Durene-poly-generation technological method and production system for preparing light hydrocarbon through methyl alcohol
A technology of durene and polygeneration, applied in the chemical industry, can solve problems such as difficult control of reaction process and product composition, fixed bed reactor cannot be operated continuously, and stable process conditions cannot be guaranteed, so as to achieve stable and suitable reaction conditions , yield control, and stability improvement effects
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Embodiment 1
[0042] Example 1 (see figure 1 ): The catalyst adopts the THP-1 catalyst developed by CNOOC Tianjin Research Institute of Chemical Industry, the silicon-aluminum ratio is 40, the molecular sieve aperture is 0.4nm, and the particle size is 1.6mm. The methanol etherification reactor is a fixed-bed reactor, and the synthesis reactor is 3-stage moving bed reactor with corresponding regeneration system. The raw material refined methanol and the high-temperature reaction synthesis gas are vaporized after heat exchange, and then heated by the circulating gas and divided into three strands. The main raw material accounting for 70% is sent to the methanol etherification reactor to generate dimethyl ether, which is mixed with the circulating gas and sent to the moving bed first A synthesis reactor, 20% methanol and the synthesis gas from the first synthesis reactor are sent to the second synthesis reactor, 10% methanol is mixed with the synthesis gas from the second synthesis reactor an...
Embodiment 2
[0046] Example 2 (see figure 2 ): The basic conditions are the same as in Example 1, the difference is that the methanol etherification reactor is eliminated, and a one-step method is adopted. After methanol is preheated, it directly enters the moving bed reactor. The process conditions, reaction results and product distribution of hydrocarbon components are shown in the table below.
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