thing as an ultra-low carbon steel with a carbon content of less than 20ppm. It has been used because people think that adding high-carbon ferromanganese instead of low-carbon ferromanganese will increase the carbon content of the steel, and it is difficult to control it below 20PPm. Therefore, all the more expensive low-carbon ferromanganese are used, resulting in increased production costs.

Method used

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  • Method for smelting ultra-low carbon steel with carbon lower than or equal to 20 PPm

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Experimental program
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Effect test

Embodiment 1

[0029] The method for smelting C≤15PPm ultra-low carbon steel, the steps:

[0030] 1) Use pure magnesium and slaked lime to desulfurize molten iron. The ratio of pure magnesium and slaked lime is 1:4. No less than 95% of the bare face;

[0031] 2) Converter smelting: During the tapping process, the oxygen content is 732PPm, so the high-carbon ferromanganese added at 2.7Kg / ton of steel;

[0032] 3) Argon blowing, the blowing time is 3.5 minutes;

[0033] 4) Vacuum treatment in RH furnace:

[0034] A. Carry out vacuum decarburization first, and control the argon flow at 66Nm during the first 5 minutes of treatment 3 / hour; then increase the argon flow rate to 125Nm 3 / hour until the end of vacuum treatment;

[0035] B. Adding a low-carbon refining agent with a carbon content of less than 0.15wt% for desulfurization and slag removal, the addition amount is 1.95Kg / ton of steel;

[0036] The components and contents of the low-carbon refining agent are: CaO 38.2 wt%, Al 2 o...

Embodiment 2

[0043] The method for smelting C≤18PPm ultra-low carbon steel, the steps:

[0044] 1) Use pure magnesium and slaked lime to desulfurize molten iron. The ratio of pure magnesium and slaked lime is 1:4.5. No less than 95% of the bare face;

[0045] 2) Converter smelting: During the tapping process, the oxygen content is 718PPm, so the high-carbon ferromanganese added at 2.71Kg / ton of steel;

[0046] 3) Argon blowing, the blowing time is 4.0 minutes;

[0047] 4) Vacuum treatment in RH furnace:

[0048] A. Carry out vacuum decarburization first, and control the argon flow at 61Nm during the first 6 minutes of treatment 3 / hour; then increase the argon flow rate to 108Nm 3 / hour until the end of vacuum treatment;

[0049] B. Adding a low-carbon refining agent with a carbon content of less than 0.15wt% for desulfurization and slag removal, the addition amount is 1.82Kg / ton of steel;

[0050] The components and contents of the low-carbon refining agent are: CaO 41 wt%, Al 2 o ...

Embodiment 3

[0057] The method for smelting C≤16PPm ultra-low carbon steel, the steps:

[0058] 1) Use pure magnesium and slaked lime to desulfurize molten iron. The ratio of pure magnesium and slaked lime is 1:5. No less than 95% of the bare face;

[0059] 2) Converter smelting: During the tapping process, the oxygen content is 742PPm, so the high-carbon ferromanganese added at 2.79Kg / ton of steel;

[0060] 3) Argon blowing, the blowing time is 4.5 minutes;

[0061] 4) Vacuum treatment in RH furnace:

[0062] A. Carry out vacuum decarburization first, and control the argon flow at 80Nm during the first 7 minutes of treatment 3 / hour; then increase the argon flow rate to 129Nm 3 / hour until the end of vacuum treatment;

[0063] B. Adding a low-carbon refining agent with a carbon content of less than 0.15wt% for desulfurization and slag removal, the addition amount is 2.2Kg / ton of steel;

[0064] The components and contents of the low-carbon refining agent are: CaO 45 wt%, Al 2 o ...

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Abstract

The invention discloses a method for smelting ultra-low carbon steel with carbon lower than or equal to 20 PPm. The method comprises the steps that molten iron desulphurization is conducted through pure magnesium and slaked lime, smelting in another furnace is conducted, high carbon ferromanganese is added according to high oxygen content; argon blowing is conducted; vacuum treatment is carried out inside a RH furnace; vacuum decarburization is conducted, a low-carbon refining agent is added to carry out desulfuration and slugging, and when the vacuum treatment is conducted for 15 min, aluminum balls are added; after recycling is conducted for 3 min, silicon iron, ferromanganese, a low-carbon desulfurizing agent are added immediately, and after the recycling is conducted for 5 min, the vacuum treatment is finished; the aluminum balls are sprinkled on the surface of steel slag, and after the total content of iron oxide and MnO in the slag is lower than 5.5 wt%, a later procedure is conducted. On the premise that the mechanical property of the ultra-low carbon steel is guaranteed, the carbon can be lower than or equal to 20 PPm, parts of low-carbon ferromanganese is replaced with parts of the high carbon ferromanganese, the carbon content is lower than 0.15 wt%, parts of slugging materials and parts of a deoxidizing agent are replaced with the low-carbon refining agent and the low-carbon desulfurizing agent, the cost can be lowered by at least 30 yuan per ton of steel, the smelting process is stable, and slagging is good in the refining process.

Description

technical field [0001] The invention relates to a method for smelting steel, in particular to a method for smelting ultra-low carbon steel with C≤20PPm. Background technique [0002] At present, the steel market is severe. Users not only require high-quality and easy-to-use steel products, but also require low prices. Sometimes 5 yuan / ton of steel of the same material can determine the user's buying and selling intentions. The market has forced the demand for steel production costs to be lower and more Well, the lower the production cost, the stronger the competitiveness of steel products, so it is imperative to widely use cheaper raw materials to replace more expensive raw materials in steel production. [0003] Smelting ultra-low carbon steel with carbon less than 0.002%. The principle of producing this steel is that alloys and raw materials with high carbon content cannot be added. The price of refined micro-carbon alloys and raw materials is often high, just like smeltin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/28C21C7/064C21C7/068C21C7/10
Inventor 刘凯吴维轩刘小鸥王春锋刘先同陶勇钢黄东熊英刘立钢
Owner 武汉钢铁有限公司
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