Method for deeply treating antibiotic pharmaceutical wastewater based on magnetic Fenton-like resin

A technology for advanced treatment of pharmaceutical wastewater, applied in natural water treatment, chemical instruments and methods, multi-stage water/sewage treatment, etc. Effect

Active Publication Date: 2015-11-11
TAIZHOU UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Many antibiotic wastewater treatment processes reported in the literature are almost all evaluating the treatment effect of wastewater based on the removal of wastewater COD as an index, but did not pay enough attention to the antibiotic compounds contained in wastewater, and the treated wastewater still contains antibiotic compound

Method used

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  • Method for deeply treating antibiotic pharmaceutical wastewater based on magnetic Fenton-like resin
  • Method for deeply treating antibiotic pharmaceutical wastewater based on magnetic Fenton-like resin
  • Method for deeply treating antibiotic pharmaceutical wastewater based on magnetic Fenton-like resin

Examples

Experimental program
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Effect test

Embodiment 1

[0032] Such as figure 1 , 2As shown, a device based on magnetic Fenton resin for advanced treatment of antibiotic pharmaceutical wastewater is a coagulation sedimentation tank 1, Fenton-like reactor 2, anaerobic baffle reactor 3, aerobic biological Contact oxidation tank 4, sedimentation tank 5, magnetic resin Fenton oxidation tank 6, resin adsorption tower 7; wherein the coagulation sedimentation tank 1 and the sedimentation tank adopt a vertical flow structure; the Fenton-like reactor 2 is equipped with agitator and pH meter; the anaerobic baffle reactor 3 is provided with four vertically installed baffles, which are the first lower baffle, the first upper baffle, the second lower baffle, and the second upper baffle Flow plate, four baffle plates divide the anaerobic baffle reactor 3 into a first upflow chamber, a first downflow chamber, a second upflow chamber, a second downflow chamber, a third upflow chamber, the first upflow chamber and the second upflow chamber The tw...

Embodiment 2

[0044] Embodiment 2: basically the same as embodiment 1, the difference is: in the step (1), the coagulant dosage is controlled at 50g / m 3 , hydraulic retention time is controlled at 3.5h; In step (2), the dosage of Fe-ZSM-5 is 0.5g / L, H 2 o 2 The dosage is 5ml / L, the reaction pH value is controlled between 4-5, and the hydraulic retention time is controlled at 1h; the hydraulic retention time is controlled at 10h in step (3); the dissolved oxygen DO value is controlled at 4mg / L, hydraulic retention time is controlled at 7h; In step (5), hydraulic retention time is 3h; In step (6), H 2 o 2 The dosage is 0.5ml / L, the hydraulic retention time is controlled at 1h, and the hydraulic retention time is controlled at 5h in step (7).

Embodiment 3

[0045] Embodiment 3: basically the same as Embodiment 1, the difference is: in step (1), the dosage of coagulant is controlled at 100g / m 3 , hydraulic retention time is controlled at 3h; In step (2), the dosage of Fe-ZSM-5 is 0.8g / L, H 2 o 2 The dosage is 0.5ml / L, the reaction pH value is controlled between 5-6, and the hydraulic retention time is controlled at 0.5h; the hydraulic retention time is controlled at 6h in step (3); the DO value of dissolved oxygen in step (4) Control at 5mg / L, hydraulic retention time is controlled at 8h; In step (5), hydraulic retention time is 2.5h; In step (6), H 2 o 2 The dosage is 1ml / L, the hydraulic retention time is controlled at 1h, and the hydraulic retention time is controlled at 3h in step (7).

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Abstract

The invention discloses a method and a device for deeply treating antibiotic pharmaceutical wastewater based on magnetic Fenton-like resin. The device comprises a coagulative precipitation tank, a Fenton-like reactor, an anaerobic baffle plate reactor, an aerobic biological contact oxidation tank, a sedimentation tank, a magnetic resin Fenton-like oxidation tank and a resin adsorption tower which are sequentially communicated by virtue of pipelines. By using the method and the device, the antibiotic pharmaceutical wastewater can be deeply treated; and effluent obtained after the antibiotic pharmaceutical wastewater is treated by using the method and the device disclosed by the invention can stably reach up to the emission limit regulated by Fermented Pharmaceutical Industrial Water Pollutant Emission Standard (GB21903-2008).

Description

technical field [0001] The invention belongs to the field of wastewater treatment, and in particular relates to a method and device for advanced treatment of antibiotic pharmaceutical wastewater based on magnetic Fenton resin. Background technique [0002] Antibiotics are important chemical drugs for humans to control various diseases. At present, in antibiotic production, there are still many technical difficulties in the screening and production of antibiotics, strain selection, etc., resulting in many problems such as low raw material utilization rate, low refining purity, high residual antibiotic content in wastewater, and serious environmental pollution. Antibiotic pharmaceutical wastewater mainly comes from production processes such as fermentation, filtration, extraction and crystallization, chemical extraction, and refining. The wastewater has high concentration of COD, BOD and ammonia nitrogen, strong acidity and strong biological toxicity. At present, the treatme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F103/34
Inventor 蒋胜韬祝建中王佳王三秀管玉江白书立
Owner TAIZHOU UNIV
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