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Slump retention agent and preparation method thereof

A technology of retaining agent and slump, which is applied in the field of slump retaining agent and its preparation, can solve the problems of uneven slump retaining performance of concrete, limited source of slump retaining agent raw materials, and affecting concrete construction performance, etc., to achieve the expansion of raw materials source, excellent slump performance

Active Publication Date: 2016-01-27
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Along with the wide application of slump retaining agent, its usage is increasing day by day, the synthetic raw material of existing slump retaining agent generally comprises polyether, initiator, chain transfer agent, reducing agent, small monomer and water, wherein, Polyether often chooses one or two or more of polyethylene glycol monomethyl ether, allyl polyoxyethylene ether, methallyl polyoxyethylene ether and methylbutenyl polyoxyethylene ether; Some slump retaining agents have limited sources of raw materials, and due to the differences in concrete composition, preparation technology and construction environment, the slump retaining agents have different performances on concrete and thus affect the construction performance of concrete; the existing slump The slump retaining agent can no longer meet the actual use requirements, so it is necessary to develop more slump retaining agent raw materials while ensuring the excellent performance of the slump retaining agent

Method used

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  • Slump retention agent and preparation method thereof
  • Slump retention agent and preparation method thereof
  • Slump retention agent and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0024] The raw material components are as follows in parts by mass: 160 parts of methallyl glycol polyoxyethylene ether, 1440 parts of methallyl polyoxyethylene ether, 8 parts of ammonium persulfate, 4 parts of thioglycolic acid, 4 parts Ascorbic acid, 80 parts of acrylic acid, 20 parts of sodium hydroxide, 2284 parts of water;

[0025] Put the above-mentioned 160 parts of methallyl glycol polyoxyethylene ether, the above-mentioned 1440 parts of methallyl polyoxyethylene ether and 1067 parts of water into the reaction device, turn on the stirring and heating equipment to heat the reactant to 54 ° C, Stop heating after the temperature reaches 54°C, and obtain a polyether solution with a mass percent concentration of 60% after fully dissolving, mix the above-mentioned 4 parts of thioglycolic acid, the above-mentioned 4 parts of ascorbic acid and 792 parts of water, and stir evenly to obtain a mass percent concentration of 1% mixture solution, the above-mentioned 80 parts of acry...

Embodiment 2

[0029] The raw material components are as follows in parts by mass: 360 parts of methallyl glycol polyoxyethylene ether, 1440 parts of methylbutenyl polyoxyethylene ether, 20 parts of sodium persulfate, 9.6 parts of mercaptopropionic acid, 8 Parts of sodium sulfite, 150 parts of acrylic acid, 50 parts of methacrylic acid, 40 parts of sodium hydroxide, 2348 parts of water;

[0030] Put the above-mentioned 360 parts of methallyl glycol polyoxyethylene ether, the above-mentioned 1440 parts of methallyl polyoxyethylene ether and 771 parts of water into the reaction device, turn on the stirring and heating equipment to heat the reactant to 56 °C, Stop heating after the temperature reaches, and obtain a polyether solution with a mass percent concentration of 70% after fully dissolving, mix the above-mentioned 9.6 parts of mercaptopropionic acid, the above-mentioned 8 parts of sodium sulfite and 569 parts of water, and stir evenly to obtain a mass percent concentration of 3 % mixture...

Embodiment 3

[0034] The raw material components are as follows in parts by mass: 825 parts of methallyl glycol polyoxyethylene ether, 425 parts of methallyl polyoxyethylene ether, 400 parts of methylbutenyl polyoxyethylene ether, 8.8 Parts of hydrogen peroxide, 4.4 parts of mercaptopropionic acid, 5.2 parts of sodium sulfite, 93 parts of acrylic acid, 7 parts of hydroxyethyl acrylate, 3.5 parts of hydroxypropyl acrylate, 3.5 parts of hydroxybutyl acrylate, 35.2 parts of sodium hydroxide and 2189.4 parts of water;

[0035] Put the above-mentioned 825 parts of methallyl glycol polyoxyethylene ether, 425 parts of methallyl polyoxyethylene ether, 400 parts of methylbutenyl polyoxyethylene ether and 888 parts of water into the reaction device, and open Stir the heating equipment to heat the reactant to 55°C, stop heating after the temperature reaches, and obtain a polyether solution with a mass percent concentration of 65% after fully dissolving, mix the above 4.4 parts of mercaptopropionic acid...

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Abstract

The invention discloses a slump retention agent and a preparation method thereof, which relates to the field of concrete additives, and solves the problems that the slump retention agent is limited in the source of raw materials. Raw materials of the slump retention agent consist of the following components by weight percent: 40 to 45 percent of polyether, 0.2 to 0.5 percent of initiator, 0.1 to 0.24 percent of chain transfer agent, 0.1 to 0.2 percent of reducing agent, 2 to 5 percent of small monomers, 48.06 to 58.7 percent of water and 0.5 to 1.0 percent of alkali, wherein the polyether is methyl allyl glycol polyoxyethylene ether, or the polyether is a mixture of methyl allyl glycol polyoxyethylene ether and methyl allyl polyoxyethylene ether and / or methyl butenyl polyoxyethylene ether. The slump retention agent is wide in selectable range of raw materials and excellent in performance.

Description

technical field [0001] The invention relates to the field of concrete admixtures, in particular to a slump retaining agent and a preparation method thereof. Background technique [0002] As a building material, concrete is widely used in many fields. With the development of concrete, the technology of concrete admixture has also been rapidly developed. Concrete admixture is an indispensable component in concrete. It plays a role in concrete production technology. To the core role, determines the quality of concrete. Among them, as an important concrete admixture, water reducing agent can effectively improve the construction performance of concrete and increase the strength of concrete. Among many water reducers, polycarboxylate water reducer is the third generation water reducer, which has high water reducing rate, less dosage, environmental protection and the ability to maintain concrete slump. With the rapid development of my country's economy and construction With the ra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/32
Inventor 白杰蔡阳王博
Owner CHINA BUILDING MATERIALS ACAD
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