Preparation method of functionalized polysulfone-tb(Ⅲ) ion complex luminescent material

A luminescent material and functionalization technology, which is applied in the direction of luminescent materials, chemical instruments and methods, etc., can solve the problems of limited luminescent performance, and achieve the effects of excellent mechanical properties, easy processing and molding, and strong light absorption performance

Active Publication Date: 2017-12-15
铁居科技(海南)有限公司
View PDF2 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the reported bonded polymer-rare earth complex luminescent material systems, most of the ligands participating in the coordination in the polymer side chain are aliphatic carboxyl groups (mainly from monomeric acrylic acid or methacrylic acid), and aliphatic carboxyl groups It only plays the role of coordination and chelation for rare earth ions, without the function of sensitization (that is, "Antenna" effect). It needs to add small molecule ligands that cooperate with coordination to form luminescent materials (Suo Q l, Lu F, Shi J W ,Hong H L, Luo J P. Journal of Rare Earths, 2009,27:28), which largely limits the luminescent properties of this type of functional materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of functionalized polysulfone-tb(Ⅲ) ion complex luminescent material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Add 0.5 g of chloromethylated polysulfone (CMPSF) with a chlorine content of 1.6 mmol / g and 50 mL of N,N-dimethylacetamide (DMAC) into a four-necked flask equipped with a condenser, a stirrer, and a thermometer , to fully dissolve CMPSF, then add 0.166g glyoxylic acid (GA) and 0.159g acid-binding agent Na 2 CO 3 , under the protection of nitrogen, at a constant temperature of 85 ° C, stirring for 10 hours to undergo esterification reaction, after the reaction, add ethanol to precipitate the product, filter it with suction, wash it repeatedly with ethanol and distilled water, and dry it in vacuum to constant weight to obtain the side chain bonded B Modified polysulfone PSF-AL with aldehyde (AL) groups.

[0020] Add 0.5g of modified polysulfone PSF-AL to 50mL of N,N-dimethylacetamide (DMAC) and dissolve completely, then add 0.05g of 3-aminopyridine (AP), keep the temperature at 70°C, N 2 Under protection and stirring conditions, the Schiff base reaction between PSF-AL a...

Embodiment 2

[0024] Add 0.5 g of chloromethylated polysulfone (CMPSF) with a chlorine content of 1.7 mmol / g and 50 mL of solvent DMAC into a four-neck flask equipped with a condenser, a stirrer, and a thermometer to fully dissolve CMPSF. Then add 0.266g glyoxylic acid (GA) and 0.19g acid-binding agent Na 2 CO 3 , N 2 Under protection, at a constant temperature of 65°C, the esterification reaction occurred with stirring for 8 hours. After the reaction, add ethanol to precipitate the product, filter it with suction, wash repeatedly with ethanol and distilled water, and dry it in vacuum to constant weight to obtain the modified polysulfone PSF-AL with acetaldehyde (AL) group bonded to the side chain. After completely dissolving 0.5g of modified polysulfone PSF-AL and 50mL of solvent DMAC, add 0.065g of 3-aminopyridine (AP), keep the temperature at 60°C, N 2Under protection and stirring conditions, the Schiff base reaction between PSF-AL and AP was carried out for 7 h. After the reaction, ...

Embodiment 3

[0026] In a four-necked flask equipped with a condenser, a stirrer, and a thermometer, add 0.5 g of chloromethylated polysulfone (CMPSF) with a chlorine content of 1.8 mmol / g and 50 mL of solvent DMAC to fully dissolve CMPSF. Then add 0.233g glyoxylic acid (GA) and 0.19g acid-binding agent Na 2 CO 3 , N 2 Under protection, at a constant temperature of 75°C, the esterification reaction occurred with stirring for 12 hours. After the reaction, add ethanol to precipitate the product, filter it with suction, wash repeatedly with ethanol and distilled water, and dry it in vacuum to constant weight to obtain the modified polysulfone PSF-AL with acetaldehyde (AL) group bonded to the side chain. After completely dissolving 0.5g of modified polysulfone PSF-AL and 50mL of solvent DMAC, add 0.075g of 3-aminopyridine (AP), keep the temperature at 70°C, N 2 Under protection and stirring conditions, the Schiff base reaction between PSF-AL and AP was carried out for 8 h. After the reactio...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the field of bonded high molecule-rare earth complex luminescent materials, and relates to a preparation method of a functional polysulfone-Tb (III) ion complex luminescent material. According to the invention, a bidentate Schiff base ligand with coordination chelation and sensitization luminescent dual functions is synthesized and bonded on the side chain of polysulfone. The Schiff base ligand can coordinate with rare earth Tb (III) ion to form a stable high molecule-rare earth complex, and has a conjugated aromatic ring. The Schiff base ligand has high light absorption performance, can considerably generate intramolecular energy transfer, and can strongly sensitize the fluorescence emission of rare earth Tb (III) ion. Therefore, the photo-luminescent material emitting green light can be successfully obtained.

Description

technical field [0001] The invention belongs to the field of bonded polymer-rare earth complex luminescent materials, and in particular relates to a preparation method for functionalized polysulfone-Tb(III) ion complex luminescent materials. Background technique [0002] In the field of luminescent materials, bonded polymer-rare earth complexes have important application value and development prospects. This type of material not only retains the unique and excellent luminescent properties of small-molecule rare earth complexes, but also has the excellent mechanical properties of polymer compounds and the characteristics of easy processing and molding (especially the characteristics of easy film formation), and it can be combined with small-molecule rare earth complexes. Compared with the luminescent material formed by doping in the polymer matrix, the bonded polymer-rare earth complex luminescent material exhibits the characteristics of internal homogeneity, and these charac...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C08G75/20C09K11/06
Inventor 门吉英高保娇王蕊欣安富强张丹丹
Owner 铁居科技(海南)有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap