A kind of polymer shielding material and preparation method thereof
A technology of shielding material and polymer, applied in the field of polymer shielding material and its preparation, can solve the problems of difficult molding and processing, heavy weight, limited application, etc., and achieve the effects of light weight, good shielding performance and simple preparation process
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Embodiment 1
[0019] A method for preparing a polymer shielding material, comprising the steps of:
[0020] 1) Weigh each raw material: by weight: 30 parts of polyphenylene sulfide, 20 parts of polyethylene, 5 parts of graphene oxide, 4 parts of carbon fiber, 3 parts of dolomite, 2 parts of boron nitride, maleic anhydride 3 parts of grafted polyethylene, 1 part of POE, 18 parts of 0.5mol / L nitric acid, 6 parts of hydrazine hydrate, 1 part of antioxidant, 1 part of coupling agent and appropriate amount of dichloroethane;
[0021] 2) Put the carbon fiber and graphite oxide in the raw material in a solution of 0.5mol / L nitric acid, ultrasonically disperse for 2 hours, filter, wash and dry, and set aside;
[0022] 3) Put the treated short fibers and graphite oxide in 2) in dichloroethane, then add hydrazine hydrate, heat up to 110°C and stir, after stirring for 3 hours, cool to 40°C, continue to add dolomite and boron nitride , stir evenly, and after drying, a mixed powder is obtained;
[002...
Embodiment 2
[0026] A method for preparing a polymer shielding material, comprising the steps of:
[0027] 1) Weigh each raw material: by weight: 52 parts of polyphenylene sulfide, 40 parts of polyethylene, 11 parts of graphene oxide, 12 parts of carbon fiber, 16 parts of dolomite, 11 parts of boron nitride, maleic anhydride 10 parts of grafted polyethylene, 5 parts of POE, 30 parts of 0.5mol / L nitric acid, 20 parts of hydrazine hydrate, 4 parts of antioxidant, 5 parts of coupling agent and appropriate amount of dichloroethane;
[0028] 2) Put the carbon fiber and graphite oxide in the raw material in a solution of 0.5mol / L nitric acid, ultrasonically disperse for 5h, filter, wash and dry, and set aside;
[0029] 3) Put the treated short fibers and graphite oxide in 2) in dichloroethane, then add hydrazine hydrate, heat up to 110°C and stir, after stirring for 6 hours, cool to 60°C, continue to add dolomite and boron nitride , stir evenly, and after drying, a mixed powder is obtained;
...
Embodiment 3
[0033] A method for preparing a polymer shielding material, comprising the steps of:
[0034] 1) Weigh each raw material: by weight: 41 parts of polyphenylene sulfide, 30 parts of polyethylene, 8 parts of graphene oxide, 8 parts of carbon fiber, 10 parts of dolomite, 6 parts of boron nitride, maleic anhydride 7 parts of grafted polyethylene, 3 parts of POE, 24 parts of 0.5mol / L nitric acid, 13 parts of hydrazine hydrate, 2 parts of antioxidant, 3 parts of coupling agent and appropriate amount of dichloroethane;
[0035] 2) Put the carbon fiber and graphite oxide in the raw material in a solution of 0.5mol / L nitric acid, disperse ultrasonically for 3 hours, filter, wash and dry, and set aside;
[0036] 3) Put the treated short fibers and graphite oxide in 2) in dichloroethane, then add hydrazine hydrate, heat up to 110°C and stir, after stirring for 4 hours, cool to 50°C, continue to add dolomite and boron nitride , stir evenly, and after drying, a mixed powder is obtained;
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