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Comprehensive stabilization treatment technology of waste incineration fly ash

A waste incineration fly ash and stabilization treatment technology, applied in chemical instruments and methods, dispersed particle separation, separation methods, etc., can solve the problems of complex components, large fluctuations, and increased amount of fly ash in flue gas and fly ash, etc. Achieve the effect of avoiding unsatisfactory stabilization effect, reducing the fluctuation of physical and chemical properties, and reducing the difficulty of stabilization

Active Publication Date: 2016-02-03
TIANJIN YIMING ENVIRONMENTAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, activated carbon powder spraying is widely used to adsorb dioxins in the flue gas pollution control facilities of incinerators. The oxins are transferred to the fly ash in the solid phase, but they are not completely removed; another study uses calcium-based inhibitors to interact with the dioxin precursors in the cooling flue gas to inhibit the synthesis of dioxins, but this The method is still the method of spraying lime powder, which leads to an increase in the amount of fly ash, which in turn increases the difficulty of subsequent treatment of fly ash
[0005] Most of the fly ash stabilization process adopts the method of directly adding organic or inorganic heavy metal stabilizers, alkali activators, etc., and it is difficult to determine the reasonable process parameters such as the type of agent and the amount of addition, and stabilizers are common in conventional agent stabilization processes. The problem of high addition ratio and low pass rate of fly ash stabilized products makes it difficult to ensure that the safe disposal rate of fly ash reaches the goal of 100% pass
[0006] The complexity of garbage components leads to complex and fluctuating components of flue gas and fly ash. Traditional single treatment measures are often passive, and it is difficult to achieve the comprehensive treatment of flue gas and fly ash source purification or reduction.

Method used

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  • Comprehensive stabilization treatment technology of waste incineration fly ash
  • Comprehensive stabilization treatment technology of waste incineration fly ash
  • Comprehensive stabilization treatment technology of waste incineration fly ash

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Sampling is taken at the discharge chute of the ash conveying equipment, and the heavy metal leaching toxicity of the fly ash sample exceeds the requirements of GB16889-2008 "Pollution Control Standards for Domestic Waste Landfill Sites" during on-site semi-quantitative testing, and the addition of comprehensive stabilizers should be appropriately increased Amount, and determine the amount of heavy metal stabilizer added in the fly ash stabilization system is 1.5% of the total amount of fly ash. After the fly ash is treated by the stabilization system, it enters the temporary storage, takes samples, and quantitatively detects the fly ash samples. The results are shown in Table 1. Landfill Pollution Control Standards, directly enter the domestic waste landfill for safe landfilling.

[0033] Table 1 List of heavy metal leaching toxicity and dioxin content in fly ash after comprehensive stabilization:

[0034]

[0035]Example 2

Embodiment 2

[0037] Sampling at the discharge chute of the ash conveying equipment, if the heavy metal leaching toxicity of the fly ash sample exceeds the requirements of GB16889-2008 "Pollution Control Standards for Domestic Waste Landfill Sites" during semi-quantitative testing on site, the amount of comprehensive stabilizer should be appropriately increased Addition amount, and determine the addition amount of heavy metal stabilizer in the fly ash stabilization system as 1% of the total amount of fly ash. After the fly ash has been treated by the stabilization system, it enters the temporary storage for sampling and quantitative testing of the fly ash samples. The test results are shown in Table 2. The leaching concentration of lead is still not up to the standard. During temporary storage, due to changes in environmental conditions, etc., the lead in fly ash is re-leached. Add 8% mixture of sodium phosphate and sodium polysulfide as an emergency stabilizer to fly ash that does not meet...

Embodiment 3

[0045] Sampling was taken at the discharge chute of the ash conveying equipment, and the heavy metal leaching toxicity and dioxin content of the fly ash samples did not exceed the requirements of GB16889-2008 "Pollution Control Standards for Domestic Waste Landfill Sites" during the on-site semi-quantitative testing. Directly enter the temporary storage, and take another sample for quantitative detection. The test results are shown in Table 4. The leaching concentration of heavy metals and dioxin content in fly ash all meet the requirements of GB16889-2008 "Pollution Control Standards for Domestic Waste Landfill Sites". Into the domestic waste landfill safe landfill.

[0046] Table 4 List of heavy metal leaching toxicity and dioxin content in fly ash after comprehensive stabilization:

[0047]

[0048] In Examples 1 to 3, the impact of high activity deacidification agent and comprehensive stabilizer spray volume on pollutants in flue gas is as follows: figure 1 shown. It ...

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Abstract

The invention relates to a comprehensive stabilization treatment technology of waste incineration fly ash, aims at the problems of high consumption of lime slurry, large generation amount of fly ash and high treatment difficulty in the smoke treatment process of the waste incineration plant in the prior art and the problems of high chemical adding ratio and low qualified rate of the fly ash in the ordinary stabilization technology, and combines four core technologies of modifying a smoke deacidification agent through a semi-dry process, reinforcing deacidification of smoke through a dry process and pre-stabilizing fly ash, carrying out chemical stable rapid field detection, reinforcing stabilization effect of fly ash and emergently remedying. Through adoption of high-activity, high-efficiency, high-stability and low-dosage chemicals, the comprehensive stabilization purposes of reducing fly ash source, degrading dioxin source, stabilizing components of smoke and fly ash and stabilizing heavy metals in the fly ash are achieved; the fly ash treatment difficulty is greatly reduced; the generation of fly ash is changed into production of fly ash; the purpose of ensuring that the safe treatment rate of the fly ash reaches up to 100% on the premise of controllable cost can be finally achieved.

Description

technical field [0001] The technology relates to a comprehensive stabilization treatment technology for waste incineration fly ash, and belongs to the technical field of hazardous waste treatment and disposal. Background technique [0002] Incineration is considered to be one of the most effective ways to deal with urban and industrial waste, but waste incineration fly ash, as a secondary pollutant produced in the process of waste incineration disposal, contains high concentrations of heavy metals and dioxin-like persistent organic pollutants. are classified as hazardous waste. It is estimated that the annual output of waste incineration fly ash will reach 3.2 million tons by the end of 2015, which will seriously hinder the healthy and sustainable development of the waste incineration industry. At present, the fly ash of waste incineration is generally stabilized and then landfilled. Although it can alleviate the urgent need, as an end-of-life disposal method, it has disadv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/75B01D53/50B01D53/68B01D53/40B01D53/70B01D53/64
Inventor 张曙光王娟娟李萍
Owner TIANJIN YIMING ENVIRONMENTAL TECH CO LTD
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