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Piston type fluidized bed low temperature dry distillation technological process

A process method and fluidized bed technology, applied in special dry distillation, petroleum industry, coke oven, etc., can solve the problems of small single furnace processing capacity, high investment and operation costs, and large water consumption, so as to avoid secondary polymerization Wait for the reaction, improve the heat utilization rate, improve the effect of production capacity

Inactive Publication Date: 2008-12-24
ZHUHAI TOP ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Disadvantages of Fushun type retort furnace: 1) The diameter of the oil shale block entering the furnace is 12-75mm, and the utilization rate of oil shale is only 80%, and the oil shale <12mm is discarded; 2) The discarded oil shale occupies a large amount of land, polluting 3) The oil recovery rate is as low as 60-65%; 4) The processing capacity of a single furnace is small, and the production capacity is low; 5) The calorific value of gas is low; 6) Direct water washing, large water consumption, and high sewage treatment costs
The main disadvantage of this method is that the system is complex, not only including two fluidized bed reactors and supporting related equipment, but also need to set up a high-temperature flue gas energy recovery system and a heating system for hot carrier gas, etc. These systems are all installed in a high-temperature environment Work system, high investment and operating costs

Method used

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  • Piston type fluidized bed low temperature dry distillation technological process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Raw materials: Maoming oil shale (the property is mass content) has a water content of 2%, an oil content of 7.15%, and an oil recovery rate of >95%. It takes about 14 tons of oil shale to produce 1 ton of oil.

[0046] The production is carried out according to the processing capacity of 6 million t / a (retort raw material processing capacity), and the riser fluidized retort-water gas production device with the above parameters and conditions is adopted. The powdered Maoming oil shale with a particle size of less than 3mm is sent to the raw material tank, and then sent to the lower end of the riser reactor through the screw propeller, and the superheated steam is used to adjust the temperature of the high-temperature water gas to 650-680°C, and 750t / h powdered Maoming The oil shale enters the riser reactor, and the reaction materials pass through the riser reactor in a plug-flow fluidized bed reaction, and the semi-coke is separated from the oil and gas in the settler; t...

Embodiment 2

[0065] Raw materials: Angolan oil sands (the nature is mass content) moisture content 95%, producing 1 ton of oil requires about 10.5 tons of oil sands, gas production 30m 3 / t.

[0066] According to the 6 million t / a oil shale processing equipment and conditions in Example 1, the Maoming oil shale was replaced with Angola oil sand.

[0067] The processing capacity of powdery Angola oil sand is 750t / h=6 million t / a

[0068] Gas heat carrier at 650-680°C: the amount required to maintain the thermal balance of the system

[0069] Available: liquid oil 570,000 t / a

[0070] Dry gas 180 million m 3 / a

[0071] Ash slag 5.29 million t / a

[0072] (Charged amount 30,000t / a)

[0073] Water gas 116.25 million m 3 / a

Embodiment 3

[0075] Raw materials: Lignite (mass content) moisture content 3 / t.

[0076] According to Example 1 in the 6 million t / a oil shale processing equipment and conditions, powdery lignite replaces Maoming oil shale.

[0077] Powdered lignite processing capacity: 750t / h=6 million t / a

[0078] Gas heat carrier at 650-680°C: the amount required to maintain the thermal balance of the system

[0079] Available: liquid oil 1.2 million t / a

[0080] Dry gas 120 million m 3 / a

[0081] Ash 930,000 t / a

[0082] (Charged amount 4.29 million t / a)

[0083] Water gas 6641.75 million m 3 / a

[0084] Using Fischer-Tropsch water gas to synthesize petroleum: 6641.75 million m of water gas 3 / a

[0085] Available: light synthetic oil 2.19 million t / a of which C 5 + 1.28 million t / a

[0086] by-product CO 2 2.19 million t / a

[0087] Hydrogen production with water gas can obtain high-purity H 2 : 300,000 t / a.

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Abstract

The invention relates to a process method for low temperature carbonization on a fluidized bed. The process method uses the principle of a lift pipe fluid catalytic cracker, uses a lift pipe reactor of the lift pipe fluid catalytic cracker as a carbonization reactor, uses a catalyst regenerator of the lift pipe fluid catalytic cracker as a high-temperature water gas generator, and uses high-temperature water gas as a fluidizing medium and a heat carrier of a carbonization raw material. The carbonization method comprises the following steps that: a carbonizing raw material is conveyed to the lift pipe fluidized bed reactor for a carbonization reaction of the raw material; the reacted oil and gas are separated to produce a carbonized product; carbonized carbocoal enters the water gas regenerator; carbon in the carbonized carbocoal, oxygen and water vapour in air are subjected to oxidation reaction and water gas reaction; the water gas obtained in the reaction is used as the fluidizing medium and the heat carrier during the carbonization process; and solid clinkers produced after the carbonized carbocoal is subjected to the water gas reaction are discharged. Compared with the prior art, the method has the advantages of simple process, high production capacity, less equipment and so on, and can be used in oil shale, oil sand, coal and other substances to produce liquid petroleum products.

Description

technical field [0001] The present invention relates to an energy chemical technology, in particular to a low-temperature dry distillation process technology, in particular to a piston-type fluidized bed low-temperature dry distillation process for oil shale, oil sand, peat, coal and other solid minerals. Background technique [0002] With the worldwide economic development, the worldwide consumption of petroleum continues to grow, resulting in increasingly tight supply of petroleum, rising petroleum prices, and energy security has become a global issue. Especially in China, due to the rapid development of the economy, the consumption of oil has grown rapidly, but the domestic crude oil production is far from keeping up with the growth rate of demand, resulting in a rapid increase in crude oil imports year by year. In 2007, China's crude oil and refined oil imports exceeded 180 million Ton, foreign dependence reached 47%, close to the warning line of 50%, has seriously threat...

Claims

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Application Information

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IPC IPC(8): C10B57/14C10B53/06
Inventor 马广旭苏宏伟陈益洲陈玉宽徐鹤生徐秉声
Owner ZHUHAI TOP ENERGY TECH
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